Fluid treatment

• US 4,384,943 A
• Filed: 09/11/1980
• Issued: 05/24/1983
• Est. Priority Date: 09/11/1980
• Status: Expired due to Term

• Current Assignee: University of Virginia Patent Foundation (University of Virginia)
• Original Assignee: University of Virginia Patent Foundation (University of Virginia)
• Inventors: Stoner, Glenn E., Scribner, Louie L. Jr., Cahen, George L. Jr.
• Primary Examiner(s): Tufariello, T. M.
• Application Number:
  US06/185,733
• Time in Patent Office: 985 Days
• Field of Search: 204/149, 204/151, 204/152, 204/186, 204/180 R, 204/275, 204/260, 204/268, 204/237, 317/262 AE
• US Class Current: 205/744
• CPC Class Codes: C02F 1/46104 Devices therefor; Their operating or servicing
• CPC Class Codes: C02F 1/467 by electrochemical disinfection; by electrooxydation or by electroreduction
• CPC Class Codes: C02F 1/4674 with halogen or compound of halogens, e.g. chlorine, bromine
• CPC Class Codes: C02F 2001/46128 Bipolar electrodes
• CPC Class Codes: C02F 2103/008 Originating from marine vessels, ships and boats, e.g. bilge water or ballast water
• CPC Class Codes: C02F 2103/42 from bathing facilities, e.g. swimming pools
• CPC Class Codes: C02F 2201/4613 Inversing polarity
• CPC Class Codes: C02F 2201/4615 Time
• CPC Class Codes: C02F 2301/08 Multistage treatments, e.g. repetition of the same process step under different conditions
• CPC Class Codes: C02F 2303/04 Disinfection

Abstract

Methods and apparatus for electrochemically disinfecting or treating contaminated aqueous liquids by contact disinfection and/or the generation of a biocidally active chemical agent in the liquid being treated. Rapid polarization of reactor electrodes after polarity reversal and out-of-phase operation of paired reactors can be employed to promote efficient disinfection, reduce the bulk of the apparatus, and protect the reactor electrodes against damage.

Claims

1. A method of electrochemically treating aqueous fluids to neutralize or destroy harmful or otherwise unwanted microorganisms therein, said method comprising the steps of:

passing said fluid between a pair of reversibly polarizable electrodes;

applying a D.C. potential across said electrodes, said potential being maintained at a level which is effective to neutralize or destroy said organisms by contact with one of said electrodes and/or by the electrolytic generation of a chemical agent which is biocidally effective against said organisms;

periodically reversing the polarity of said electrodes to chemically and/or biologically defoul them, the reversal of polarity being carried out by creating between said electrodes a flow of current exceeding that needed to maintain said electrodes at said effective level, thereby bringing about a rapid repolarization of said electrodes to said effective potential level; and

thereafter maintaining the potential across said electrodes at the effective level until the next reversal of polarity by controlling the voltage applied across or the current density between said electrodes and allowing the other of said parameters to vary in proportion to the resistance between the electrodes.

6. A method as defined in any of the preceding claims 1, 3, or 5 in which the potential across said electrodes is maintained at a level of 3.5 to 4.4 volts.

7. A method as defined in any of the preceding claims 1, 3, or 5 in which the current density is maintained at a level of 0.01 to 0.016 amps/cm².

8. A method as defined in any of the preceding claims 1, 3, or 6 in which the reversal of potential is effected about every 2.5 to 5 minutes.

9. A method as defined in any of the preceding claims 1, 3, or 6 in which the current density between said electrodes is maintained at a level of 0.03 to 0.05 amps/cm² during said rapid repolarization and then reduced to a level of 0.01 to 0.016 amps/cm² until the next reversal of potential is effected.

10. A method as defined in claim 9 wherein said current density is maintained at said level of 0.03 to 0.05 amps/cm² for a period of 1 to 45 seconds.

2. A method of electrochemically treating aqueous fluids to neutralize or destroy harmful or otherwise unwanted microorganisms therein, said method comprising the steps of:

passing said fluid between first and second pairs of reversibly polarizable electrodes;

applying a D.C. potential across each pair of electrodes, said potential being maintained at a level which is effective to neutralize or destroy said organisms by contact with one of said electrodes and/or by the electrolytic generation of a chemical agent which is biocidally effective against said organisms; and

periodically reversing the polarity of the electrodes of each said pair to chemically and/or biologically defoul them, the reversal of polarity across the two pairs of electrodes being so time phased that one of said pairs is always capable of functioning as aforesaid.

4. A method as defined in claim 2 wherein the reversal of polarity is carried out by creating between the electrodes of each said pair a flow of current exceeding that needed to maintain the potential therebetween at said effective level, thereby bringing about a rapid repolarization of the electrodes of said pair to said effective potential level and thereby making them capable of functioning as aforesaid;

and thereafter maintaining the potential across said electrodes at the effective level until the next reversal of polarity by controlling the voltage across or the current density between said electrodes and allowing the other of those parameters to vary in proportion to the resistance between said electrodes.

5. A method as defined in claim 2 in which the reversal of polarity of the two pairs of electrodes is effected on the order of 90 degrees out-of-phase.

3. A method of electrochemically treating aqueous fluids to neutralize or destroy harmful or otherwise unwanted microorganisms therein, said method comprising the steps of:

passing said fluid between a pair of reversibly polarizable electrodes;

applying a D.C. potential across said electrodes, said potential being maintained at a level which is effective to neutralize or destroy said organisms by contact with one of said electrodes and/or by the electrolytic generation of a chemical agent which is biocidally effective against said organisms; and

introducing into said liquid a composition that is electrolytically decomposable at the potential maintained across the electrodes to furnish said chemical agent in an available form to the fluid being treated, said method also including the steps of;

periodically reversing the polarity of said electrodes to chemically and/or biologically defoul them, the reversal of polarity being carried out by creating between said electrodes a flow of current exceeding that needed to maintain said electrodes at said effective potential level, thereby bringing about a rapid repolarization of said electrodes to said effective level; and

thereafter maintaining the potential across said electrodes at the effective level until the next reversal of polarity by controlling the voltage applied across or the current density between said electrodes and allowing the other of those parameters to vary in proportion to the resistance between the electrodes.