Method of extruding and pelletizing expandable polymeric composition with recycling of transparent water supplied across the face of the extrusion die

• US 4,385,016 A
• Filed: 12/19/1980
• Issued: 05/24/1983
• Est. Priority Date: 12/19/1980
• Status: Expired due to Fees

• Current Assignee: Phillips Petroleum Company (ConocoPhillips)
• Original Assignee: Phillips Petroleum Company (ConocoPhillips)
• Inventors: Gwinn, J. S.
• Primary Examiner(s): Anderson, Philip E.
• Application Number:
  US06/218,229
• Time in Patent Office: 886 Days
• Field of Search: 264/53, 264/54, 264/142, 264/40.7, 264/DIG. 5, 264/37, 425/144, 425/308
• US Class Current: 264/37.26
• CPC Class Codes: B29B 13/00 Conditioning or physical treatment of the material to be shaped chemical aspects C08J3/00 ; heating, cooling or curing during shaping B29C35/00; thermal after-treatment B29C71/02
• CPC Class Codes: B29B 7/603 in measured doses, e.g. proportioning of several materials
• CPC Class Codes: B29B 7/728 Measuring data of the driving system, e.g. torque, speed, power, vibration B29B7/724 takes precedence
• CPC Class Codes: B29B 7/748 Plants B29B7/7433, B29B7/7485, B29B7/7495 take precedence
• CPC Class Codes: B29B 9/065 under-water, e.g. underwater pelletizers
• CPC Class Codes: B29B 9/16 Auxiliary treatment of granules
• CPC Class Codes: B29C 44/461 dispensing apparatus, e.g. dispensing foaming resin over the whole width of the moving surface
• CPC Class Codes: Y10S 264/05 Use of one or more blowing agents together

Abstract

A method for providing pellets of extrusion compounded expandable polymeric compositions by (a) introducing a blowing agent and polymeric compound into an extruder, (b) extruding a composition containing the blowing agent and polymeric compound with discharge of the extrusion underwater through a pelleter at a temperature below blowing agent activation temperature, (c) supplying a stream of water across the die face of the pelleter at a predetermined first temperature sufficient to produce pellets, (d) supplying additional transport water downstream of the pelleter to further cool the pellets to a second predetermined temperature, and (e) separating the cooled pellets from the transport water. In an additional embodiment collecting the separated pellets, conditioning the transport water to the first predetermined temperature, and recycling the transport water to the die face.

In a process for extruding and transporting pellets in which an extruder discharges underwater through a pelleting device a method for controlling the temperature of the pellets in which transport water is supplied to the die plate of the pelleter at the first predetermined temperature sufficient to produce pellets and additional transport water supplied downstream of the pelleter further to cool the pellets to a predetermined second temperature.

In a method for transporting pelleted material a control system that comprises sensing and operating conditions, generating a signal according to the operating condition, and diverting flow of the pelleted material in response to that signal.

Claims

1. A method for providing pellets of extrusion compounded expandable polymeric compositions comprising:

(a) introducing a blowing agent and said polymeric compound into an extruder in a ratio of flowing agent to polymeric compounds sufficient to provide expansion of a composition of the polymeric compound and blowing agent upon elevation of temperature to the activation temperature of the blowing agent,

(b) extruding a composition of said polymeric compound and blowing agent discharging underwater through a pelleter at a temperature below the flowing agent activation temperature,

(c) supplying a stream of water across the die face of said pelleter for cooling and transporting pellets, said water being supplied at a predetermined first temperature in a range to maintain pellets below blowing agent activation temperature but sufficiently elevated to cause formation of uniform pellets,

(d) supplying additional transport water downstream of said pelleter in an amount and of a temperature further to cool the pellets and total flow of transport water to a second predetermined temperature in a range substantially to prevent activation of blowing agent by heat retained in said pellets, and

(e) separating the cooled pellets from said transport water.

2. A method of claim 1 further comprising:

(f) collecting said separated pellets,

(g) conditioning said transport water of step (d) to said predetermined first temperature, and

(h) recycling said transport water to the die face.

3. A method of claim 1 wherein said blowing agent is combined with at least one other additive chosen from powdered polymeric compounds and antioxidants for introduction into said extruder thereby providing an additive composition.

4. A method of claim 1, 2 or 3 wherein said separated pellets are transported through a flow diverter valve into product storage in response to a signal generated according to operation upstream in the process being sensed within designed parameters.

5. A method of claim 1, 2 or 3 wherein said separated pellets are transported through a flow diverter valve into a scrap storage vessel in response to a signal generated according to operation upstream in the process being sensed that is outside of designed parameters.

6. A method of claim 4 wherein the operating condition is the sensed transporting of an additive to the extruder.

7. A method of claim 5 wherein the operating condition is the sensed transporting of an additive to the extruder.

8. A method of claim 1, 2, or 3 wherein said thermoplastic resin is high-density polyethylene, said blowing agent is azodicarbonamide activated at a temperature in the range of about 365°

-385°

F., said predetermined first temperature is in the range of about 150°

-180°

F., and said predetermined second temperature is in the range of about 120°

to about 180°

F.

9. A method of claim 8 wherein the azodicarbonamide blowing agent is activated at a temperature of about 375°

F., said first predetermined temperature is about 170°

F., and said second predetermined temperature is about 170°

F.

10. In a process for extruding and transporting pellets in which an extruder is discharged underwater through a pelleting device a method for controlling the temperature of the pellets comprising

(a) supplying transport water to the die plate of said pelleter at a predetermined first temperature in a range sufficiently elevated to form uniform pellets but below a specifically designated temperature, and

(b) supplying additional transport water downstream of said pelleter at a flow and temperature further to cool said pellets to a predetermined second temperature in a specifically designated range.

11. In a method for transporting pelleted material a control system comprising:

(a) sensing the operation of a device transporting an additive to the inlet of the extruder process,

(b) generating a signal according to said sensed operation, and

(c) diverting flow of said pelleted material in response to said signal.