Laminated light-polarizing sheet

• US 4,387,133 A
• Filed: 07/06/1981
• Issued: 06/07/1983
• Est. Priority Date: 07/11/1980
• Status: Expired due to Term

• Current Assignee: Toyoda Gosei Company Limited (Toyota Motor Corporation)
• Original Assignee: Toyoda Gosei Company Limited (Toyota Motor Corporation)
• Inventors: Ichikawa, Rinjiro, Hitomi, Chiyoji
• Primary Examiner(s): Robinson, Ellis P.
• Application Number:
  US06/280,491
• Time in Patent Office: 701 Days
• Field of Search: 428/1, 428/425.8, 428/418, 428/419, 428/413, 428/215, 428/480, 428/458, 428/463, 428/411, 428/522, 428/910, 428/416, 428/334-336, 350/337, 350/370, 427/163, 427/124
• US Class Current: 428/215
• CPC Class Codes: B32B 2250/40 Symmetrical or sandwich layers, e.g. ABA, ABCBA, ABCCBA
• CPC Class Codes: B32B 2307/202 Conductive
• CPC Class Codes: B32B 2307/412 Transparent
• CPC Class Codes: B32B 2307/734 Dimensional stability
• CPC Class Codes: B32B 2363/00 Epoxy resins
• CPC Class Codes: B32B 2367/00 Polyesters, e.g. PET, i.e. polyethylene terephthalate
• CPC Class Codes: B32B 2457/202 LCD, i.e. liquid crystal displays
• CPC Class Codes: B32B 27/08 of synthetic resin
• CPC Class Codes: B32B 27/286 comprising polysulphones; polysulfides
• CPC Class Codes: B32B 27/36 comprising polyesters
• CPC Class Codes: C09K 2323/031 Polarizer or dye
• CPC Class Codes: G02B 5/3033 in the form of a thin sheet or foil, e.g. Polaroid
• CPC Class Codes: G02F 1/133305 Flexible substrates, e.g. plastics, organic film
• CPC Class Codes: G02F 1/133528 Polarisers
• CPC Class Codes: Y10S 428/91 Product with molecular orientation
• CPC Class Codes: Y10T 428/24967 Absolute thicknesses specified
• CPC Class Codes: Y10T 428/263 Coating layer not in excess of 5 mils thick or equivalent
• CPC Class Codes: Y10T 428/264 Up to 3 mils
• CPC Class Codes: Y10T 428/265 1 mil or less
• CPC Class Codes: Y10T 428/31511 Of epoxy ether
• CPC Class Codes: Y10T 428/31522 : Next to metal
• CPC Class Codes: Y10T 428/31529 : Next to metal
• CPC Class Codes: Y10T 428/31533 : Of polythioether
• CPC Class Codes: Y10T 428/31605 : Next to free metal
• CPC Class Codes: Y10T 428/31681 : Next to polyester, polyamide or polyimide [e.g., alkyd, glue, or nylon, etc.]
• CPC Class Codes: Y10T 428/31699 : Ester, halide or nitrile of addition polymer
• CPC Class Codes: Y10T 428/31786 : Of polyester [e.g., alkyd, etc.]
• CPC Class Codes: Y10T 428/31935 : Ester, halide or nitrile of addition polymer

Abstract

A laminated light-polarizing sheet comprising a film or sheet of a polymer, especially a phenoxyether polymer, laminated at least on one surface of a light-polarizing film and a transparent conductive layer formed by vacuum metal evaporation etc. on a surface of a film or sheet to the light-polarizing film, wherein the film or sheet has specified ranges of retardation value, heat distortion temperature, average visible light transmittance, water vapor permeability, Izod impact strength and degree of swelling in solvents.

Claims

1. A laminated light-polarizing sheet comprising a light-polarizing film, a polymeric supporting film or sheet having a thickness in the range of 5 to 1000 microns formed to at least one surface of said light-polarizing film, and a transparent conductive layer comprising a metal oxide or a mixture of metal oxides or a metal formed on the surface of said polymeric supporting film or sheet opposite to said light-polarizing film wherein said polymeric supporting film or sheet has the following physical properties:

Retardation value;

not more than 30 millimicrons;

Heat distortion temperature;

not lower than 80°

C.;

Average visible light transmittance;

not less than 75%;

Water vapor permeability;

not higher than 30 g/m² ·

24 hr.;

Izod impact strength;

not less than 1.5 kg·

cm/cm;

Degree of swelling on a surface in a solvent;

not more than 0.5%.

2. A laminated light-polarizing sheet according to claim 1, wherein the polymeric supporting film or sheet has a critical bending length of not more than 5 mm.

3. A laminated light-polarizing sheet according to claim 1 or 2, wherein said surface of said polymeric supporting film or sheet on the opposite side with respect to said light-polarizing film is cured after it is coated or impregnated with a monomer and/or curable polymer, the so-formed cured layer having a thickness of from 1 to 10 microns.

4. A laminated light-polarizing sheet according to claim 1 or 2, wherein said polymeric supporting film or sheet is made of a cross-linked phenoxyether polymer obtained on cross-linking reaction between a polyfunctional compound and active hydrogen groups of a phenoxyether polymer having at least 20 units and not less than 50 weight percent of repeat units of the formula:

##STR4## wherein R¹ to R⁶ are independently hydrogen or alkyl groups containing 1 to 3 carbon atoms, R⁷ is an alkylene group containing 2 to 4 carbon atoms and m is an integer of 0 to 3

or a mixture consisting predominantly of said phenoxyether polymer and one or more other polymers.

5. A laminated light-polarizing sheet according to claim 4, wherein said phenoxyether polymer has the formula:

##STR5## wherein n is an integer of 50 to 500.

6. A laminated light-polarizing sheet according to claim 3, wherein the monomer and/or curable polymer is mainly composed of an acryloyl or methacryloyl compound containing at least 50% of a monomer having at least 3 aryloyloxy and/or methacryloyloxy groups per molecule.

7. A laminated light-polarizing sheet according to claim 3, wherein the curable polymer is a mixture of polyfunctional compound and phenoxyether polymer having at least 20 units and not less than 50 weight percent of repeat units of the formula:

##STR6## wherein R¹ to R⁶ are independently hydrogen or alkyl groups containing 1 to 3 carbon atoms, R⁷ is an alkylene group containing 2 to 4 carbon atoms and m is an integer of 0 to 3

or a mixture consisting predominantly of said phenoyether polymer and one or more other polymers.

8. A laminated light-polarizing sheet according to claim 3, wherein said curable polymer consists of an epoxy resin or a mixture thereof with other polymers and a curing agent.

9. A laminated light-polarizing sheet according to claim 3, wherein the polymeric supporting film or sheet is formed of a polymeric material selected from the group consisting of polyethersulfones, polysulfones and polyacrylates.

10. A laminated light-polarizing sheet according to claim 1 or 2, further comprising a biaxially stretched film or sheet of a terephthalate polyester, having a heat distortion temperature of not lower than 130°

C., laminated to the opposite side of said transparent conductive layer.

11. A laminated light-polarizing sheet according to claim 10, wherein said terephthalate polyester is polyethylene terephthalate.

12. A laminated light-polarizing sheet according to claim 1 or 2, wherein the laminated light-polarizing film has a light transmittance of not less than 60% within the wavelength range of 500 to 800 microns and of not more than 10% within the range of 420 to 230 microns.

13. A laminated light-polarizing sheet according to claim 1 or 2, further comprising a reflective layer lying on the side opposite to the transparent conductive layer.

14. A laminated light-polarizing sheet according to claim 1 or 2, wherein the light-polarizing element of said light-polarizing film comprises dichroic dyes or polyene linkages.

15. A laminated light-polarizing sheet according to claim 1, wherein the polymeric supporting film or sheet is laminated on the light-polarizing film by hot glueing.

16. A laminated light-polarizing sheet according to claim 1, wherein said polymeric supporting film is laminated on the light-polarizing film by coating said light-polarizing film with a synthetic resin and then curing the same.

17. A laminated light-polarizing sheet according to claim 1, wherein the polymeric supporting film or sheet is bonded on the light-polarizing film.