Heat stable polyphase polyamide compositions and preparation thereof

• US 4,387,184 A
• Filed: 12/05/1980
• Issued: 06/07/1983
• Est. Priority Date: 12/10/1979
• Status: Expired due to Term

• Current Assignee: Rhone-Poulenc Industries
• Original Assignee: Rhone-Poulenc Industries
• Inventors: Coquard, Jean, Goletto, Jean
• Primary Examiner(s): Lieberman, Paul
• Application Number:
  US06/213,666
• Time in Patent Office: 914 Days
• Field of Search: 525/432, 525/420.5, 525/66, 525/92, 525/183, 260/18 N
• US Class Current: 525/183
• CPC Class Codes: C08L 77/00 Compositions of polyamides obtained by reactions forming a carboxylic amide link in the main chain of polyhydrazides C08L79/06; of polyamideimides or polyamide acids C08L79/08; Compositions of derivatives of such polymers

Abstract

Provided are heat-stable polyphase polyamido compositions having improved mechanical properties which comprise (i) from 50 to 99% by weight of a nylon polyamide resin matrix and (ii) from 1 to 50% by weight of a particulate disperse phase comprising a polyamide incompatible with the polyamide resin matrix, and methods for the preparation thereof. Shaped articles comprising said compositions exhibit improved physical properties, particularly with regard to impact strength.

Claims

1. A heat-stable polyphase polyamido composition of matter having enhanced mechanical properties, comprising (i) from 55 to 99% by weight of a nylon polyamide resin matrix, the polyamide resin matrix having a number-average molecular weight of at least 5,000, and (ii) from 1 to 45% by weight of a particulate disperse phase comprising a polyamide sufficiently incompatible with the polyamide resin matrix to provide a polyphase composition, the particulates having a particle size ranging from 0.01 to 10 microns, and the disperse phase comprising a polyamide having a content in amide groups of less than 40% of the amide groups comprising said polyamide matrix resin and the disperse phase having a glass transition temperature of less than 5°

C.

2. The composition of matter as defined by claim 1, comprising from 70 to 90% by weight of the matrix (i), the polyamide resin having a number-average molecular weight in excess of 10,000, from 10 to 30% by weight of the disperse phase (ii) comprising particulates having a particle size ranging from 0.05 to 3μ

, and said polyamide having a glass transition temperature below -10°

C.

3. The composition of matter as defined by claim 1, the polyamide matrix resin being polycaprolactam or polyhexamethylene adipamide.

4. The composition of matter as defined by claim 1, the disperse phase comprising a polyamide prepared from a dimeric acid.

5. The composition of matter as defined by claim 4, the dimeric acid containing at least 36 carbon atoms.

6. The composition of matter as defined by claim 1, the disperse phase comprising a polyamide prepared from a dimeric diamine.

7. The composition of matter as defined by claim 6, the dimeric diamine containing at least 36 carbon atoms.

8. The composition of matter as defined by claim 4, the disperse phase comprising a polyamide prepared from a polyamine comprising an ether group and at least 8 carbon atoms.

9. The composition of matter as defined by claim 4, the disperse phase comprising a polyamide prepared from a secondary bis-primary polyamine.

10. The composition of matter as defined by claim 9, the secondary bis-primary polyamine being bis-hexamethylene triamine.

11. The composition of matter as defined by claim 6, the disperse phase comprising a polyamide prepared from a mixture of a dimeric diamine and a second bis-primary polyamine.

12. The composition of matter as defined by claim 11, the disperse phase comprising a polyamide prepared from a mixture of a dimeric diamine containing at least 36 carbon atoms and bishexamethylenetriamine.

13. The composition of matter as defined by claim 4, the disperse phase comprising a polyamide prepared from a mixture of a dimeric acid and a polyacid having at least 3 functional groups.

14. The composition of matter as defined by claim 13, said polyacid being a trimeric acid.

15. The composition of matter as defined by claim 1, the disperse phase comprising a mixture of a polyamide and a statistical, block or graft copolymer derived from an unsaturated or polyunsaturated monomer containing groups which are reactive toward the polyamide in an amount ranging from 0.5 to 10 mol %, the groups being selected from the group consisting of acid, amino, anhydride, sulphonated and amido groups.

16. The composition of matter as defined by claim 15, the copolymer derived from an unsaturated monomer being a copolymer of ethylene, methacrylic acid or methacrylic esters.

17. A process for the preparation of the composition of matter as defined by claim 1 comprising subjecting a mixture of the polyamide matrix resin and disperse phase polyamide, the polyamide matrix resin and the disperse phase polyamide having a number-average molecular weight in excess of 5,000, to shearing conditions, in a closed system and at a temperature above the melting point of the polyamide matrix resin, sufficient to disperse the disperse phase polyamide in the polyamide matrix resin in the form of particles having a size ranging from 0.01 to 10 microns.

18. The process of claim 17 wherein the number-average molecular weight of the polyamide matrix resin is in excess of 10,000, and the number-average molecular weight of the disperse phase polyamide is in excess of 15,000.

19. The process of claim 17 wherein polycondensation of the polyamide matrix resin, same initially having a number-average molecular weight in excess of 2,000, is completed conjointly with the dispersion of the disperse phase polyamide, in a system equipped for degassing.

20. The process of claim 19 wherein polycondensation of the polyamide matrix resin and the disperse phase polyamide is carried out simultaneously with the dispersion of the disperse phase polyamide.

21. The process of claim 17 wherein polycondensation of the polyamide matrix resin is carried out conjointly with the dispersion of the disperse phase, which is carried out under shear conditions sufficient to result in the disperse phase being dispersed in the form of particles having a size ranging from 0.01 to 10 microns upon polycondensation of the polyamide matrix resin.

22. A shaped article comprising the composition of matter as defined by claim 1.