Selective ion sensitive electrode and method of making it

• US 4,388,165 A
• Filed: 08/31/1981
• Issued: 06/14/1983
• Est. Priority Date: 02/28/1981
• Status: Expired due to Fees

• Current Assignee: Olympus Optical Company Ltd. (Olympus Corporation)
• Original Assignee: Olympus Optical Company Ltd. (Olympus Corporation)
• Inventors: Kamiyama, Takashi, Koshiishi, Kiyozo, Ono, Noriaki, Kato, Yoshimi
• Primary Examiner(s): Kaplan, G. L.
• Application Number:
  US06/298,343
• Time in Patent Office: 652 Days
• Field of Search: 204/195 M, 427/409, 427/405, 427/125, 428/447
• US Class Current: 204/418
• CPC Class Codes: G01N 27/3335 the membrane containing at least one organic component G01N27/3271 takes precedence; aspects concerning the enzyme reagent in enzyme electrodes C12Q1/001
• CPC Class Codes: Y10T 428/31663 As siloxane, silicone or silane

Abstract

A selective ion sensitive electrode is so constructed that an ion exchanger sensitive to a specific ion is formed on a metal electrode, an electric conductive resin electrode or a chlorinated metal electrode to which a signal wire is connected so as to maintain a stable electric connection between the signal wire and the ion exchanger over a long period of time. A layer of a silane coupling agent is used between the electrode member and ion exchanger.

Claims

1. A selective ion sensitive electrode including an ion exchanger selectively sensitive to a specific ion, comprising:

an electrode member to which a signal wire is connected on one side thereof, said member comprised of one of a metal, an electrically conductive resin and a chlorinated metal;

a corrosion resistant conductive thin film formed on the opposite side of said electrode member from said signal wire;

a layer of a silane coupling agent on said corrosion resistant conductive thin film; and

an ion exchanger formed on the surface of said layer of a silane coupling agent.

2. A selective ion sensitive electrode according to claim 1 in which the ion exchanger is formed by the process comprising the steps of applying a solution including at least an ion-exchanger substance, dissolved in a volatile solvent onto the layer of a silane coupling agent and allowing the solvent to evaporate.

3. A selective ion sensitive electrode according to claim 2 in which the solution further comprises a supporting substance selected from the group consisting of polyvinyl chloride and dioctyladipic acid.

4. A selective ion sensitive electrode according to claim 1 further comprising a stem in which the electrode member is held, the stem comprising a substance which is in part merged into the ion exchanger.

5. A selective ion sensitive electrode according to claim 1 in which the electrode member is comprised of a metal and the signal wire is integrally formed with the metal electrode member.

6. A selective ion sensitive electrode according to claim 5, further comprising an insulating member surrounding the signal wire and a metal stem surrounding the insulating member, the metal stem serving to shield the signal wire.

7. A selective ion sensitive electrode according to claim 1 in which the electrode member is a metal.

8. A selective ion sensitive electrode according to claim 7 in which the corrosion resistant conductive thin film is made from a noble metal.

9. A selective ion sensitive electrode according to claim 7 in which the ion exchanger is formed by the process comprising the steps of applying a solution including at least an ion exchange substance dissolved in a volatile solvent onto the conductive thin film and allowing the solvent to evaporate.

10. A selective ion sensitive electrode according to claim 7 in which the surface of the metal electrode member on which the ion exchanger is formed is made rough with a roughness of 1 to 100μ

.

11. A selective ion sensitive electrode according to claim 8 in which the noble metal is selected from the group consisting of gold, silver and platinum.

12. A selective ion sensitive electrode according to claim 10 further comprising a stem in which the electrode member is held, the stem comprising a substance which is in part merged into the ion exchanger.

13. A selective ion sensitive electrode according to claim 1 in which the signal wire is connected directly to the electrode member.

14. A sensitive ion selective electrode according to claim 13 in which the electrode member is comprised of a metal and the signal member is integrally formed with the metal electrode member.

15. A selective ion sensitive electrode according to claim 1, further comprising a housing for supporting said electrode member, said housing being formed from a nonconductive material, said electrode member being contained within an opening within said housing so that said ion exchanger is flush with a surface of said housing.

16. A selective ion sensitive electrode according to claim 15, further comprising an inner housing member for holding said electrode member, said inner housing member being received within said opening.

17. A selective ion sensitive electrode according to claim 16 in which the corrosion resistant conductive thin film is made from a noble metal.

18. A selective ion sensitive electrode according to claim 15 in which said housing is formed as a cylindrical tube adapted to receive a liquid therein, said tube having an inner cylindrical surface, an outer cylindrical surface and an opening in said tube between said inner and outer surfaces, said electrode member being formed to conform to said outer surface adjacent said opening and to cover said opening, said ion exchanger being flush with said inner surface.

19. A selective ion sensitive electrode according to claim 18 in which the electrode member is ring-shaped and extends around the periphery of the cylindrical tube.

20. A selective ion sensitive electrode according to claim 19 in which the corrosion resistant conductive thin film is made of a noble metal selected from the group consisting of gold, silver and platinum.

21. A selective ion sensitive electrode according to claim 18 in which the surface of the electrode member on which the ion exchanger is formed is made rough with a roughness of 1 to 100μ

.

22. A selective ion sensitive electrode according to claim 15 in which the electrode member is a metal.

23. A process of forming a selective ion sensitive electrode comprising the steps of providing an electrode member to which a single wire is connected on one side thereof, said member comprised of one of a metal, an electrically conductive resin and a chlorinated metal, a corrosion resistant conductive thin film formed on the opposite side of said member from said signal wire and a layer of a silane coupling agent on the surface of said corrosion resistant conductive thin film;

applying a solution having an ion exchange substance dissolved in a volatile solvent to the surface of said layer of silane coupling agent; and

allowing the solvent to evaporate to form an ion exchanger on said layer of silane coupling agent.

24. The process of claim 23, further comprising the step of inserting the electrode member into an opening in a stem in which the electrode member is held before applying the solution.

25. The process of claim 24 in which the electrode member is inserted to a depth in the opening so that the ion exchanger formed is flush with a surface of the stem.

26. The process of either of claims 24 or 25 in which the portion of the stem is partly merged into the ion exchanger due to the action of the solvent upon the stem.