Process and apparatus for generation of steam via catalytic combustion

• US 4,388,892 A
• Filed: 01/26/1981
• Issued: 06/21/1983
• Est. Priority Date: 01/26/1981
• Status: Expired due to Term

• Current Assignee: RODY MARC P.N., 8718 ARLINGTON BOULEVARD, FAIRFAX, VA.
• Original Assignee: Frank W. Sudia, Marc P.N. Rody
• Inventors: Sudia, Frank W., Rody, Marc P. N.
• Primary Examiner(s): Favors, Edward G.
• Application Number:
  US06/228,052
• Time in Patent Office: 876 Days
• Field of Search: 122/4 R, 122/4 D, 122/31, 122/28, 431/4, 431/2, 60/39.55
• US Class Current: 122/4.00D
• CPC Class Codes: F22B 1/003 using combustion of hydrogen with oxygen power plants using steam created by combustion of hydrogen with oxygen F01K25/005
• CPC Class Codes: F22B 1/26 Steam boilers of submerged-flame type, i.e. the flame being surrounded by, or impinging on, the water to be vaporised , e.g. water in sprays
• CPC Class Codes: F23C 13/00 Apparatus in which combustion takes place in the presence of catalytic material in a fluidised bed of catalytic particles F23C10/01; radiant gas burners using catalysis for flameless combustion F23D14/18

Abstract

A mixture of fuel and air is introduced onto a catalytic combustion surface, preferably an inert, refractory substrate coated with trace amounts of a catalyst. Combustion is normally initiated by an ignition device, and proceeds spontaneously once the minimum temperature has been reached. Water is introduced directly onto the heated combustion surface, in metered quantities to prevent cooling below the desired minimum combustion temperature, thus generating a continuous flow of steam at a pressure equal to the inlet pressure of the air, fuel and water. The quantities of air, fuel and water may be varied proportionately to produce rapid variation in the volume, temperature and pressure of the steam generated, a function that may be greatly facilitated by the choice of a combustion element having a low thermal mass. Both the catalytic combustion of fuel and the vaporization of inert working fluids can occur over a wide range of temperature and pressure conditions.

Claims

1. A process for vaporizing water via catalytic combustion comprising steps

(a) for reacting a mixture of fuel, oxidizer and water on a catalytic surface, where the catalytic oxidation of the fuel releases thermal energy which vaporizes the water, and where the water and water vapor pass directly across the working surface of the catalyst,

(b) for conducting the water vapor and combustion product gases away from the catalytic element, and

(c) for utilizing the product.

2. A process for vaporizing water as in claim 1, in which the oxidizer used is air.

5. A process for vaporizing water as in claim 1, wherein the mixture of fuel, oxidizer and water is directed to the catalytic element in a combustion chamber.

7. A process for vaporizing water as in claim 5, comprising, in addition, steps for pressurizing the oxidizer, fuel, and water to be directed into the combustion chamber, for injecting the pressurized oxidizer, fuel, and water into the combustion chamber, whereupon the fuel, oxidizer, and water react to produce pressurized water vapor, and for utilizing the pressurized water vapor so produced.

9. A process for vaporizing water as in claims 1, 5, or 7, comprising additional steps for warming the oxidizer, fuel, and water prior to their being directed to the catalytic element.

11. A process for vaporizing water as in claims 1, 5, or 7, comprising additional steps for generating ultrasonic energy and for transmitting the ultrasonic energy into the oxidizer, fuel, and/or water prior to their being directed to the catalytic element, where the ultrasonic energy aids in promoting the mixing of said oxidizer, fuel or water prior to combustion.

13. A process for vaporizing water as in claims 1, 5, or 7, comprising an additional step for catalytic hydrogenation of unsaturated fuels prior to combustion on the catalytic element.

15. A process for vaporizing water as in claim 1, comprising in addition steps for heating the catalytic element to assist the initiation of combustion upon said element.

17. A process for vaporizing water as in claim 1, comprising additional steps for supplying a second fuel of heavier grade, for directing the second fuel to the catalytic element, for substituting the second fuel for the first fuel during the continuance of the catalytic combustion process after the catalytic combustion reaction has reached a temperature that will support efficient combustion of the second fuel, whereupon steam generation may proceed utilizing the second fuel.

19. A process for vaporizing water as in claim 1, comprising additional steps for supplying a fuel-water composition, in the form of a solution or emulsion, for mixing the fuel-water composition with oxidizer, for directing the mixture of oxidizer, fuel, and water to the catalytic element whereupon the fuel is combusted and the water is vaporized by the resulting heat, and for utilizing the steam so produced.

21. A process for vaporizing water in a catalytic combustion steam generator as in claims 5 or 7, comprising additional steps for compressing oxidizer, for regulating the pressure thereof, for introducing the oxidizer into the combustion chamber, whereupon pressurized steam is produced, for delivering a portion of the steam to a steam driven motor which generates mechanical energy, and for transmitting and utilizing a portion of the mechanical energy to carry out the said steps for compressing oxidizer.

23. A process for vaporizing water as in claims 5 or 7, comprising additional steps for utilizing steam in a closed system steam utilization application, for condensing waste steam recovered from said closed system application, for separating and removing exhaust gases and unreacted air components, for recovering and storing the water produced by said condensation and separation steps, and for recirculating said water for reuse in the catalytic combustion steam generator.

27. A process for vaporizing water as in claim 5, comprising additional steps for directing a supply of oxidizer to the catalytic element at a plurality of successive points adjacent to the main flow of other reactants across and through the catalytic element, and for regulating the quantity of oxidizer so directed to the catalytic element, in order to create zones of progressively more complete combustion.

28. A process for vaporizing water as in claim 5, comprising additional steps for directing a supply of fuel to the catalytic element at a plurality of successive points adjacent to the main flow of other reactants across and through the catalytic element, and for regulating the quantity of fuel so directed to the catalytic element.

29. A process for vaporizing water as in claim 5, comprising additional steps for directing a flow of water to the catalytic element at a plurality of successive points adjacent to the main flow of other reactants across and through the catalytic element, and steps for regulating the quantity of water so directed to the catalytic element.

33. A process for vaporizing water in a combustion chamber as in claim 5, comprising additional steps to regulate the flow of oxidizer, fuel, and water being injected into the combustion chamber so as to induce a succession of explosive expansion steam generation states followed alternately by partial vacuum states induced by the rapid exiting of the steam, whereupon the partial vacuum induces a flow of oxidizer into the combustion chamber through a one-way oxidizer valve, and for utilizing the pulsed steam so produced.

35. A process for vaporizing water as in claim 19, comprising an additional step for suspending the fuel in the water by emulsifying or dissolving it to form a fuel-water composition.

3. Apparatus for vaporizing water comprising

(a) a catalytic element,

(b) means for supplying a mixture of fuel, oxidizer and water to said element to support a combustion-vaporization reaction thereon, and

(c) means for utilizing the mixture of water vapor and combustion product gases so produced.

4. Apparatus for vaporizing water as in claim 3 wherein the said means for supplying oxidizer to the catalytic element are adapted to the use of air as an oxidizer.

6. An apparatus for vaporizing water as in claim 3, wherein the apparatus comprises a combustion chamber enclosing therein said catalytic element, and means for supporting said catalytic element within said chamber, with said means for supplying a mixture of fuel, oxidizer and water to the chamber in fluid communication with said chamber, wherein said mixture sustains a combustion-vaporization reaction on the element, and with means for receiving and utilizing the water vapor produced being in fluid communication with said chamber.

8. An apparatus for vaporizing water as in claim 6, wherein the apparatus also comprises means for pressurizing fuel, oxidizer and water, means for injecting said fuel, oxidizer and water under pressure into said combustion chamber containing a catalytic element upon which the fuel and oxidizer combust producing heat which vaporizes the water, and means for utilizing the pressurized water vapor so produced.

10. An apparatus for vaporizing water as in claims 3, 6, or 8, comprising additional means for warming the oxidizer, fuel, and water prior to their being directed to the catalytic element.

12. An apparatus for vaporizing water as in claims 3, 6, or 8, comprising additional means for generating ultrasonic energy and means for transmitting the ultrasonic energy into the oxidizer, fuel, and/or water prior to their being directed to the catalytic element, where the ultrasonic energy aids in promoting the mixing of said oxidizer, fuel or water prior to combustion.

14. An apparatus for vaporizing water as in claims 3, 6, or 8, comprising additionally a hydrogenation catalyst suitable for the hydrogenating of unsaturated hydrocarbon fuel substances, means for supporting said hydrogenation catalyst, means for conducting the unsaturated hydrocarbon fuel substances to said hydrogenation catalyst, means for delivering water to said hydrogenation catalyst, whereupon the unsaturated hydrocarbon fuel is hydrogenated and is broken into smaller, more saturated fuel molecules, means for supplying heat to said hydrogenation catalyst to support the hydrogenation reaction thereon, means for conducting the product to the catalytic element for utilization in catalytic combustion steam generation, means for supplying oxidizer to said catalytic element to support combustion thereon, means for directing water to said catalytic element, which is vaporized thereon, and means for utilizing the water vapor so produced.

16. An apparatus for vaporizing water as in claim 3, comprising additional means for heating the catalytic element to assist the initiation of combustion upon said element.

18. An apparatus for vaporizing water as in claim 3, comprising additional means for supplying a second fuel of heavier grade, and means for directing said second fuel to the catalytic element.

20. An apparatus for vaporizing water as in claim 3, comprising additional means for supplying a fuel-water composition, and means for directing the composition to the catalytic element.

22. An apparatus for vaporizing water in a catalytic combustion steam generator as in claims 6 or 8, comprising additional means for compressing oxidizer, means for regulating the pressure thereof, means for transmitting the oxidizer to the combustion chamber, whereupon pressurized steam is produced, means for transmitting a portion of the steam to a steam driven motor which generates mechanical energy, and means for transmitting a portion of the mechanical energy to operate said means for compressing oxidizer.

24. A process for vaporizing water as in claim 25, comprising an additional step of purifying the recovered water to remove acids in the water resulting from dissolved exhaust gases.

25. An apparatus for vaporizing water as in claims 6 or 8, comprising additional means for utilizing steam in a closed system steam utilization application, means for condensing waste steam recovered from said closed system application, means for separating exhaust gases and unreacted air components, means for recovering and storing the water produced by said means for waste steam condensation and exhaust gas separation, and means for recirculating the water for reuse in the catalytic combustion steam generator.

26. An apparatus for vaporizing water as in claim 25, comprising additional means for purifying the recovered water to remove acids in the water resulting from dissolved exhaust gases.

30. An apparatus for vaporizing water as in claim 6, comprising additional means for directing a supply of oxidizer to the catalytic element at a plurality of successive points adjacent to the main flow of the reactants across and through said catalytic element, and means for regulating the quantity of oxidizer so directed to said catalytic element, in order to create zones of progressively more complete combustion.

31. An apparatus for vaporizing water as in claim 6, comprising additional means for directing a supply of fuel to the catalytic element at a plurality of successive points adjacent to the main flow of other reactants across and through said catalytic element, and means for regulating the quantity of fuel so directed to said catalytic element.

32. An apparatus for vaporizing water as in claim 6, comprising additional means for directing a supply of water to the catalytic element at a plurality of successive points adjacent to the main flow of other reactants across and through said catalytic element, and means for regulating the quantity of water so directed to said catalytic element.

34. An apparatus for vaporizing water as in claim 6, comprising additionally a one-way oxidizer valve placed at the oxidizer inlet to the combustion chamber, and means for regulating the flow of fuel and water so as to induce a succession of explosive expansion steam generation states followed alternately by partial vacuum states induced by the rapid exiting of the steam, whereupon the partial vacuum induces a flow of oxidizer into the combustion chamber through said one-way oxidizer valve, and means for utilizing the pulsed steam so produced.

36. An apparatus for vaporizing water as in claim 20, comprising additionally means for suspending the fuel in the water by emulsifying or dissolving it to form a fuel water composition.