Spheroidal alumina particles and catalysts employing the particles as a support
First Claim
1. A catalyst support comprising spheroidal alumina particles having a total pore volume of about 0.8 to about 1.7 cubic centimeters per gram, a pore volume of about 0.5 to about 1.0 cubic centimeters per gram in pores of 100 to 1000 A. in diameter, a pore volume of about 0.1 to about 0.4 cubic centimeters per gram in pores of 1000 to 10,000 A. in diameter, an attrition loss of less than about 5%, and a compacted bulk density of about 20 to about 36 pounds per cubic foot.
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Abstract
Spheroidal alumina particles have a combination of high macroporosity, surface area, crush strength and low attrition loss and bulk density. The particles are prepared by an improved external gelation oil-drop process. In the process a slurry of alumina, preferably a microcrystalline boehmite-pseudoboehmite intermediate, is prepared in an acidic aqueous medium and droplets of the slurry are passed through air into a column containing an upper body of water-immiscible liquid and ammonia and a lower body of aqueous coagulating agent. Catalysts employing the particles as a support and having catalytic agents distributed at controlled depths in the particle have excellent initial and sustained activity and durability, especially for eliminating pollutants in automotive exhaust streams.
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Citations
20 Claims
- 1. A catalyst support comprising spheroidal alumina particles having a total pore volume of about 0.8 to about 1.7 cubic centimeters per gram, a pore volume of about 0.5 to about 1.0 cubic centimeters per gram in pores of 100 to 1000 A. in diameter, a pore volume of about 0.1 to about 0.4 cubic centimeters per gram in pores of 1000 to 10,000 A. in diameter, an attrition loss of less than about 5%, and a compacted bulk density of about 20 to about 36 pounds per cubic foot.
Specification