Injection moldable poly(ethylene terephthalate)

• US 4,390,649 A
• Filed: 02/18/1982
• Issued: 06/28/1983
• Est. Priority Date: 02/18/1982
• Status: Expired due to Fees

• Current Assignee: Allied Corp. (Honeywell International Inc.)
• Original Assignee: Allied Corp. (Honeywell International Inc.)
• Inventors: Aharoni, Shaul M.
• Primary Examiner(s): Lieberman, Allan
• Assistant Examiner(s): SHORT, PATRICIA A
• Application Number:
  US06/349,781
• Time in Patent Office: 495 Days
• Field of Search: 524/413, 524/434, 524/437, 524/435, 524/167, 524/292, 524/314, 525/176, 260/DIG. 35
• US Class Current: 524/167
• CPC Class Codes: C08K 3/22 of metals
• CPC Class Codes: C08L 67/02 Polyesters derived from dicarboxylic acids and dihydroxy compounds C08L67/06 takes precedence

Abstract

A molding composition of a terephthalate polyester such as PET, a plasticizing material and a crystal nucleating agent. The nucleating agent is a powdered metal hydroxide such as aluminum hydroxide, which raises the T_cc of the composition and permits reduced cycling time and enables higher molecular weight polymer to be used in the molding process.

Claims

1. In a molding composition comprising

a. a thermoplastic, saturated, linear polyester of terephthalic acid,

b. a plasticizing material and

c. a crystal nucleating agent, the improvement which consists in using as the nucleating agent a powdered crystalline metal hydroxide of grain size not exceeding 45 microns, selected from the group of hydrated aluminum hydroxide containing 30±

5% water of hydration, nickel hydroxide, indium hydroxide and copper hydroxide in an amount sufficient to increase the crystallization temperature of an article molded from the polyester composition by at least about 15°

C. with regard to that of the mixture of a and b.

2. A molding composition as described in claim 1, wherein the polyester is selected from the group of poly(ethylene terephthalate), poly(1,4-butylene terephthalate) poly(1,6-hexylene terephthalate) and poly(1,4-cyclohexylidenedimethylene terephthalate), the intrinsic viscosity of said polyester being at least 0.4.

3. A molding composition as described in claim 1, wherein the polyester is poly(ethylene terephthalate) having intrinsic viscosity in the range of about 0.4 to about 1.0.

4. A molding composition as described in claim 1, wherein the nucleating agent is hydrated aluminum hydroxide containing 30±

5% water of hydration.

5. A molding composition as described in claim 1, wherein the plasticizer is present in an amount from about 0.1 to 15% by weight of the polyester resin.

6. A molding composition as described in claim 1, further comprising from 15% to 150% by weight of the polyester of glass fiber reinforcement.

7. A molding composition as described in claim 1, also comprising one or more components selected from the group consisting of fillers, impact modifiers chain extenders, colorants, mold release agents antioxidants, fire retardants and lubricants.

8. A molding composition as described in claim 7 wherein the chain extender is an epoxy resin.

9. A molding composition as described in claim 7 wherein the impact modifier is a copolymer derived from an alpha-olefin and an alpha-olefinic carboxylic acid in which the carboxylic functions have been partially or totally neutralized by metal ions.

10. A molding composition as described in claim 9 wherein the impact modifier is a terpolymer derived from an alpha-olefin, an alpha-olefinic carboxylic acid and an alpha-olefinic carboxylic ester in which the free carboxylic acid functions have been partially or totally neutralized by metal ions.

11. A molding composition as described in claim 10 wherein

a. the terpolymer is derived from ethylene, methacrylic acid and isobutyl methacrylate and

b. from 15 to 70% of the free carboxylic acid groups are neutralized by sodium or zinc ions.

12. A molding composition as described in claim 7 wherein the impact modifier is an acrylonitrile-butadiene-styrene alloy.

13. A molding composition as described in claim 7 wherein the impact modifier is poly(methyl methacrylate).

14. A shaped article of a thermoplastic composition as described in claim 1, 6 or 7.

15. In the process of producing shaped articles of high surface quality and gloss by cooling in a mold a molten thermoplastic polyester composition comprising:

a. a polyester of terephthalic acid with diol selected from the group of ethanediol, 1,4-butanediol, and hexanediol and 1,4-cyclohexanedimethanol or mixtures or copolymers thereof,

b. a plasticizing material and

c. a nucleating agent,

the improvement which comprises using as the nucleating agent a powdered crystalline metal hydroxide of grain size not exceeding 45 microns, selected from the group of hydrated aluminum hydroxide containing 30±

5% water of hydration, nickel hydroxide, indium hydroxide and copper hydroxide in an amount sufficient to increase the crystallization temperature of the polyester composition by at least about 15°

C. with regard to the mixture of a and b.