Reduction of cyclopentadiene from isoprene streams

• US 4,390,742 A
• Filed: 02/22/1982
• Issued: 06/28/1983
• Est. Priority Date: 02/22/1982
• Status: Expired due to Term

• Current Assignee: Goodyear Tire & Rubber Company
• Original Assignee: Goodyear Tire & Rubber Company
• Inventors: Wideman, Lawson G.
• Primary Examiner(s): Gantz, Delbert E.
• Assistant Examiner(s): Pal, A.
• Application Number:
  US06/350,915
• Time in Patent Office: 491 Days
• Field of Search: 585/809, 585/810, 585/820, 585/829, 585/853, 585/854
• US Class Current: 585/854
• CPC Class Codes: C07C 7/1485 oxides; hydroxides; salts C07C7/156 takes precedence

Abstract

A process for reducing the level of cyclopentadiene present in a hydrocarbon stream containing isoprene and cyclopentadiene which involves contacting the stream with an alkali metal hydroxide wherein the reaction product is an insoluble salt of CPD.

Claims

1. A process for reducing the level of cyclopentadiene present in a C-5 hydrocarbon stream containing no carbonyl compounds comprising forming the respective insoluble salt by contacting said stream with an alkali metal hydroxide, said alkali metal hydroxide being selected from the group consisting of sodium hydroxide, potassium hydroxide, and lithium hydroxide.

2. A process according to claim 1 wherein the alkali metal hydroxide is mounted on an inert carrier.

3. A process according to claim 2 wherein said inert carrier is selected from the group comprising oxide of silicon, corundum, celite and aluminum oxide.

4. A process according to claim 1 wherein said stream has an LHSV value of 0.1 to 30.

5. A process according to claim 1 wherein said alkali metal hydroxide is powdered potassium hydroxide.

6. A process according to claim 4 wherein said stream has an LHSV value of 0.48.

7. A process according to claim 1 wherein said stream is at a temperature from 0°

C. to 100°

C.

8. A process for reducing the level of CPD present in a C-5 hydrocarbon stream containing isoprene and CPD comprising contacting said stream with an alkali metal hydroxide wherein said reaction product of CPD and the alkali metal hydroxide is an insoluble salt compound.