Method and apparatus for remotely detecting gases in the atmosphere

• US 4,390,785 A
• Filed: 12/29/1980
• Issued: 06/28/1983
• Est. Priority Date: 12/29/1980
• Status: Expired due to Term

• Current Assignee: E. I. du Pont de Nemours and Company (Corteva, Inc.)
• Original Assignee: E. I. du Pont de Nemours and Company (Corteva, Inc.)
• Inventors: Prober, James M., Faulhaber, Mark E.
• Primary Examiner(s): Smith, Alfred E.
• Assistant Examiner(s): Howell, Janice A.
• Application Number:
  US06/220,997
• Time in Patent Office: 911 Days
• Field of Search: 250/330, 250/334, 250/339, 250/340, 250/343, 356/51, 356/407, 356/416, 356/418
• US Class Current: 250/330
• CPC Class Codes: G01J 5/60 using determination of colour temperature
• CPC Class Codes: G01M 3/38 by using light G01M3/02 takes precedence
• CPC Class Codes: G01N 21/314 with comparison of measurements at specific and non-specific wavelengths dual wavelength spectrometry G01J3/427
• CPC Class Codes: G01N 21/35 using infrared light G01N21/39 takes precedence
• CPC Class Codes: G01N 21/3504 for analysing gases, e.g. multi-gas analysis
• CPC Class Codes: G01N 33/0047 Organic compounds
• CPC Class Codes: G01V 9/007 by detecting gases or particles representative of underground layers at or near the surface analysing earth materials G01N33/24; analysing gases per se G01N

Abstract

Presence and location of infrared radiation-absorbing or emitting gases in the atmosphere can be ascertained by means of an infrared imaging-analyzing means which views a given scene and receives infrared radiation therefrom. Analytic and reference beams are produced, the latter having reduced sensitivity to the gas of interest, and are converted to electric signals, which are processed in real time to provide a signal corresponding to their ratio. This ratio signal is further processed to generate an image, which can be displayed and viewed. This technique is particularly suitable for surveying large areas for seepage of methane or other hydrocarbon gases from underground gas and/or oil deposits.

Claims

1. A method of detecting the presence in the atmosphere of a gas which absorbs or emits infrared radiation within a defined wavelength region and determining its location with respect to at least one fixed background reference point, wherein

(a) a number of points within a circumscribed background area, which are at a temperature different from the average temperature of the intervening atmosphere are viewed by the imaging optics of an imaging-analyzing means having a first sensor means and a second sensor means capable of generating electrical output signals that are responsive to the resulting net radiative flux transmitted through the atmosphere;

the first sensor means having a higher sensitivity and the second sensor means having a lower sensitivity to the gas of interest in the defined infrared wavelength region;

(b) the amplitudes of the output signals generated by said sensor means are ratioed pixel-by-pixel within the defined infrared wavelength region; and

(c) an image signal responsive to the ratio of said output signal amplitudes is produced, said image signal being displayed on a display means, the image indicating the presence of the gas of interest at at least one point within the circumscribed area being surveyed.

2. The method of claim 1 wherein the sensitivity of one of the sensor means to the gas of interest is reduced by placing in the path of infrared radiation reaching said sensor means a gas filter cell containing said gas of interest.

3. The method of claim 1 wherein the sensitivity of one of the sensor means to the gas of interest is altered by placing in the path of infrared radiation reaching said sensor at least one interference filter.

4. A method of claim 1 wherein the amplitudes of the output signals are ratioed continuously.

5. The method of claim 1 wherein the amplitudes of the output signals are ratioed repeatedly.

6. The method of claim 1 wherein the analysis is performed in real time.

7. The method of claim 1 wherein the gas of interest is a hydrocarbon.

8. The method of claim 7 wherein the gas is a member of the class consisting of methane and ethylene.

9. The method of claim 7 wherein the imaging-analyzing means is transported in an aircraft over areas of gas seepage.

10. The method of claim 1 wherein the presence and location of at least two gases is determined in turn, an appropriate filter being placed in the path of one of the infrared beams before it reaches the sensor means.

11. The method of claim 10 wherein two time-synchronized single channel imaging-analyzing means view the same scene, one of said means providing analytic data and the other reference data.

12. The method of claim 10 wherein a dual channel imaging-analyzing means equipped with a beam splitter which does not discriminate by wavelength is used to provide analytic and reference infrared radiation beams.

13. The method of claim 10 wherein the filter is a gas filter.

14. The method of claim 10 wherein the filter is an interference filter.

15. An apparatus for detecting the presence and determining the location of an infrared radiation-absorbing or emitting gas in the atmosphere, said apparatus comprising:

(1) an infrared imaging-analyzing means capable of viewing a circumscribed background area, receiving infrared radiation therefrom, producing in real time an analytic beam and a reference beam, and sensing said beams with two separate sensor means, one sensor means having greater sensitivity to the gas of interest than the other;

(2) signal processing means for ratioing pixel-by-pixel the amplitudes of said reference and analytic signals; and

(3) means for producing an image corresponding to the results of said ratioing.

16. An apparatus of claim 15 wherein analytic and reference infrared beams are produced by means of a beam splitter which does not discriminate by wavelength.

17. An apparatus of claim 15 which contains two separate time-synchronized single-channel imaging-analyzing means viewing the same circumscribed area.

18. The apparatus of claim 15 wherein the signal processing means comprises an automatic gain control circuitry for maintaining constant the long term amplitude values of the analytic and reference signals.

19. The apparatus of claim 15 wherein the signal processing means comprises an analog-to-digital converter for generating a point-by-point ratio of the amplitudes of the reference and analytic signals.

20. An apparatus of claim 15 wherein the values of the analytic and reference signals are biased by constants C₁ and C₂, which are voltage values obtained when the gas of interest is absent from the scene being viewed.

21. An apparatus of claim 20 wherein the values of C₁ and C₂ can be varied by means of the output of a radiometer.

22. An apparatus of claim 15 wherein the removal of a portion of infrared radiation from the reference beam is accomplished by placing in the path of said beam a filter.

23. The apparatus of claim 22 wherein the filter is a gas filter.

24. The apparatus of claim 22 wherein the filter is an interference filter.