Helichromic compounds and displays
First Claim
1. A composition consisting essentially of a nematic liquid crystal material and, in admixture therewith, an organic, nonionic, nonliquid-crystalline helichromic compound, said helichromic compound being soluble in said nematic liquid crystal material, and said helichromic compound being a dichroic dye and having the general formula
wherein;
Q is a radical selected from the group consisting of azo, azo-stilbene, benzothiazolyl polyazo, methine, azo-methine, merocyanine and methine arylidene radicals;
Z is an organic group capable of imparting helical ordering characteristics to said mixture of nematic liquid crystal and helichromic compound; and
n is an integer having a value of 1 or greater.
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Accused Products
Abstract
A composition for use in liquid crystal display devices, consisting essentially of a nematic liquid crystal material and a helichromic compound possessing both a chromophoric moiety and a helical ordering moiety. The helical ordering moiety is capable of helically ordering the mixture of liquid crystal material and helichromic compound. The helichromic compound can be utilized in conventional "guest-host" and "twist nematic" displays as well as in unique helichromic displays. When used in helichromic displays, the helichromic compounds eliminate after-image scattering and enable the display to be operated at reduced voltages.
41 Citations
33 Claims
- 1. A composition consisting essentially of a nematic liquid crystal material and, in admixture therewith, an organic, nonionic, nonliquid-crystalline helichromic compound, said helichromic compound being soluble in said nematic liquid crystal material, and said helichromic compound being a dichroic dye and having the general formula
- space="preserve" listing-type="equation">Q--Z).sub.n
wherein; Q is a radical selected from the group consisting of azo, azo-stilbene, benzothiazolyl polyazo, methine, azo-methine, merocyanine and methine arylidene radicals; Z is an organic group capable of imparting helical ordering characteristics to said mixture of nematic liquid crystal and helichromic compound; and n is an integer having a value of 1 or greater. - View Dependent Claims (6, 7, 8, 9, 13, 14, 15, 16, 19)
- 2. A composition consisting essentially of a nematic liquid crystal material and, in admixture therewith, an organic, nonionic, nonliquid-crystalline helichromic compound, said helichromic compound being soluble in said nematic liquid crystal material, and said helichromic compound being a dichroic dye and having the general formula
- space="preserve" listing-type="equation">Q--Z).sub.n
wherein; Q is an anthraquinone radical; n is 1 and Z is an organic group capable of imparting helical ordering characteristics to said mixture of nematic liquid crystal material and helichromic compound, and Z is substituted in the 1, 4, 5, position of Q.
- 3. A composition consisting essentially of a nematic liquid crystal material and, in admixture therewith, an organic, nonionic, nonliquid-crystalline helichromic compound, said helichromic compound being soluble in said nematic liquid cyrstal material, and said helichromic compound being a dichroic dye and having the general formula
- space="preserve" listing-type="equation">Q--Z).sub.n
wherein; Q is an anthraquinone radical; n is 2; and Z is an organic group capable of imparting helical ordering characteristics to said mixture of nematic liquid crystal material and helichromic compound, and Z is substituted in the 1 and 4, or 1 and 8 positions of Q. - View Dependent Claims (10)
- 4. A composition consisting essentially of a nematic liquid crystal material and, in admixture therewith, an organic, nonionic, nonliquid-crystalline helichromic compound, said helichromic compound being soluble in said nematic liquid crystal material, and said helichromic compound being a dichroic dye and having the general formula
- space="preserve" listing-type="equation">Q--Z).sub.n
wherein; Q is an anthraquinone radical; Z is an organic group capable of imparting helical ordering characteristics to said mixture of nematic liquid crystal and helichromic compound, and Z includes a linking group linking it to said Q, wherein said linking group is selected from the group consisting of --CH═
N--, --CH═
CH--, --N═
N--, --O--, --CH2)p, --O--CH2)p, --C--CH3)2 --, ##STR96## --C6 H10 --, phenyl groups, naphthyl groups and combinations thereof, wherein p is 1, 2, 3, 4 or 5, and Z is substituted in the 1, 4, 5 or 8 position of Q or any combination thereof; andn is an integer having a value of 1 or greater. - View Dependent Claims (11)
- 5. A composition consisting essentially of a nematic liquid crystal material and, in admixture therewith, an organic, nonionic, nonliquid-crystalline, helichromic compound, said helichromic compound being soluble in said nematic liquid crystal material, and said helichromic compound being a dichroic dye having the general formula
- space="preserve" listing-type="equation">Q--Z).sub.n
wherein; Q is an anthraquinone heterocyclic dicarboximide radical; n is an integer equal to 1; and Z is an organic group capable of imparting helical ordering characteristics to said mixture of nematic liquid crystal and helichromic compound, and Z is substituted on the nitrogen of said heterocyclic dicarboximide radical. - View Dependent Claims (12)
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17. A liquid crystal display device which is responsive to the absence or presence of an electric field, said device having no auxiliary polarizers and comprising a layer of a nematic liquid crystal composition and two conductive electrodes positioned, respectively, adjacent opposing surfaces of said layer, said nematic liquid crystal composition consisting essentially of a nematic liquid crystal material and, in admixture therewith, an organic, nonionic, nonliquid-crystalline helichromic compound, said helichromic compound being soluble in said nematic liquid crystal material, said helichromic compound being a dichroic dye, said helichromic compound comprising at least one helical ordering moiety capable of imparting helical ordering characteristics to said mixture of nematic liquid crystal and helichromic compound, and said helichromic compound being present in said mixture in an amount effective to allow said mixture to substantially absorb unpolarized light incident thereon in the absence of an electric field and to substantially transmit unpolarized light incident thereon in the presence of an electric field.
- View Dependent Claims (18, 20, 21, 22, 23, 24, 25, 26, 27, 28, 29, 30, 31)
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22. The liquid crystal display device of claim 21 wherein n is an integer having a value between 1 and 4.
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23. The liquid crystal display device of claim 21 wherein Z is an organic group having an asymmetric carbon atom.
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24. The liquid crystal display device of claim 23 wherein Z is selected from the group consisting of a (+)-2-methylalkyl group, a (+)-3-methylalkyl group, a (+)-citronellyl group, a (+)-camphanyl group, a (+)-3-methylcyclohexyl group, and a (+)-α
- -methylbenzyl group.
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25. The liquid crystal display device of claim 21 wherein Q is a radical selected from the group consisting of azo, azo-stilbene, benzothiazolyl polyazo, methine, azo-methine, merocyanine and methine arylidene radicals.
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26. The liquid crystal display device of claim 31 wherein Q is an anthraquinone radical and Z is substituted in the 1, 4, 5 or 8 position of Q, or any combination thereof.
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27. The liquid crystal display device of claim 21 wherein Q is an anthraquinone heterocyclic dicarboximide radical and Z is substituted on the nitrogen of said heterocyclic dicarboximide radical.
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28. The liquid crystal display device of claims 26 wherein Z additionally comprises a linking group linking said Z organic group group to said Q, wherein said linking group is selected from the group consisting of --CH═
- N--, --CH═
CH--, --N═
N--, --NH--, --N(alk)--, --O--, --S--, CH2 --p, --O--CH2 --p, --C(CH3)2 --, ##STR101## --C6 H10 --, phenyl groups and naphthyl groups and combinations thereof, wherein p is 1, 2, 3, 4 or 5.
- N--, --CH═
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29. The liquid crystal display device of claim 21 wherein Q additionally comprises one or more ballasting groups selected from the group consisting of NH2, --CH2 --p CH3, --O--(CH2 --p CH3, --CH(CH3)2, ##STR102## C6 H11, phenyl groups, naphthyl groups and combinations thereof, wherein p is 0, 1, 2, 3 or 4.
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30. The liquid crystal display device of claim 21 wherein Q comprises at least one aromatic ring having one or more substituents independently selected from the group consisting of lower alkyl, lower alkoxy, F, Cl, Br, NO2, NH(alk), N(alk)2, OH, CN, CF3, and CH3, substituted thereon.
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31. The liquid crystal display device of claim 17 wherein said helichromic compound is selected from the group consisting of ##STR103##
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32. A composition consisting essentially of a nematic liquid crystal material and, in admixture therewith, an organic, nonionic, nonliquid-crystalline helichromic compound, said helichromic compound being soluble in said nematic liquid crystal material, and said helichromic compound being a dichroic dye and having the general formula Q(Z)n
wherein: -
Q is an anthraquinone radical; n is 3; and Z is an organic group capable of imparting helical ordering characteristics to said mixture of nematic liquid crystal material and helichromic compound, and Z is substituted in the 1, 4 and 5 positions of Q.
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33. A composition consisting essentially of a nematic liquid crystal material and, in admixture therewith, an organic, nonionic, nonliquid-crystalline helichromic compound, said helichromic compound being soluble in said nematic liquid crystal material, and said helichromic compound being a dichroic dye and having the general formula Q(Z)n
wherein: -
Q is an anthraquinone radical; n is 4; and Z is an organic group capable of imparting helical ordering characteristics to said mixture of nematic liquid crystal material andhelichromic compound, and Z is substituted in the 1, 4, 5 and 8 positions of Q.
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Specification