Diaphragms for alkaline water electrolysis and method for production of the same as well as utilization thereof

• US 4,394,244 A
• Filed: 07/07/1980
• Issued: 07/19/1983
• Est. Priority Date: 07/07/1979
• Status: Expired due to Term

• Current Assignee: Kernforschungsanlage Julich Gesellschaft mit beschrankter Haftung
• Original Assignee: Kernforschungsanlage Julich Gesellschaft mit beschrankter Haftung
• Inventors: Mergel, Jurgen, Divisek, Jiri
• Primary Examiner(s): Edmundson, F.
• Application Number:
  US06/166,448
• Time in Patent Office: 1,107 Days
• Field of Search: 204/295, 204/296, 204/286, 204/282
• US Class Current: 204/295
• CPC Class Codes: C25B 1/04 by electrolysis of water
• CPC Class Codes: C25B 13/04 characterised by the material
• CPC Class Codes: Y02E 60/36 Hydrogen production from non-carbon containing sources, e.g. by water electrolysis

Abstract

A diaphragm of porous sinter material for alkaline water electrolysis characterized by a porous sinter metal oxidized at least partially to metal oxide. A frame structure of the sinter body is provided especially wire net. The base metal of the sinter body is formed by nickel, iron or copper. The method includes forming a porous metal sinter body and oxidizing the same at elevated temperature in oxygen-containing atmosphere. The method for production of nickel oxide diaphragms furthermore includes applying to a nickel net a pasty mass of nickel powder containing a binder and burning. Applying in a thin layer as by brushing nickel powder of a particle size of about 1 to 10 mm in a rubber solution in toluene upon a carrier, especially a nickel net, and this arrangement is subjected to sintering at 700° to 1,000° C. for a time or duration of 10 to 20 minutes in inert or reducing atmosphere especially in hydrogen and the sinter body which is obtained is subjected to roasting in air at 1000° C. to 1200° C. up to three hours, especially for a time duration in a range of between ten and forty minutes. The diaphragms are produced with a thickness in a range of approximately 1 mm, especially in a range of approximately 0.3 mm to 0.7 mm. Utilization of the diaphragm includes electrolysis cells with active porous nickel electrode fixed on the diaphragm in a sandwich manner of construction.

Claims

1. A diaphragm for alkaline water electrolysis and made of a porous sinter material, comprising a porous sinter metal oxidized at least partially to metal oxide of partial oxidation in structure thereof, the partial oxidation penetrating the whole structure resulting in a sufficiently isolating but mechanically consistent body.

2. A diaphragm according to claim 1, comprising a sinter body comprising a frame structure of a wire net covered with nickel powder mass.

3. A diaphragm according to claim 2, in which said sinter body is formed of a base metal which is one from a group consisting of nickel, iron or copper.

4. A diaphragm according to claim 3, comprising active porous nickel electrodes means fixed on the diaphragm in a sandwich manner of construction for electrolysis cells.

5. A diaphragm for alkaline water electrolysis, comprising:

a metal frame oxidized at least partially to metal oxide, and

a layer of sintered nickel formed from sintered nickel powder covering the frame completely to form a diaphram which is at least partially oxidized throughout and which is mechanically rigid and electrically insulated.

6. The diaphragm according to claim 5 wherein the metal frame is made of nickel.

7. The diaphragm according to claim 5 wherein the frame is configured as a nickel net.

8. The diaphragm of claim 7 wherein the nickel powder has a particle size in a range of approximately 1 um to 10 um and is deposited in a thin layer upon the nickel net, using a rubber solution in toluene as a binding medium;

wherein the powder and net are sintered in a temperature range between 700°

C. to 1000°

C. for a time duration in the range of 10 minutes to 40 minutes in an inert or reducing atmosphere, and wherein the resulting sinter body is heated up to three hours in air at a temperature ranging between 1000°

C. to 1200°

C.

9. The diaphragm according to claim 8 wherein the nickel powder has a particle size in a range between 2 um to 3 um.

10. The diaphragm according to claim 9 in which said sintering occurs in hydrogen and said heating is effected during a time interval ranging between 10 minutes to 20 minutes.

11. The diaphragm according to claim 7 wherein the diaphragm has a thickness up to approximately 1 mm.

12. The diaphragm of claim 7 wherein the diaphragm has a thickness in the range of 0.3 mm to 0.7 mm.