Method for lithium anode and electrochemical cell fabrication

• US 4,398,346 A
• Filed: 10/23/1981
• Issued: 08/16/1983
• Est. Priority Date: 10/23/1981
• Status: Expired due to Fees

• Current Assignee: Medtronic Incorporated (Medtronic Plc)
• Original Assignee: Medtronic Incorporated (Medtronic Plc)
• Inventors: Helgeson, William D., Underhill, Lloyd J.
• Primary Examiner(s): Larson, Lowell A.
• Assistant Examiner(s): Scherer, Jonathan L.
• Application Number:
  US06/314,210
• Time in Patent Office: 662 Days
• Field of Search: 29/623.1, 29/623.5, 429/191, 429/192, 429/197, 429/199, 429/213, 429/215, 429/218, 427/58, 427/384
• US Class Current: 29/623.5
• CPC Class Codes: H01M 4/12 of consumable metal or alloy electrodes use of alloy compositions as active materials H01M4/38
• CPC Class Codes: H01M 6/182 with halogenide as solid electrolyte
• CPC Class Codes: H01M 6/50 Methods or arrangements for servicing or maintenance, e.g. for maintaining operating temperature constructional details of current conducting connections for detecting conditions inside cells or batteries, e.g. details of voltage sensing terminals, H01M50/569
• CPC Class Codes: Y10T 29/49108 Electric battery cell making
• CPC Class Codes: Y10T 29/49115 including coating or impregnating

Abstract

Method of preparing lithium anodes contacted with organic materials prior to association of the anode with a cathode material wherein the contacted anode is first subjected to a heat treatment. Upon incorporation of the improved anode into an electrochemical battery or cell and association of the heat treated anode with a suitable cathode material, the cell may be discharged under controlled conditions for a short time prior to its usual "burn-in" discharge.

Claims

1. A method of preparing an anode for an electrochemical cell comprising the steps of:

providing a lithium anode element having an operative surface area to be associated with a cathode;

contacting at least the operative surface area of the anode element with organic material, and

heating the anode element and organic material together to a temperature between at least about 260°

F. and the melting temperature of the organic material.

2. The method of claim 1 wherein the anode element is held at the heating temperature for a predetermined period of time.

3. The method of claim 2 wherein the time is at least about one hour.

4. The method of claim 2 wherein the anode is cooled to room temperature after the heating step before any further preparation steps are carried out.

5. The method of claim 1 wherein the anode and contacting organic material are incorporated into a subassembly including an open cell container prior to the heating step and the entire subassembly is heated.

6. The method of claim 1 wherein the heating is by means of a forced air oven.

7. The method of claim 6 wherein the oven if preheated to a temperature between about 260°

F. and about 310°

F., the anode and contacting organic material are placed in the oven and heated to substantially the temperature at which the oven is maintained over a period of at least about 45 minutes to one hour and thereafter maintained at that temperature for at least about one hour.

8. The method of claim 7 wherein the anode element is removed from the oven following the heating step and cooled to room temperature before any further assembly operations are performed involving it.

9. The method of claim 1 wherein the organic material is in the form of a coating on the anode element.

10. The method of claim 1 wherein the organic material is in the form of a multi-layer coating on the anode element.

11. The method of claim 1 wherein the organic material is in the form of a self-supporting sheet.

12. The method of claim 1 wherein the heating temperature is about 295°

F.±

about 10°

F.

13. The method of claim 12 wherein the heating is accomplished over a period of time of about two hours ±

15 minutes.

14. The method of claim 1 wherein the heating temperature is between about 260°

F. and 310°

F.

15. The method of claim 1 wherein the organic material is a polyvinylpyridine polymer.

16. The method of claim 15 wherein the organic material is poly-2-vinylpyridine.

17. The method of claim 1 wherein the organic material is poly-2-vinylpyridine in the form of a coating on the operative surface area of the anode element and the heating temperature to which the coated anode is heated is about 295°

F.±

about 10°

F.

18. The method of claim 17 wherein the heating is for a period of time of about 2 hours ±

15 minutes.

19. The method of claim 17 wherein the coated anode element is held at the heating temperature for at least about one hour.

20. The method of claim 17 wherein the coated anode is incorporated into a subassembly including a cell container prior to the heating step and the entire subassembly is heated.

21. A method of making an electrochemical cell wherein the anode includes an operative surface area and the cathode comprises a charge-transfer complex material, comprising the steps:

providing a lithium anode element having an operative surface to be associated with a cathode in a cell;

contacting at least the operative surface of the anode element with organic material;

heating the anode element and organic material to a temperature between at least about 260°

F. and the melting temperature of the organic material;

providing a cathode including a charge-transfer complex material, and

assembling the anode and cathode in electrochemically operative relationship.

22. The method of claim 21 wherein a container is provided for the cell components, the anode and the contacting organic material are assembled into the container following which they are heated, and the cathode material is subsequently melted and poured into the container.

23. The method of claim 22 wherein the assembly is cooled prior to the addition of the cathode material.

24. The method of claim 21 wherein the cell is shorted across a resistor of about 0.1 to 0.2 ohms for a predetermined time following its assembly.

25. The method of claim 24 wherein the discharge is accomplished in two steps, the first step being discharge at a relatively high rate for a relatively short period of time;

the second step being discharge at a relatively low rate for a relatively long period of time.

26. The method of claim 25 wherein the first step discharge is carried out across a resistor of about 0.1 to 0.2 ohms for a period of about one hour.

27. The method of claim 21 wherein the cathode comprises the reaction product of a mixture of polyvinylpyridine and iodine.

28. The method of claim 27 wherein the polyvinylpyridine is poly-2-vinylpyridine.

29. The method of claim 28 wherein the iodine and poly-2-vinylpyridine are present in a weight ratio greater than about 30:

1.

30. The method of claim 29 wherein the weight ratio is about 50:

1.

31. The method of claim 29 wherein the weight ratio is greater than 50:

1.

32. The method of claim 29 wherein the weight ratio is about 100:

1.

33. The method of claim 29 wherein the anode element is held at the heating temperature for a period of time.

34. The method of claim 33 wherein the time is at least about one hour.

35. The method of claim 33 wherein the anode is cooled to room temperature after the heating step before any further preparation steps are carried out on it.

36. The method of claim 21 wherein the anode and contacting organic material are incorporated into a subassembly including an open cell container prior to the heating step and the entire subassembly is heated.

37. The method of claim 21 wherein the heating is by means of a forced air oven.

38. The method of claim 37 wherein the oven is preheated to a temperature between about 260°

F. and about 310°

F., the anode and contacting organic material are placed in the oven and heated to substantially the temperature at which the oven is maintained over a period of about 45 minutes to about one hour and thereafter maintained at that temperature for about one hour.

40. The method of claim 21 wherein the organic material is in the form of a coating on the anode element.

41. The method of claim 21 wherein the organic material is in the form of a multi-layer coating on the anode element.

42. The method of claim 21 wherein the organic material is in the form of a self-supporting sheet.

43. The method of claim 21 wherein the heating temperature is about 295°

F.±

about 10°

F.

44. The method of claim 21 wherein the heating temperature is between about 260°

F. and 310°

F.

45. The method of claim 21 wherein the organic material is a polyvinylpyridine polymer.

46. The method of claim 45 wherein the organic material is poly-2-vinylpyridine.

47. The method of claim 21 wherein the organic material is poly-2-vinylpyridine in the form of a coating on the operative surface area of the anode element and the heating temperature to which the coated anode is heated is about 295°

F.±

about 10°

F.

48. The method of claim 47 wherein the coated anode element is held at the heating temperature for at least about one hour.

49. The method of claim 47 wherein the coated anode is incorporated into a subassembly including a cell container prior to the heating step and the entire subassembly is heated.

50. The method of claim 47 wherein the cell is discharged across a resistor of about 0.1 to 0.2 ohms for a predetermined time following its assembly.

51. The method of claim 50 wherein the discharge is accomplished in two steps, the first step being discharge at a relatively high rate for a relatively short period of time;

the second step being discharge at a relatively low rate for a relatively long period of time.

52. The method of claim 47 wherein the cathode comprises the reaction product of a mixture of polyvinylpyridine and iodine.

53. The method of claim 47 wherein the polyvinylpyridine is poly-2-vinylpyridine.

54. The method of claim 47 wherein the iodine and poly-2-vinylpyridine are present in a weight ratio greater than about 30:

1.

55. The method of claim 47 wherein the weight ratio is about 50:

1.

56. The method of claim 47 wherein the weigth ratio is greater than 50:

1.

57. The method of claim 47 wherein the weight ratio is about 100:

1.

58. The method of claim 47 wherein the cell is discharged across a resistor of about 0.1 to 0.2 ohms for a predetermined time following its assembly.

59. The method of claim 54 wherein the resistance is about 0.1 ohms and the time is about one hour.

60. The method of claim 47 wherein the discharge is accomplished in two steps, the first step being discharge at a relatively high rate for a relatively short period of time;

the second step being discharge at a relatively low rate for a relatively long period of time.

61. The method of claim 47 wherein the first step discharge is carried out across a resistor of about 0.1 to 0.2 ohms for a period of about one hour.

39. The method of claim 39 wherein the anode element is removed from the oven following the heating step and cooled to room temperature before any further assembly operations are performed involving it.