Metal-composite bonding

• US 4,398,659 A
• Filed: 01/11/1982
• Issued: 08/16/1983
• Est. Priority Date: 12/12/1980
• Status: Expired due to Fees

• Current Assignee: United Technologies Corporation (Raytheon Technologies Corporation d/b/a RTX)
• Original Assignee: United Technologies Corporation (Raytheon Technologies Corporation d/b/a RTX)
• Inventors: Richter, Mark A.
• Primary Examiner(s): Robinson, Ellis P.
• Application Number:
  US06/338,824
• Time in Patent Office: 582 Days
• Field of Search: 428/336, 428/334, 428/335, 428/367, 428/389, 428/390, 428/426, 428/428, 428/902, 428/663, 428/666, 428/672, 428/630, 428/631, 428/939, 428/433, 156/306.6, 156/182, 156/307.7, 156/308.2, 156/325, 228/121, 228/122, 228/124
• US Class Current: 228/124.1
• CPC Class Codes: B32B 15/08 of synthetic resin
• CPC Class Codes: C03C 14/002 the non-glass component being in the form of fibres, filaments, yarns, felts or woven material
• CPC Class Codes: C03C 2214/02 Fibres; Filaments; Yarns; Felts; Woven material
• CPC Class Codes: C03C 27/046 of metals, metal oxides or metal salts only
• CPC Class Codes: Y10T 428/2918 including free carbon or carbide or therewith [not as steel]
• CPC Class Codes: Y10T 428/30 Self-sustaining carbon mass or layer with impregnant or other layer

Abstract

A method of bonding a graphite fiber reinforced glass matrix composite to a metal structure comprising depositing a layer of eutectic alloy metal component to the bond surfaces of the metal and composite followed by placing the thus treated bond surfaces of the metal and composite together with a layer of eutectic alloy containing such metal therebetween. The metal-bond-composite is then heated to melt the alloy and bond the composite to the metal. Articles formed by such a process are also described. The method has particular utility in bonding cooling channel containing metal bases to graphite-glass composite laser mirrors.

Claims

1. A method of bonding a high strength, thermally stable, graphite fiber reinforced glass matrix composite to a metal surface, the glass matrix having a low coefficient of thermal expansion and the graphite fiber having a highly negative axial coefficient of thermal expansion comprising depositing a thin layer of a eutectic alloy metal component to the bond surfaces of the composite and the metal, inserting a thin layer of eutectic alloy containing the metal component between the bond surfaces, placing the metal and composite bond surfaces together with the eutectic alloy in between and raising the temperature of the metal-alloy-composite to a temperature sufficient to melt the alloy and bond the composite.

2. The method of claim 1 wherein the metal component layers are deposited in thicknesses up to 25 microns.

3. The method of claim 1 wherein the bond produced has a strength of at least 2800 psi (1.9×

10⁷ NT/M²).

4. The method of claim 1 wherein the graphite fibers have a modulus of elasticity of at least 531 GPa, a tensile strength of at least 1724 MPa and a density of about 1.96 gm/cm³.

5. The method of claim 1 wherein the composite contains 40% to 70% by volume graphite fibers having orientation in the composite of 0°

and 90°

;

0°

, 45° and

90°

;

0°

, 60° and

120°

;

are discontinuous;

or have fiber orientation substantially perpendicular to the bond.

6. The method of claim 1 wherein the metal surface is molybdenum.

7. The method of claim 1 wherein the eutectic alloy metal component is gold and the eutectic alloy is a gold-tin mixture.