Radiation cured abrasion resistant coatings of pentaerythritol acrylates and cellulose esters on polymeric substrates

• US 4,399,192 A
• Filed: 10/23/1981
• Issued: 08/16/1983
• Est. Priority Date: 01/07/1980
• Status: Expired due to Fees

• Current Assignee: Panelographic Corporation
• Original Assignee: Panelographic Corporation
• Inventors: Russell, Raymond J.
• Primary Examiner(s): Bleutge, John C.
• Assistant Examiner(s): KOECKERT JR, ARTHUR
• Application Number:
  US06/314,128
• Time in Patent Office: 662 Days
• Field of Search: 204/159.12, 428/412, 428/481, 428/510
• US Class Current: 428/412
• CPC Class Codes: C08F 220/20 of polyhydric alcohols or phenols , e.g. 2-hydroxyethyl (meth)acrylate or glycerol mono-(meth)acrylate
• CPC Class Codes: C08F 251/02 on to cellulose or derivatives thereof
• CPC Class Codes: Y10T 428/31507 Of polycarbonate
• CPC Class Codes: Y10T 428/3179 Next to cellulosic
• CPC Class Codes: Y10T 428/31797 Next to addition polymer from unsaturated monomers
• CPC Class Codes: Y10T 428/31891 Where addition polymer is an ester or halide
• CPC Class Codes: Y10T 428/31906 Ester, halide or nitrile of addition polymer

Abstract

Actinic radiation curable coating compositions are provided applicable to many substrates comprising a pentaerythritol-based polyacrylate or polymethacrylate such as pentaerythritol tetraacrylate, a cellulose ester such as cellulose acetate butyrate and a photoinitiator. The compounds are preferably applied to the substrate by spraying a solution of the composition in one or more solvents selected from the group consisting of lower alcohols and ester, ketones having from 3 to 7 carbon atoms and lower alkyl Cellosolves, and removing the solvents.

Upon curing in air the compositions form extremely abrasion resistant coatings on the substrate and are also characterized by being scratch resistant and resistant to attack by chemical and organic solvents.

Claims

1. A product comprising a substrate selected from the group consisting of polyacrylics, polyvinyls, polycarbonates and polyesters having coated thereon a cured, abrasion resistant, optical coating composition consisting essentially of a pentaerythritol-based polyacrylate selected from the group consisting of a pentaerythritol polyacrylate, a pentaerythritol polymethacrylate, a dipentaerythritol polyacrylate, a dipentaerythritol polymethacrylate, a tripentaerythritol polyacrylate and a tripentaerythritol polymethacrylate, a cellulose ester comprising the reaction product of cellulose with at least one organic carboxylic acid having from 2 to 4 carbon atoms or nitric acid and a photoinitiator, wherein the weight ratio of said polyacrylate to said ester is from about 6 to 1 to about 100 to 1.

2. A product comprising a substrate selected from the group consisting of polyacrylics, polyvinyls, polycarbonates and polyesters having coated thereon a cured, abrasion resistant, optical coating composition comprising a pentaerythritol based polyacrylate selected from the group consisting of a pentaerythritol polyacrylate, a pentaerythritol polymethacrylate, a dipentaerythritol polyacrylate, a dipentaerythritol polymethacrylate, a tripentaerythritol polyacrylate and a tripentaerythritol polymethacrylate, a cellulose acetate butyrate containing on the average from about 15% to 50% butyryl groups, from about 1% to 30% acetyl groups and from 1% to 5% hydroxyl groups and a photoinitiator, wherein the weight ratio of said polyacrylate to said butyrate is from about 6 to 1 to about 100 to 1.

3. A product comprising a substrate selected from the group consisting of polyacrylics, polyvinyls, polycarbonates and polyesters having coated thereon a cured, abrasion resistant, optical coating composition comprising a pentaerythritol-based polyacrylate selected from the group consisting of a pentaerythritol polyacrylate, a pentaerythritol polymethacrylate, a dipentaerythritol polyacrylate, a dipentaerythritol polymethacrylate, a tripentaerythritol polyacrylate and a tripentaerythritol polymethacrylate, a cellulose acetate butyrate containing on the average 37% butyryl groups, 13% acetyl groups and 2% hydroxy groups and having a viscosity in Poises of from 64 to 124 at 25°

C. in a solution comprising 20 wt. % cellulose acetate butyrate, 72 wt. % acetone and 8 wt. % ethyl alcohol and a photoinitiator wherein the ratio of said tetraacrylate to said cellulose acetate butyrate is from about 6 to 1 to 100 to 1.