Heat storage material

• US 4,400,287 A
• Filed: 01/28/1982
• Issued: 08/23/1983
• Est. Priority Date: 03/09/1981
• Status: Expired due to Term

• Current Assignee: Mitsubishi Denki Kabushiki Kaisha (Mitsubishi Electric Corporation)
• Original Assignee: Mitsubishi Denki Kabushiki Kaisha (Mitsubishi Electric Corporation)
• Inventors: Kimura, Hiroshi, Kai, Junjiro
• Primary Examiner(s): Kittle, John E.
• Assistant Examiner(s): Wax, Robert A.
• Application Number:
  US06/343,767
• Time in Patent Office: 572 Days
• Field of Search: 252/70, 165/10 A, 165/104.17, 165/DIG. 4, 126/400
• US Class Current: 252/70
• CPC Class Codes: C09K 5/063 Materials absorbing or liberating heat during crystallisation; Heat storage materials
• CPC Class Codes: Y10S 165/902 Heat storage

Abstract

A heat storage material comprises NaCH₃ COO.3H₂ O as a main component and a nucleating agent comprising 95 to 10 wt. % of anhydrous sodium acetate and 5 to 90 wt. % of at least one of the other sodium salts selected from the group consisting of Na₃ PO₄, Na₂ HPO₄, NaH₂ PO₄, NaNH₄ PO₄.4H₂ O, Na₅ P₃ O₁₀, C₆ H₅ Na₂ PO₄.2H₂ O, NaBO₂.2H₂ O, Na₂ B₄ O₇.10H₂ O, Na₂ C₂ O₄, NaBr, NaCl, CH₂ (COONa)₂.H₂ O, (CHCOONa)₂.H₂ O, (CH₂ COONa)₂.6H₂ O, HOC(CH₂)₂ (COONa)₂.2H₂ O, CH₃ (CH₂)₂ COONa, CH₃ (CH₂)₆ COONa, HOOCCH(NH₂)(CH₂)₂ COONa.H₂ O sodium oleate, and sodium stearate.

Claims

1. A heat storage material which comprises NaCH₃ COO.3H₂ O as a main component and a nucleating agent comprising 95 to 10 wt.% of anhydrous sodium acetate and 5 to 90 wt.% of at least one other sodium salt selected from the group consisting of Na₃ PO₄, Na₂ HPO₄, NaH₂ PO₄, NaNH₄ HPO₄.4H₂ O, Na₅ P₃ O₁₀, C₆ H₅ Na₂.2H₂ O, NaBO₂.2H₂ O, Na₂ B₄ O₇.10H₂ O, Na₂ C₂ O₄, NaBr, NaCl, CH₂ (COONa)₂.H₂ O, (CHCOONa)₂.H₂ O, (CH₂ COONa)₂.6H₂ O, HOC(CH₂)₂ (COONa)₃.2H₂ O, CH₃ (CH₂)₂ COONa, CH₃ (CH₂)₆ COONa, HOOCCH(NH₂)(CH₂)₂ COONa.H₂ O, sodium oleate, and sodium stearate.

2. The heat storage material according to claim 1 wherein said nucleating agent further comprises a thermoplastic organic material as a binder.

3. The heat storage material according to claim 2 wherein said thermoplastic organic material is a natural vegetable or animal wax which has a melting point of 60°

C. or higher.

4. The heat storage material according to claim 2 wherein said thermoplastic organic material is a synthetic wax.

5. The heat storage material according to claim 2 wherein said thermoplastic organic material is a plastic resin selected from the group consisting of polyethylene, polypropylene, polystyrene, acrylic resin and polyvinyl chloride.

6. The heat storage material according to claim 2 wherein said anhydrous sodium acetate, said other sodium salt, said thermoplastic organic material and a network structured support are bonded in one-piece by a hot-press.

7. The heat storage material according to claim 6 wherein said network structured support is made of a plastic or a metal.

8. The heat storage material according to claim 6 wherein said network structured support is embedded in a mixture of anhydrous sodium acetate, the other sodium salt and said thermoplastic organic material.

9. The heat storage material according to claim 6 wherein two sheets of said network structured support are placed on both surfaces in a sandwich structure.

10. The heat storage material according to claim 6 wherein said network structured support covers all surfaces of said molded product.

11. The heat storage material according to claim 6, wherein the mesh of the network structured support has a diameter ranging from 50 to 5 mm.

12. The heat storage material according to claim 6 wherein said network structured support is fibrous material dispersed in the mixture of anhydrous sodium acetate, the other sodium salt and said thermoplastic organic material.

13. The heat storage material according to claim 12 wherein said fibrous material is at least one selected from the group consisting of metallic fiber, glass fiber, other inorganic fiber, carbon fiber and heat resistant organic fibers.

14. A heat storage material which comprises NaCH₃ COO.3H₂ O having incorporated therein a molded product obtained by hot-pressing a mixture of anhydrous sodium acetate;

at least one other sodium salt selected from the group consisting of Na₃ PO₄, Na₂ HPO₄, NaH₂ PO₄, NaNH₄ HPO₄.4H₂ O, Na₅ P₃ O₁₀, C₆ H₅ Na₂ PO₄.2H₂ O, NaBO₂.2H₂ O, Na₂ B₄ O₇.10H₂ O, Na₂ C₂ O₄, NaBr, NaCl, CH₂ (COONa)₂.H₂ O, (CHCOONa)₂.H₂ O, (CH₂ COONa).6H₂ O, HOC(CH₂)₂ (COONa)₃.2H₂ O, CH₃ (CH₂)₂ COONa, CH₃ (CH₂)₆ COONa, HOOCCH(NH₂)(CH₂)₂ COONa.H₂ O, sodium oleate, and sodium stearate; and

a thermoplastic organic material.

15. The heat storage material according to claim 14 wherein said thermoplastic organic material is a powder having a diameter of 1 mm or less.

16. The heat storage material according to claim 14 wherein the pressure in said hot-pressing is 10 kg/cm² or higher.

17. The heat storage material according to claim 14 wherein the temperature in said hot-press is the melting point of said thermoplastic organic material or lower.

18. The heat storage material according to claim 6 or 14, wherein said NaCH₃ COO.3H₂ O further comprises 5 to 20 wt. % of NaHCOO.3H₂ O or 5 to 15 wt. % of NaBr.2H₂ O.