Economic recovery of ethylene and/or propylene from low concentration feeds

• US 4,401,450 A
• Filed: 09/11/1981
• Issued: 08/30/1983
• Est. Priority Date: 09/11/1980
• Status: Expired due to Fees

• Current Assignee: Linde AG (Linde Plc)
• Original Assignee: Linde AG (Linde Plc)
• Inventors: Schramm, Walter
• Primary Examiner(s): Sever, Frank
• Application Number:
  US06/301,261
• Time in Patent Office: 718 Days
• Field of Search: 62/17, 62/24, 62/27, 62/28, 62/38, 62/39, 62/13, 62/12
• US Class Current: 62/631
• CPC Class Codes: B01D 53/1406 Multiple stage absorption
• CPC Class Codes: B01D 53/1418 Recovery of products
• CPC Class Codes: B01D 53/1487 Removing organic compounds
• CPC Class Codes: C07C 11/02 Alkenes
• CPC Class Codes: C07C 7/005 Processes comprising at least two steps in series
• CPC Class Codes: C07C 7/11 by absorption, i.e. purification or separation of gaseous hydrocarbons with the aid of liquids

Abstract

C₂ -C₃ olefins are recovered from a low concentration gaseous feedstream, e.g. a Fischer-Tropsch waste gas. In a first process stage, the weight percent concentration of the olefins is enriched to at least about 25%. One specific enrichment technique includes scrubbing, preferably 2-stage scrubbing, with hydrocarbon scrubbing agents. Another technique comprises condensation of the olefin in regenerators and absorbing same in a purge phase. The resultant enriched stream, in any case, is then subjected to conventional low temperature separation to recover relatively pure individual streams of ethylene and propylene.

Claims

1. A process for recovering C₂ -C₄ olefins from a gaseous feedstream obtained from a Fischer-Tropsch waste gas containing about 2-3 mol % ethylene or propylene, said process comprising in a first process stage, scrubbing said gaseous feedstream with a C₄ -C₈ liquid hydrocarbon, to absorb said olefin therein and recovering from said liquid hydrocarbon a gaseous stream, the weight percent concentration of said olefins in said gaseous stream being at least about 25%;

and in a second process stage, recovering said olefins from said gaseous stream by a low-temperature separation, and wherein said Fischer-Tropsch waste gas is subjected to a carbon dioxide separating step before entering the first stage.

2. A process according to claim 1, wherein the olefins are enriched in the first process stage to more than 35 mol-%.

3. A process according to claim 1, said gas scrubbing stage being a two-stage scrubbing process conducted with a temperature which is lower in the second scrubbing stage than in the first scrubbing stage, differing scrubbing media being employed in the two scrubbing stages, which scrubbing media are regenerated separately from each other and are recycled into the respective scrubbing stages.

4. A process according to claim 3, wherein the scrubbing media employed are, in the first scrubbing stage, C₄ - or higher hydrocarbons and, in the second scrubbing stage, C₆ - or higher hydrocarbons, the second stage scrubbing media having a higher normal boiling point than said first stage.

5. A process according to claim 4, wherein the scrubbing medium in the first scrubbing stage is butane and the scrubbing medium in the second scrubbing stage is hexane.

6. A process according to claim 4, wherein in the first scrubbing stage, C₃ - and higher hydrocarbons are substantially quantitatively scrubbed out and, in the second scrubbing stage, C₂ -hydrocarbons are substantially quantitatively scrubbed out.

7. A process according to claim 4, wherein in the first scrubbing stage, C₃ - and higher hydrocarbons are scrubbed out at -20°

C. and, in the second scrubbing stage, C₂ -hydrocarbons are scrubbed out at -40°

C.

8. A process according to claim 4, the hydrocarbons in both scrubbing stages being scrubbed out at approximately the same pressures ranging between 10 and 20 bar.

9. A process according to claim 4, further comprising stripping C₃ -hydrocarbons from loaded scrubbing medium of the first scrubbing stage, withdrawing remaining scrubbing medium, heating said remaining scrubbing medium to evolve C₄ - or higher hydrocarbons out and utilizing resultant evolved gas for said stripping of the C₃ -hydrocarbons.

10. A process according to claim 9, wherein said stripping of C₃ -hydrocarbons from the scrubbing medium of the first scrubbing stage is conducted in a C₃ /C₄ -separating column, a second separating column for higher hydrocarbons being placed underneath said C₃ /C₄ separating column, the vapors from this second separating column rising through the liquid in the C₃ /C₄ -separating column and functioning as reboiler vapor.

11. A process for recovering C₂ -C₄ olefins from a gaseous feedstream obtained from a Fischer-Tropsch waste gas containing 2-3% ethylene or propylene, said process comprising in a first process stage partially condensing said feedstream in at least one of several cyclically operated and interconnected regenerators to condense out olefins in said regenerator and then removing said condensed out olefins therefrom as a gaseous stream having a weight percent concentration of said olefins of at least 25%;

and in a second process stage recovering said olefins from said gaseous stream by a low temperature separation, and wherein said Fischer-Tropsch waste gas is subjected to a carbon dioxide separating step prior to entering the first stage.

12. A process according to claim 11, wherein at least three regenerators are employed.

13. A process according to claim 11, wherein the feedstream is a gaseous stream consisting essentially of components having a lower boiling point than the olefins, and comprising substantially entirely condensing the olefins and any corresponding paraffins during a loading phase of the regenerators while the gaseous feedstream flows therethrough, and revaporizing said olefins and any corresponding paraffins by passing a purge gas through said regenerator, and conducting resultant purge gas containing the olefins to the second process stage.

14. A process according to claim 13, wherein said gaseous feedstream is cooled during a loading phase to a temperature at which the C₂ -hydrocarbons are condensed to an extent of at least 95%.

15. A process according to claim 13, wherein a partial stream of uncondensed feedstream withdrawn from the loading phase is utilized as the purge gas stream.

16. A process according to claim 15, further comprising engine expanding said purge gas stream to provide make-up refrigeration for the regenerators.

17. A process according to claim 13, further comprising engine expanding of at least one portion of the uncondensed gaseous feedstream withdrawn from the loading phase to provide make-up refrigeration for said regenerators.

18. A process according to claim 13, wherein purge gas pressure is 0.1-2.0 bar.

19. A process according to claim 13, wherein the gaseous feedstream in the first process stage is under a pressure of between 5 and 15 bar.

20. A process according to claim 11, wherein the olefins are enriched in the first process stage to more than 35 mol-%.