Method and apparatus for treating hydrocarbon and halogenated hydrocarbon contaminated ground and ground water

• US 4,401,569 A
• Filed: 07/09/1981
• Issued: 08/30/1983
• Est. Priority Date: 07/09/1981
• Status: Expired due to Term

• Current Assignee: Groundwater Decontamination Systems Incorporated
• Original Assignee: Groundwater Decontamination Systems Incorporated
• Inventors: Snyder, Harold, Mazzacca, Alfred J., Jhaveri, Vidyut
• Primary Examiner(s): Castel, Benoit
• Application Number:
  US06/281,773
• Time in Patent Office: 782 Days
• Field of Search: 405/128, 405/129, 405/36, 210/610, 210/611, 210/747, 210/170, 210/617, 210/622, 210/901, 210/908, 435/281, 435/262, 166/246
• US Class Current: 210/610
• CPC Class Codes: B09C 1/10 microbiologically, biologically or by using enzymes
• CPC Class Codes: C02F 3/04 using trickle filters
• CPC Class Codes: C02F 3/046 Soil filtration
• CPC Class Codes: C02F 3/34 characterised by the microorganisms used
• CPC Class Codes: Y02W 10/10 Biological treatment of water, waste water, or sewage
• CPC Class Codes: Y10S 210/901 Specified land fill feature, e.g. prevention of ground water fouling

Abstract

A method and apparatus for treating ground and ground water contaminated with hydrocarbon and halogenated hydrocarbon compounds. Treatment of contaminated water removed from the ground is accomplished by microorganisms which consume the contaminants. Growth of microorganisms is enhanced under controlled conditions by addition of nutrients and gases such as oxygen, nitrogen, carbon dioxide or a combination of these and other gases to the contaminated water. Treated water carrying microorganisms, nutrients and gases is returned for recirculation through the contaminated area of ground to leach out and biodegrade the contaminants deposited in the ground. Microorganism activity is also enhanced in the ground by injection of nutrients and oxygen or other gases into the ground and ground water in the contaminated area.

Claims

1. A method of treating hydrocarbon-contaminated ground water to reduce the level of contamination comprising:

(a) removing ground water from a location proximate to, and down gradient of ground water flow through, an area of ground containing hydrocarbon contamination;

(b) treating the removed ground water with nutrients and gases for a period of time sufficient to reduce the level of hydrocarbon contamination and to enhance the growth of hydrocarbon consuming microorganisms in the removed ground water, said nutrients and gases being suitable for enhancing the growth of hydrocarbon-consuming microorganisms and for reducing the level of contamination; and

then;

(c) returning the treated water containing microorganisms, nutrients and gases to the ground at a position upgradient of ground water flow through the contaminated area toward said removal location; and

(d) adding gases into the ground of the contaminated area.

2. The method of claim 1 wherein the ground water is removed from and returned to locations comprising trenches dimensioned to substantially isolate said ground water flowing through said contaminated area.

3. The method of claim 1 wherein the removed ground water is treated with nutrients and gases in a containment area, said treated removed ground water being held in said containment area for a period of time and under conditions sufficient to increase the bacteria count in the removed water and to accelerate the biodegradation process.

4. The method of claim 3 wherein ambient conditions are maintained in said containment area.

5. The method of claim 4 wherein the removal and return positions are trenches positioned to substantially isolate the flow of water through the contaminated ground from the surrounding ground.

6. The method of claim 3 wherein the biodegradation process in said containment area is permitted under conditions of temperature to optimize said biodegradation process.

7. The method of claim 1 wherein substantially all ground water flowing through the contaminated area of ground is removed.

8. The method of claim 1 including the step of removing some of the microorganisms and other sediment prior to returning the treated water to the ground.

10. The method in claim 1 or 9 wherein the microorganisms used for biodegradation are naturally occuring in the contaminated ground.

11. The method of claim 1 or 9 wherein the microorganisms used for biodegradation are introduced from sources other than those naturally occuring in the contaminated ground.

12. The method of claims 1 or 9 wherein the hydrocarbon contaminate is a halogenated hydrocarbon.

13. The method of claim 1 or 9 wherein said gases are one or more of the group air, oxygen, nitrogen and carbon dioxide.

9. A method of treating an area of ground contaminated by hydrocarbon compounds comprising:

(a) removing water from a location down gradient of the contaminated ground;

(b) treating the removed water with gases and nutrients for a period time sufficient to enhance the growth of hydrocarbon-consuming microorganisms and reduce the level of contaminants; and

then

(c) returning the treated water to the ground at a position upgradient of ground water flow through the contaminated ground in an amount sufficient to raise the ground water level in the contaminated area to a level at which all of the contaminated ground is contacted;

(d) injecting gases into ground water in the contaminated area; and

(e) allowing said returned and additional water to flow through the contaminated area toward said removal location.

14. The method of claim 9 wherein additional nutrients are added to the treated water.

15. The method of claim 9 wherein gas is injected into the ground water at locations throughout the contaminated area of ground.

16. The method of claim 9 wherein a sufficient amount of treated water is returned to the ground to raise the level of the ground water to the surface of the contaminated area.

17. The method of claim 16 wherein additional water is added to the ground with the treated water to raise the level of the ground water to the surface.

18. The method of claim 9 wherein additional water is added to the ground with the treated water to raise the level of the ground water to the surface.

19. The method of claim 9 including step of removing some of the microorganisms and other sediment prior to returning the treated water to the ground.

20. Apparatus for treating hydrocarbon-contaminated ground water with microorganisms to cause biodegradation of the hydrocarbon contaminants comprising:

(a) means for removing hydrocarbon contaminated ground water from an area which is contaminated, said means being capable of extracting substantially all water flowing through said contaminated ground;

(b) means for treating said removed water with nutrients and gases to increase the biodegradation activity of the microorganisms;

(c) means for settling solid material from said treated water;

(d) means for adding nutrients and gases to said treated water;

(e) means for recirculating the nutrient-laden treated water to a position proximate the contaminated area, said proximate position chosen so that said water will flow through the contaminated area toward the removal means.

21. The apparatus of claim 20 wherein the means for removing hydrocarbon contaminated ground water comprises one or more trenches dimensioned and positioned proximate to said area of contaminated ground, said trenches provided with wells connected to a pumping system for removing water from said trenches.

22. The apparatus of claim 20 wherein the means for treating the removed water comprises an enclosed vessel connected to said means for removing said hydrocarbon contaminated ground water.

23. The apparatus of claim 22 wherein the vessel has a gas distribution system and an opening through which to add nutrients, said gas system capable of aerating the entire volume of the vessel.

24. The apparatus of claim 20 wherein the means for settling solid material comprises a settling tank having a fluid connection to said means for treating.

25. The apparatus of claim 20 wherein the means for adding nutrients to said treated water comprising a nutrient addition tank injection system for nutrients.

26. The apparatus of claim 25 wherein the means for adding gas to the treated water comprises gas sparger units associated with the nutrient injection system.

27. The apparatus of claim 20 wherein the means for recirculating treated water comprises a pumping and piping system to transport water from the settling means to a location proximate to the contaminated area.

29. The apparatus for treating hydrocarbon contaminated ground water of claim 20 or 28 wherein the hydrocarbon contaminate is a halogenated hydrocarbon.

30. The apparatus of claim 21 wherein the means for transferring removed water comprises a header connecting the wells in the removal trenches, a pump operatively connected to the header and a pipeline extending from the header to the treatment area.

28. Apparatus for treating hydrocarbon-contaminated ground water with microorganisms to reduce the level of contamination, comprising:

(a) means for removing substantially all water which has percolated through an area of ground in which contaminants are present from a location proximate said area;

(b) means for transferring said removed water with hydrocarbon contaminants to a separate treatment area;

(c) means for treating said removed water by addition of nutrients and gas to cause an increased growth of microorganisms capable of biodegrading said hydrocarbon contaminants;

(d) means for settling the treated water;

(e) means for adding nutrients and gases to said treated water;

(f) means for transferring said nutrient-carrying water to a position proximate said contaminated ground such that natural or directed flow of water through said ground will carry said nutrient-carrying water through the area of contaminated ground to the removal means; and

(g) means for injecting said treated nutrient-carrying water and gases into the ground at said position.

31. The apparatus of claim 28 wherein the means for injecting the treated water into the ground comprises a trench positioned proximate the contaminated ground, said trench being dimensioned to accommodate the quantity of treated water being returned and having an injection pipe positioned within the trench.

32. The apparatus of claim 28 wherein the means for injecting gas into the ground comprises a gas sparger unit connected to a well point within the injection trench.