High efficiency continuous separation process

• US 4,402,832 A
• Filed: 08/12/1982
• Issued: 09/06/1983
• Est. Priority Date: 08/12/1982
• Status: Expired due to Term

• Current Assignee: UOP Des Plaines IL A NY General Partnership
• Original Assignee: UOP Llc (Honeywell International Inc.)
• Inventors: Gerhold, Clarence G.
• Primary Examiner(s): Adee, John
• Application Number:
  US06/407,680
• Time in Patent Office: 390 Days
• Field of Search: 210/696, 210/659, 55/67, 55/197, 127/46.2
• US Class Current: 210/659
• CPC Class Codes: B01D 15/1828 characterized by process features
• CPC Class Codes: B01D 2215/023 Simulated moving beds
• CPC Class Codes: B01D 2215/028 Co-current flow
• CPC Class Codes: B01D 2259/40005 using rotary valves
• CPC Class Codes: B01D 2259/41 using plural beds of the same adsorbent in series
• CPC Class Codes: B01D 53/04 with stationary adsorbents B01D53/025 takes precedence
• CPC Class Codes: B01D 53/0423 Beds in columns
• CPC Class Codes: B01D 53/0446 Means for feeding or distributing gases
• CPC Class Codes: C07C 15/08 Xylenes
• CPC Class Codes: C07C 7/13 by molecular-sieve technique
• CPC Class Codes: C13K 13/007 Separation of sugars provided for in subclass C13K C13K3/00 takes precedence

Abstract

A process for separating an extract component from a raffinate component contained in a feed mixture. A unidirectional fluid flow system is maintained through a series of separating units through which the components travel at different rates. A component concentration distribution is established within the system of units and divided into specific zones. Feed and displacement fluid are passed into the inlets of two of the units and extract and raffinate are taken as the entire streams from outlets of two of the units all at appropriate points on the component concentration distribution. Other inlets and outlets of the various units lying in the same zone are interconnected. At the appropriate times the inlets and outlets are shifted so as to simulate movement of the units in a direction co-current with the fluid flow and thereby enable the inlets and outlets to continually lie in the appropriate zones.

Claims

1. A process for separating an extract component from a raffinate component contained in a feed mixture comprising the steps of:

(a) maintaining a unidirectional fluid flow system through a series of separating units in which said components have differential rates of travel due to selective retardation or acceleration of each of said components in each of said units, each of said units having a fluid inlet and a fluid outlet;

(b) passing said feed mixture into one of said fluid inlets and a displacement fluid into another of said fluid inlets, said displacement fluid being capable of displacing said components from said separating units;

(c) establishing within a system comprising said fluid flow system a component concentration distribution, zones of which comprise, sequentially, the highest purity displacement fluid (zone I), extract component diluted with displacement fluid (zone II), concentrated extract component (zone III), extract and raffinate component mixture with the extract component being the major component (zone IV), extract and raffinate component mixture with the raffinate component being the major component (zone V), concentrated raffinate component (zone VI), and displacement fluid diluted with raffinate component (zone VII), each of said zones II, IV, V and VII having associated with it one of said fluid inlets and one of said fluid outlets, zone I having the fluid inlet for displacement fluid associated with it and each of zones III and VI having associated with it a fluid outlet, said feed mixture being passed through a fluid inlet the locus of which is at least proximate to the point on said component concentration of distribution where the relative proportions of the extract and raffinate components are the same as that occurring in the feed mixture;

(d) withdrawing an extract stream comprising the entire flow from the fluid outlet of zone III, and withdrawing a raffinate stream comprising the entire flow from the fluid outlet of zone VI;

(e) passing the entire stream from each of the fluid outlets of said zones II, IV, V and VII to a corresponding fluid inlet, the locuses of each said outlet and corresponding inlet being within the same zone of said component concentration distribution; and

(f) periodically simultaneously effecting the following shifting of said inlets and outlets;

the feed mixture fluid inlet to what prior to the shift was the inlet of zone V, the inlet of zone V to what had been the inlet of zone VII, the inlet of zone VII to what had been the inlet of zone I, the inlet of zone I to what had been the inlet of zone II, the inlet of zone II to what had been the inlet of zone IV, the inlet of zone IV to what had been the feed mixture inlet, the outlet of zone II to what had been the outlet of zone III, the outlet of zone III to what had been the outlet of zone IV, the outlet of zone IV to what had been the outlet of zone V, the outlet of zone V to what had been the outlet of zone VI, and the outlet of zone VI to what had been the outlet of zone VII, and the outlet of zone VII to what had been the outlet of zone II, said shifting being effected prior to the progression through said units of said component concentration distribution to the extent that the composition of the inlet or outlet streams to or from any zone becomes inconsistent with the desired composition of that zone.

2. The process of claim 1 wherein the flow rates of the fluid streams to said fluid inlets and from said fluid outlets are adjusted to provide the desired transition compositions of each inlet and outlet stream at the start and end of each flow period between said shifting.

3. The process of claim 1 wherein said separating units comprise columns at least partially packed with adsorbent having adsorptive selectivity for said extract component as compared to said raffinate component, there being at least one of said columns for each said separating unit, said displacement fluid comprising a desorbent capable of effecting desorption of said extract component from said adsorbent, said feed mixture being contacted with said adsorbent at adsorption conditions and said desorbent being contacted with said adsorbent at desorption conditions.

4. The process of claim 3 wherein said fluid flow system is in liquid phase and said adsorption and desorption conditions comprise temperature and pressures which effect said liquid phase.

5. The process of claim 4 wherein a top portion of each column comprises a compressible vapor phase, thereby enabling an accumulation or reduction of the liquid inventory of said column as desired depending on the particular portion of said component concentration distribution of which said column comprises a part at the time in question.

6. The process of claim 1 wherein the following correspondence exists between the inlets and outlets of said units:

(a) the inlet and outlet streams of a first separating unit comprises the feed mixture inlet and zone II outlet, respectively;

(b) the inlet and outlet streams of a second separating unit comprises the inlet to zone IV and zone VII outlet, respectively;

(c) the inlet and outlet streams of a third separating unit comprises the inlet to zone II and zone VI outlet respectively;

(d) the inlet and outlet streams of a fourth separating unit comprises the inlet to zone I and zone V outlet, respectively;

(e) the inlet and outlet streams of a fifth separating unit comprises the inlet to zone VII and zone IV outlet, respectively; and

(f) the inlet and outlet streams of a sixth separating unit comprises the inlet to zone V and zone III outlet, respectively.

7. The process of claim 1 wherein the following correspondence exists between the inlets and outlets of said units:

(a) the inlet and outlet streams of a first separating unit comprises the feed mixture inlet and zone III outlet, respectively;

(b) the inlet and outlet streams of a second separating unit comprises the inlet to zone IV and zone II outlet, respectively;

(c) the inlet and outlet streams of a third separating unit comprises the inlet to zone II and the zone VII outlet respectively;

(d) the inlet and outlet streams of a fourth separating unit comprises the inlet to zone I and zone VI outlet, respectively;

(e) the inlet and outlet streams of a fifth separating unit comprises the inlet to zone VII and zone V outlet, respectively; and

(f) the inlet and outlet streams of a sixth separating unit comprises the inlet to zone V and zone IV outlet, respectively.

8. The process of claim 1 wherein the following correspondence exists between the inlets and outlets of said units:

(a) the inlet and outlet streams of a first separating unit comprises the feed mixture inlet and zone IV outlet, respectively;

(b) the inlet and outlet streams of a second separating unit comprises the inlet to zone IV and zone III outlet, respectively;

(c) the inlet and outlet streams of a third separating unit comprises the inlet to zone I and the zone VII outlet respectively;

(d) the inlet and outlet streams of a fourth separating unit comprises the inlet to zone VII and zone VI outlet, respectively, there being at least one additional separating unit having fluid flow comprising (e) a unit for which the inlet and outlet streams comprise the inlet and outlet, respectively, to zone II;

or (f) a unit for which the inlet and outlet streams comprise the inlet and outlet, respectively, to zone V.

9. The process of claim 1 wherein the following correspondence exists between the inlets and outlets of said units:

(a) the inlet and outlet streams of a first separating unit comprises the feed mixture inlet and zone V outlet, respectively;

(b) the inlet and outlet streams of a second separating unit comprises the inlet to zone II and zone III outlet, respectively;

(c) the inlet and outlet streams of a third separating unit comprises the inlet to zone I and the zone II outlet respectively;

(d) the inlet and outlet streams of a fourth separating unit comprises the inlet to zone V and zone VI outlet, respectively, there being at least one additional separating unit having fluid flow comprising (e) a unit for which the inlet and outlet streams comprise the inlet and outlet, respectively, to zone IV or (f) a unit for which the inlet and outlet streams comprise the inlet and outlet, respectively, to zone VII.

10. The process of claim 1 wherein the following correspondence exists between the inlets and outlets of said units:

(a) the inlet and outlet streams of a first separating unit comprises the feed mixture inlet and zone VI outlet, respectively;

(b) the inlet and outlet streams of a second separating unit comprises the inlet to zone IV and zone V outlet, respectively;

(c) the inlet and outlet streams of a third separating unit comprises the inlet to zone II and the zone IV outlet respectively;

(d) the inlet and outlet streams of a fourth separating unit comprises the inlet to zone I and zone III outlet, respectively;

(e) the inlet and outlet streams of a fifth separating unit comprises the inlet to zone VII and zone II outlet, respectively; and

(f) the inlet and outlet streams of a sixth separating unit comprises the inlet to zone V and zone VII outlet, respectively.

11. The process of claim 1 wherein the following correspondence exists between the inlets and outlets of said units:

(a) the inlet and outlet streams of a first separating unit comprises the feed mixture inlet and zone VII outlet, respectively;

(b) the inlet and outlet streams of a second separating unit comprises the inlet to zone IV and zone VI outlet, respectively;

(c) the inlet and outlet streams of a third separating unit comprises the inlet to zone II and the zone V outlet respectively;

(d) the inlet and outlet streams of a fourth separating unit comprises the inlet to zone I and zone IV outlet, respectively;

(e) the inlet and outlet streams of a fifth separating unit comprises the inlet to zone VII and zone III outlet, respectively; and

(f) the inlet and outlet streams of a sixth separating unit comprises the inlet to zone V and zone II outlet, respectively.