Piezoelectric/pyroelectric elements

• US 4,405,402 A
• Filed: 10/10/1980
• Issued: 09/20/1983
• Est. Priority Date: 10/12/1979
• Status: Expired due to Term

• Current Assignee: Marconi Holdings Company Limited
• Original Assignee: Marconi Holdings Company Limited
• Inventors: Quilliam, Robert M.
• Primary Examiner(s): Wityshyn, Michael G.
• Application Number:
  US06/195,772
• Time in Patent Office: 1,075 Days
• Field of Search: 156/83, 156/273.7, 156/274.4, 156/274.8, 156/275.5, 156/308.2, 156/311, 156/275.7, 310/800, 29/25.35
• US Class Current: 156/273.7
• CPC Class Codes: H10N 30/045 by polarising
• CPC Class Codes: H10N 30/098 Forming organic materials
• CPC Class Codes: H10N 30/857 Macromolecular compositions
• CPC Class Codes: Y10S 310/80 Piezoelectric polymers, e.g. PVDF
• CPC Class Codes: Y10T 29/42 Piezoelectric device making

Abstract

Piezoelectric and pyroelectric elements made from polarized plastics substances such as polyvinylidene fluoride are of considerable interest in a number of fields. Unfortunately, they also suffer from a number of not insignificant drawbacks. Specifically, the maximum thickness of fully-polarized plastics film obtainable is often not sufficient to give the desired sensitivity.

A very satisfactory thick piezoelectric/pyroelectric element can, however, be made from these plastics films if, instead of using a single film which is itself thick, there is used a laminar stack of individually thin polarizable plastics films each such film being essentially in face-to-face contact with its two neighbors, and there being no significant gas space/pockets between any two adjacent films, the element being made by a method in which: the required number of films of the unpolarized but polarizable plastics substance is assembled together in the form of a multilayer sandwich adjacent individual films of which are essentially in face-to-face contact; the assembly is heated to a temperature somewhat below the deflection temperature of the plastics substance; while still hot, a polarizing electric field is applied across the assembly, from end face to end face; and while still applying the polarizing field, the assembly is allowed to cool down.

Claims

1. A method for the construction of a piezoelectric/pyroelectric element comprising an electrically-polarised laminar stack of individually thin polarisable plastics films, wherein each polarisable plastics film is essentially in face-to-face contact with its two neighbours, there being no significant gas space/pockets between any two adjacent films, in which method:

(a) the required number of films of the unpolarised but polarisable plastics substance is assembled together in the form of a multilayer sandwich adjacent individual films of which are essentially in face-to-face contact;

(b) the assembly is heated to a temperature somewhat below the deflection temperature of the plastics substance;

(c) while still hot, a polarising electric field is applied across the assembly, from end face to end face;

(d) while still applying the polarising field, the assembly is allowed to cool down; and

(e) after assembly but before cooling adjacent individual films of the assembly are bonded together.

2. A method as claimed in claim 1, in which there are from 6 to 20 individual plastics films (or sheets) in the stack.

3. A method as claimed in claim 1, in which the plastics substance used to make the films from which the stack is formed is poly(vinyl difluoride).

4. A method as claimed in claim 1, in which the thickness of the individual films used to make the stack is from 15 to 50 micron.

5. A method as claimed in claim 1, in which the stack is constructed as two "half" stacks joined with the face of the film at one end of one "half" stack joined, by a central internal electrode, to the face of the film at the opposing end of the other "half" stack.

6. A method as claimed in claim 1, which is effected under a pressure across the stack'"'"'s end faces of the order of from 1 to 5 tons per square inch (roughly from 200 to 1500 kg/cm²).

7. A method as claimed in claim 1, in which the individual films are bonded together by means of a glue.

8. A method as claimed in claim 7, in which the glue is a solvent-thinned nitrile rubber-based glue.