Method of making electromechanical transducers using improved flexible composite piezoelectric material

• US 4,407,054 A
• Filed: 10/28/1980
• Issued: 10/04/1983
• Est. Priority Date: 10/28/1980
• Status: Expired due to Term

• Current Assignee: Bell Telephone Laboratories, Inc. (Nokia Corporation)
• Original Assignee: Bell Telephone Laboratories, Inc. (Nokia Corporation)
• Inventors: Zipfel, George G. Jr.
• Primary Examiner(s): Hall, Carl E.
• Application Number:
  US06/201,473
• Time in Patent Office: 1,071 Days
• Field of Search: 29/25.35, 310/357, 310/358, 310/800, 252/62.9
• US Class Current: 29/25.35
• CPC Class Codes: C08G 18/10 Prepolymer processes involving reaction of isocyanates or isothiocyanates with compounds having active hydrogen in a first reaction step
• CPC Class Codes: C08G 18/36 Hydroxylated esters of higher fatty acids
• CPC Class Codes: H10N 30/092 Forming composite materials
• CPC Class Codes: Y10S 310/80 Piezoelectric polymers, e.g. PVDF
• CPC Class Codes: Y10T 29/42 Piezoelectric device making

Abstract

A method of making flexible composite piezoelectric materials exhibiting hydrostatic response and having a stable response over time is given. A prepolymer material is combined with a piezoelectric material and polarized by applying an electric field while inducing an electric dipole in the piezoelectric material, typically by applying hydrostatic pressure or changing the temperature. To ensure stable response characteristics, the polymer material is chosen to have a shear modulus of less than 20 pounds per square inch. To help ensure good contact between the piezoelectric material and the polymer material, controlled shrinkage may be induced in the composite materials by heat or the removal of a volatile material. The prepolymer material desirably has an electrical resistivity greater than 10¹⁰ ohm/meters. Typical piezoelectric materials include lithium sulfate and tartaric acid. Typical polymer materials include RTV rubber, urethanes, and polybutadienes, and may be in the form of oligomers.

Claims

1. A method of making a flexible composite piezoelectric material by steps comprising polarizing particles of a piezoelectric material that are dispersed in a prepolymer material by applying an electric field to said prepolymer material, while simultaneously inducing a dipole moment in said particles, wherein said prepolymer material at least partially polymerizes during said polarizing,

CHARCTERIZED IN THAT the shear modulus of the at least partially polymerized material after said polarizing is (less than 20 pounds per square inch) sufficiently small that the hydrostatic piezoelectric response of said composite is substantially stable over time, and wherein said electric field is in the range of 100 to 1,000 kilovolts per meter, and the ratio of the major-to-minor axes of said piezoelectric particles is less than 2 to 1, and wherein said piezoelectric material is selected from the group consisting of lithium sulfate monohydrate and tartaric acid.

2. The method of claim 1 FURTHER CHARACTERIZED in that said inducing a dipole moment is accomplished by applying a periodic hydrostatic pressure to said particles, and said electric field is a periodic electric field substantially in phase with said periodic pressure.

3. The method of claim 1 FURTHER CHARACTERIZED in that said inducing a dipole moment is accomplished by changing the temperature of said particles.

4. The method of claim 1 FURTHER CHARACTERIZED in that said polymer material remains substantially underpolymerized following said polarizing step.

5. The method of claim 1 FURTHER CHARACTERIZED in that the volume resistivity of said prepolymer material is greater than 1×

10 ¹⁰ ohm-meters.

6. The method of claim 1 FURTHER CHARACTERIZED by the further step of inducing shrinkage of the at least partially polymerized material so that the temporal stability of the piezoelectric response of the composite piezoelectric material is substantially increased.

7. The method of claim 6 FURTHER CHARACTERIZED by accomplishing said shrinkage by including a volatile material in said prepolymer material during said polarizing step and removing said volatile material after the at least partial polymerization of said prepolymer material.

8. The method of claim 1 FURTHER CHARACTERIZED by applying ultrasonic vibration to said prepolymer material during the polymerization process.

9. The method of claim 8 FURTHER CHARACTERIZED in that said piezoelectric material comprises greater than 20 volume percent of said composite material.

10. The method of claim 1 FURTHER CHARACTERIZED in that said polymer material is a urethane.

11. the method of claim 1 FURTHER CHARACTERIZED by electrically coupling at least 2 electrodes to said composite material.

12. The method of claim 1 wherein said shear modulus after polarizing is less than 20 pounds per square inch.