High-strength laminate

• US 4,407,877 A
• Filed: 05/27/1982
• Issued: 10/04/1983
• Est. Priority Date: 07/05/1974
• Status: Expired due to Term

• Current Assignee: Ole-Bendt Rasmussen
• Original Assignee: Ole-Bendt Rasmussen
• Inventors: Rasmussen, Ole-Bendt
• Primary Examiner(s): Ball, Michael W.
• Application Number:
  US06/382,724
• Time in Patent Office: 495 Days
• Field of Search: 428/910, 428/905, 428/105, 428/108, 428/112, 428/114, 428/113, 428/156, 428/167, 428/185, 428/515, 428/516, 428/518, 428/520, 428/522, 428/523, 428/299, 428/308, 428/196 , 428/225, 428/233, 428/298, 428/424, 428/480, 428/425, 264/171, 264/173, 264/DIG. 7, 264/290.2, 264/210.7, 156/229
• US Class Current: 428/105
• CPC Class Codes: B29C 48/08 flexible, e.g. films
• CPC Class Codes: B29C 48/10 flexible, e.g. blown foils
• CPC Class Codes: B29C 48/19 the layers being joined at their edges
• CPC Class Codes: B29C 48/20 one of the layers being a strip, e.g. a partially embedded strip
• CPC Class Codes: B29C 48/21 the layers being joined at their surfaces
• CPC Class Codes: B29C 48/22 with means connecting the layers, e.g. tie layers or undercuts
• CPC Class Codes: B32B 27/00 Layered products comprising a layer of synthetic resin fibrous or filamentary layer made of a synthetic resin B32B5/02; particulate layer made of a synthetic resin B32B5/16; foamed layer made of a synthetic resin B32B5/18
• CPC Class Codes: B32B 37/00 Methods or apparatus for laminating, e.g. by curing or by ultrasonic bonding
• CPC Class Codes: Y10S 428/905 Odor releasing material
• CPC Class Codes: Y10T 428/24058 including grain, strips, or filamentary elements in respective layers or components in angular relation
• CPC Class Codes: Y10T 428/24132 including grain, strips, or filamentary elements in different layers or components parallel

Abstract

A high-strength laminate comprising generally weakly adhered biaxially oriented films, each formed of a blend which exhibits a distinct fibrous morphology with the fibres forming a distinct unidirectional grain when measured in a micro-scale but with the fibre-portions strongly deflected from this direction as seen on a micro-scale, the films being arranged in the laminate such that the undirectional grain in at least two of the films criss-cross each other. This laminate is produced by melt attenuating the blend(s) while extruding the latter into film-like layers, cross-laminating at least two layers before or after solidification while they are still in molecularly unoriented state--except for the weak orientation produced by the melt-attenuation--and finally strongly biaxially orienting the laminate by stretching in several steps, whereby the stretching is generally uniaxial during each step.

Claims

1. A high-strength generally continuous flexible laminate comprised of at least two generally continuous films each being biaxially oriented and generally weakly adhered to an adjacent such film in face-to-face relation, each such film being formed by extrusion with coincidental melt attenuation of a blend of at least two polymers which are sufficiently incompatible as to exhibit upon said extrusion an internal microscopic fibrillar morphology in which elongated fibrils are arranged in a generalized grain-like pattern having one predominant grain direction and imparting a corresponding direction of splittability to such film, such generalized grain pattern including fibrils having microscopically visible recurrent deflections from said predominant grain direction at intervals therealong which form a substantially zig-zagging specific grain configuration incorporated within said generalized grain pattern, the films being arranged in the laminate in such manner that the respective directions of splittability for at least two such films intersect each other.

2. A laminate according to claim 1 comprising at least three of said biaxially oriented films.

3. A laminate according to claim 1 in which the adherence between at least two films is strong in spots or lines and at least weak in the remaining portions of the adjacent surfaces.

4. A laminate according to claim 3 comprising at least three such films in which the lines or spots of strong adherence are staggered in the two sides of the intermediate film.

5. A laminate according to claim 1 comprising two such films each having its generalized grain pattern extending obliquely to the extrusion direction and in criss-crossing relationship to the grain of the other layer.

6. A laminate according to claim 5 also comprising a third film between the said two layers with its generalized grain pattern extending parallel to said extrusion direction.

7. A laminate according to claim 1 in which at least one such film has its generalized grain pattern extending in a lateral direction.

8. A laminate according to claim 1 in which each such film has varying orientation and thickness according to a pattern of generally parallel narrow striations.

9. A laminate according to claim 8 in which said striations form two sets (A) and (B) interspersed with one another, each striation comprising portions of each of the oriented films, the striations (A) being relatively thick, and are biaxially cold stretched in a pronouncedly unbalanced manner, with the main axis of cold stretching generally substantially parallel to the direction of the striations, and with the tear propagation direction forming a small angle to the direction of orientation, while the striations (B) being relatively thin, and are biaxially cold stretched generally in a balanced manner or in unbalanced manner with their main axis of cold stretching criss-crossing with the direction of the striations.

10. A laminate according to claim 1 in which at least one of said films is a blend mainly containing crystalline polyolefins.

11. A laminate according to claim 10 in which at least one of said films is substantially a blend of polypropylene and high- and/or low-density polyethylene.

12. A laminate according to claim 10 in which said blend contains static polypropylene or ethylene-propylene rubber as an alloying agent.

13. A laminate according to claim 1 where each said polymer blend contains not more than 85% of any given polymer.

14. A laminate according to claim 10 where the polyolefin mainly is a polypropylene copolymer with 2-5% of ethylene.

15. A laminate according to claim 10 in which said blend is of polypropylene and an elastomer.

16. A laminate according to claim 15 in which said elastomer is atactic polypropylene, an ethylene-propylene-rubber, an ethylene-vinylacetate copolymer, a polyisobutylene, or a "thermoplastic rubber" based on butadiene/styrene.

17. A laminate according to claim 1 where each said polymer blend is of a polyester and of a polyamide, a polyester and a polyurethane, a polyester and a polycarbonate, a polyamide and a polycarbonate, or a blend of vinylidene copolymers.

18. A laminate according to claim 1 wherein the biaxial orientation of each of said films is generally balanced.