Gas sensor with pH-sensitive FET transducer

• US 4,409,980 A
• Filed: 08/17/1981
• Issued: 10/18/1983
• Est. Priority Date: 08/25/1980
• Status: Expired due to Fees

• Current Assignee: Kuraray Company Limited
• Original Assignee: Kuraray Company Limited
• Inventors: Yano, Makoto, Shibatani, Kyoichiro, Shimada, Kiyoo
• Primary Examiner(s): Apley, Richard J.
• Assistant Examiner(s): Wallen, T. J.
• Application Number:
  US06/293,304
• Time in Patent Office: 792 Days
• Field of Search: 128/635, 204/195, 324/29, 357/25, 128/630, 128/631, 128/632, 128/633, 128/634
• US Class Current: 600/361
• CPC Class Codes: A61B 5/14542 for measuring blood gases A61B5/14551 takes precedence
• CPC Class Codes: A61B 5/1473 invasive, e.g. introduced into the body by a catheter A61B5/1482 takes precedence
• CPC Class Codes: G01N 27/4141 specially adapted for gases

Abstract

A gas sensor which includes a reference electrode deposited on the surface of a pH-sensitive transducer having a gate-insulated field-effect transistor (FET) structure and adjacent a gate region of the FET, the transducer and reference electrode being housed in a flexible tube so that the gate region of the FET is located in an opening provided at the front end of or on the side wall of the tube. Lead wires connected to the FET and to the reference electrode extend along the tube. Between the inner wall of the tube and lead-wire FET bonding part is placed electrical insulation resin filling to stop the tube. A hydrophilic polymer layer containing electrolyte is provided which at least extends over both the FET gate region and a part of the reference electrode. A gas permeable membrane is laid over the polymer layer.

Claims

1. A gas sensor comprising:

a pH-sensitive FET transducer having a gate-insulated field-effect transistor structure;

a reference electrode deposited on the surface of said transducer and adjacent the gate region of said transducer;

an insulating tube which provides connecting lead wires to the FET transducer and to the reference electrode and which houses said transducer and reference electrode, said gate region of said FET transducer being located in the opening provided in said insulating tube, and said lead wires extending along said insulating tube;

electrical insulation resin placed between the inner wall of said tube and lead-wire-FET connecting points to stop said opening of the tube;

a hydrophilic polymer layer extending over both said gate region of the FET transducer and said reference electrode and containing electrolyte which is sensitive to variations in hydrogen ion concentration through gas absorption; and

a gas permeable membrane covering at least the entirety of said polymer layer.

2. The gas sensor of claim 1, wherein the surface of said gate region of the pH-sensitive FET transducer is covered with a layer of silicon nitride, alumina, tantalum pentoxide or tantalum nitride.

3. The gas sensor of claim 1, wherein said pH-sensitive FET transducer has an elongated configuration with said gate region located at the front end thereof and an electrode region at the opposite end.

4. The gas sensor of claim 1, wherein the opening provided in the insulating tube is located at the front end of the tube or on the side wall thereof.

5. The gas sensor of claim 1 or 4, wherein said insulating tube is a flexible slender tube capable of being inserted into a living body.

6. The gas sensor of claim 1, wherein said reference electrode comprises a silver layer deposited on the surface of the FET transducer and a silver chloride layer formed thereon.

7. The gas sensor of claim 6, wherein the silver layer has a thickness of at least 3μ

and the silver chloride layer has a thickness of at least 7μ

.

8. The gas sensor of claim 6, wherein a bonding layer is provided between the substrate of the FET transducer and the silver layer.

9. The gas sensor of claim 8, wherein said bonding layer is a chromium layer having a thickness of 100-1000 Å

.

10. The gas sensor of claim 1, wherein the electrolyte-containing hydrophilic polymer has a moisture content of at least 60% and is selected from the group consisting of polyvinyl alcohol, cellulose, polyhydroxyethyl methacrylate, polyvinyl pyrrolidone, agar-agar, starch and electrolytic polymer.

11. The gas sensor of claim 10, wherein the polyvinyl alcohol is plasticized with a plasticizer.

12. The gas sensor of claim 11, wherein the plasticizer is selected from the group consisting of glycerin, diethylene glycol, ethylene glycol and 3-methyl-1,2,5-trihydroxy pentane.

13. The gas sensor of claim 1 or 10, wherein the hydrophilic polymer is 1-10μ

thick in the dry state.

14. The gas sensor of claim 1, wherein the electrolyte is a mixed solution of NaHCO₃ and NaCl.

15. The gas sensor of claim 1, wherein said gas permeable membrane is a fluoroplastic, a polyolefin plastic or a silicone resin.

16. The gas sensor of claim 15, wherein the gas-permeable membrane is a polytetrafluoroethylene membrane having a thickness of 3-20μ

.

17. The gas sensor of claim 15, wherein the gas-permeable membrane is a silicon membrane having a thickness of 50-300μ

.

18. The gas sensor of claim 1, wherein the reference electrode is deposited in less than 2 mm from the gate region of the FET transducer.