Process for the production of microcapsules

• US 4,412,959 A
• Filed: 06/08/1981
• Issued: 11/01/1983
• Est. Priority Date: 06/14/1980
• Status: Expired due to Term

• Current Assignee: Bayer AG
• Original Assignee: Bayer AG
• Inventors: Jabs, Gert, Wegner, Christian, Dahm, Manfred
• Primary Examiner(s): Lovering, Richard D.
• Application Number:
  US06/271,607
• Time in Patent Office: 876 Days
• Field of Search: 252/316, 252/604, 252/610, 428/420, 428/320.6, 544/180, 544/298, 544/299, 8/526, 71/DIG. 1, 264/4
• US Class Current: 264/4.1
• CPC Class Codes: A01N 25/28 Microcapsules or nanocapsules
• CPC Class Codes: B01J 13/16 Interfacial polymerisation
• CPC Class Codes: C08G 65/34 from hydroxy compounds or their metallic derivatives C08G65/26 takes precedence
• CPC Class Codes: C08G 85/00 General processes for preparing compounds provided for in this subclass
• CPC Class Codes: Y10S 502/507 Synthetic resin, natural resin, polysaccaride, or polypeptide
• CPC Class Codes: Y10T 428/2985 Solid-walled microcapsule from synthetic polymer

Abstract

A process for the production of microcapsules by interfacial polyreaction, which comprises mixing a first reactant with an emulsion of a solution of a material to be encapsulated and a second reactant whereby the first and second reactants react to form a capsule containing the said material and wherein the second reactant dissolved in the disperse phase is a nitrogen-containing heterocyclic compound corresponding to one of the formulae I, II or III ##STR1## wherein at least two of the radicals A, B, D and E are halogen atoms, ammonium, hydrazinium, sulfonium, optionally substituted alkyl sulfonyl, aryl sulfonyl, aralkyl sulfonium, azido, aryloxy, thiocyano arylthio and sulfonic acid residues which are reactive under the conditions of the capsule-forming reaction and the remaining radicals A, B, D, E are hydrogen, alkyl, aryl, alkoxy, phenoxy, alkylamino or phenylamino radicals which are not reactive under the conditions of the capsule-forming reaction.

Claims

1. A process for the production of microcapsules by interfacial polyreaction, which comprises mixing a first reactant with an emulsion of a solution of a material to be encapsulated and a second reactant whereby the first and second reactants react to form a capsule containing the said material and wherein the second reactant dissolved in the disperse phase is a nitrogen-containing heterocyclic compound corresponding to one of the formulae (I), (II) or (III):

##STR3## wherein at least two of the radicals A, B, D and E are halogen atoms, ammonium, hydrazinium, sulfonium, optionally substituted alkyl sulfonyl, aryl sulfonyl, aralkyl sulfonium, azido, aryloxy, thiocyano arylthio and sulfonic acid residues which are reactive under the conditions of the capsule-forming reaction and the remaining radicals A, B, D, E are hydrogen, alkyl, aryl, alkoxy, phenoxy, alkylamino or phenylamino radicals which are not reactive under the conditions of the capsule-forming reaction.

2. A process according to claim 1, wherein the first reactant is a water-soluble, aliphatic, cycloaliphatic, araliphatic or aromatic compound which contains at least two Zerewitinoff-active hydrogen atoms.

3. A process according to claim 1 or 2, wherein the molar ratio between the functional groups of the first and second reactants is from 1:

0.8 to 1;

2.

4. A process according to claim 1 or 2 wherein the first reactant contains one or more NH-groups and the second reactant contains one or more halogen atoms and wherein the first reactant is used in a 1.5 to 10 fold excess.

5. A process according to claim 1 or 2, wherein the reactive radicals of the compounds of formulae (I), (II) or (III) are selected from the group consisting of halogen atoms and methyl, ethyl, phenyl and sulfonyl radicals.

6. A process according to claim 1 or 2, wherein the material to be encapsulated is an organic solvent, plant-protection agent, oil, wax, flameproofing agent, solution of a dye, leuco dye, perfume oil, adhesive, catalyst or a blowing agent.