Lightweight cement slurry and method of use

• US 4,415,366 A
• Filed: 09/21/1982
• Issued: 11/15/1983
• Est. Priority Date: 03/06/1981
• Status: Expired due to Term

• Current Assignee: Dowell Schlumberger Incorporated (Schlumberger NV)
• Original Assignee: The Dow Chemical Company (Dow, Inc.)
• Inventors: Copening, Ward L.
• Primary Examiner(s): Poer, James
• Application Number:
  US06/420,655
• Time in Patent Office: 420 Days
• Field of Search: 106/86-88, 166/293, 166/294
• US Class Current: 106/681
• CPC Class Codes: C04B 2103/40 Surface-active agents, dispersants
• CPC Class Codes: C04B 24/32 Polyethers, e.g. alkylphenol polyglycolether
• CPC Class Codes: C04B 28/14 containing calcium sulfate cements gypsum-paper plates E04C
• CPC Class Codes: C04B 38/10 by using foaming agents C04B38/02 takes precedenceor by using mechanical means, e.g. adding preformed foam
• CPC Class Codes: C04B 7/02 Portland cement
• CPC Class Codes: C09K 8/46 containing inorganic binders, e.g. Portland cement
• CPC Class Codes: C09K 8/473 Density reducing additives, e.g. for obtaining foamed cement compositions

Abstract

A foamed, thixotropic hydraulic cement slurry and method of using same in cementing subterranean voids. This lightweight cement slurry is particularly useful for cementing in oil or gas wellbores penetrating a weak underground formation which will be broken by cement slurries of ordinary density.

Claims

1. A foamed hydraulic cement slurry comprising an aqueous, thixotropic slurry of hydraulic cement in which is dispersed, as discrete stable bubbles, a gas or mixture of gases and which comprises calcium sulfate hemihydrate in an amount sufficient to impart thixotropic properties to said slurry.

2. The foamed slurry of claim 1 wherein, by volume the parts of solids per 100 parts water range from about 20 to about 100.

3. The foamed slurry of claim 1 wherein, by volume, the parts of gas per 100 parts water range from about 10 to about 220.

4. The foamed slurry of claim 3 wherein the parts solids per 100 parts water range from about 20 to about 100.

5. The foamed slurry of claim 1 wherein, by volume, the parts of solids per 100 parts range from about 27 to about 100.

6. The foamed slurry of claim 1 wherein, by volume, the parts of gas per 100 parts water range from about 45 to about 220.

7. The foamed slurry of claim 1, 2, 3, 4, 5 or 6 wherein the hydraulic cement component comprises a Portland cement.

9. The foamed slurry of claim 1 or 8 which comprises a surfactant which is present in an amount sufficient to permit the major portion of said bubbles to remain as discrete entitites until said slurry has hardened.

10. The foamed slurry of claim 1 or 8 which comprises a surfactant which is present, by volume, in an amount of about 0.1 part to about 2 parts per 100 parts water.

11. The foamed slurry of claim 1 or 8 which comprises a surfactant which is present, by volume, in an amount of about 0.1 part to about 2 parts per 100 parts water, and which is capable of forming a stable foam in an aqueous solution at a pH of about 12 or greater.

12. The foamed slurry of claim 1 or 8 wherein the major portion of said bubbles have an average diameter of about 1.5 millimeter or less.

13. The foamed slurry of claim 11 wherein the major portion of said bubbles have an average diameter of about 1.5 millimeter or less.

14. The foamed slurry of claim 13 wherein about 0.5 to about 1.5 part surfactant is present and the average diameter is about 1 millimeter or less.

15. The foamed slurry of claim 14 wherein said average diameter is about 0.5 millimeter or less.

16. The foamed slurry of claim 1 or 8 wherein the calcium sulfate hemihydrate is employed in an amount of from about 10 parts to about 160 parts per 100 parts of hydraulic cement, by volume.

17. A method of filling a subterranean void which comprises emplacing in said void a foamed hydraulic cement slurry of claim 1, 2, 3, 4, 5, 6 or 8, and thereafter allowing said slurry to harden therein.

18. The method of claim 17 wherein the foamed slurry comprises a surfactant which is present in an amount sufficient to permit the major portion of said bubbles to remain as discrete entities having an average diameter of about 1.5 millimeters or less.

19. The method of claim 18 wherein said surfactant is present, by volume, in an amount of about 0.1 part to about 2 parts per 100 parts water, and is capable of forming a stable foam in an aqueous solution at a pH of about 12 or greater.

20. The method of claim 19 wherein the hydraulic cement comprises a Portland cement.

21. The method of claim 19 wherein at least a portion of said void comprises at least a portion of a wellbore which penetrates a subterranean formation.

8. A foamed, hydraulic cement slurry comprising an aqueous, thixotropic slurry of hydraulic cement, comprising Portland cement and comprising calcium sulfate hemihydrate in an amount sufficient to impart thixotropic properties to said slurry, in which slurry a gas or mixture of gases is dispersed as discrete, stable bubbles, wherein the parts of solids and parts of gas per 100 parts of water, range, from about 27 and 45, respectively, to about 100 and 220, respectively, by volume.

22. A foamed, hydraulic cement slurry comprising an aqueous, thixotropic slurry of hydraulic cement, comprising Portland cement and calcium sulfate hemihydrate, in which slurry a gas or a mixture of gases is dispersed as discrete, stable bubbles, wherein about 10 parts to about 20 parts calcium sulfate hemihydrate are present per 100 parts Portland cement;

about 27 to about 100 parts solids and about 45 parts to about 220 parts gas are present per 100 parts of water;

wherein the major portion of said bubbles have an average diameter of about 1 millimeter or less; and

wherein a surfactant is present in an amount of about 0.5 part to about 2 parts per 100 parts water;

all parts by volume.

23. A method of filling a subterranean void which comprises emplacing in said void a foamed, hydraulic cement slurry of claim 22 and thereafter allowing said slurry to harden therein.