Contact enhancing composition

• US 4,415,694 A
• Filed: 05/18/1982
• Issued: 11/15/1983
• Est. Priority Date: 07/14/1981
• Status: Expired due to Term

• Current Assignee: 3M Company
• Original Assignee: Minnesota Mining and Manufacturing Co (3M Company)
• Inventors: Roiko, Russell A., Pokorny, Richard J.
• Primary Examiner(s): Michl, Paul R.
• Application Number:
  US06/379,340
• Time in Patent Office: 546 Days
• Field of Search: 524/200, 524/207, 524/208, 525/199, 260/DIG. 24
• US Class Current: 524/200
• CPC Class Codes: C08L 2666/04 Macromolecular compounds according to groups C08L7/00 - C08L49/00, or C08L55/00 - C08L57/00; Derivatives thereof
• CPC Class Codes: C08L 35/00 Compositions of homopolymers or copolymers of compounds having one or more unsaturated aliphatic radicals, each having only one carbon-to-carbon double bond, and at least one being terminated by a carboxyl radical, and containing at least one other carboxyl radical in the molecule, or of salts, anhydrides, esters, amides, imides or nitriles thereof; Compositions of derivatives of such polymers
• CPC Class Codes: H01B 7/282 Preventing penetration of fluid , e.g. water or humidity, into conductor or cable
• CPC Class Codes: H01R 13/03 characterised by the material, e.g. plating, or coating materials

Abstract

A composition for coating on low pressure sliding connections to enhance electrical contact comprises an admixture of an anhydride copolymer; a flexibilizing copolymer; a hydrophobic, soluble, compatible fluoroaliphatic radical-containing composition; an antioxidant; optionally a mercaptan; and a suitable solvent system. Articles coated with the contact enhancing composition are disclosed.

Claims

1. A soft, deformable composition comprising an admixture of:

a. an effective amount of an anhydride copolymer,

b. an effective amount of a flexibilizing polymer selected from polyisobutylene, styrene olefin styrene block polymer, and polymers of ethylene copolymerized with vinyl acetate, vinyl acrylate, vinyl methacrylate, and alpha-olefins;

c. an effective amount of a hydrophobic, compatible, fluoroaliphatic radical-containing composition,

d. up to 5 weight percent of the composition of a mercaptan compound, and

e. an effective amount of an antioxidant compound.

2. A composition according to claim 1 wherein:

a. said anhydride copolymer is present in the range of 8 to 75 weight percent of the dried composition,

b. said flexibilizing polymer is present in the range of 8 to 75 weight percent of the dried composition,

c. said fluoroaliphatic radical-containing composition is present in the range of 5 to 75 weight percent of the dried composition,

d. said mercaptan compound is present in the range of 0 to 7 weight percent of the dried composition, and

e. said antioxidant compound is present in the range of 1.0 to 20 weight percent of the dried composition.

3. The composition according to claim 1 wherein said anhydride copolymer is derived from an alkyl-, phenyl- or phenylalkyl-substituted or unsubstituted cyclic anhydride in which said alkyl group contains 1 to 6 carbon atoms and said cyclic group contains 4 to 15 carbon atoms.

4. The composition according to claim 1 wherein said anhydride copolymer is selected from maleic anhydride and itaconic anhydride copolymerized with C₁₀ to C₂₄ aliphatic hydrocarbons.

5. The composition according to claim 4 wherein said anhydride copolymer is selected from maleic anhydride octadecene copolymer, maleic anhydride decene copolymer, and maleic anhydride tetradecene copolymer.

6. The composition according to claim 1 wherein said flexibilizing polymer is selected from polyisobutylene, styrene olefin styrene block polymer, and polymers of ethylene copolymerized with vinyl acetate, vinyl acrylate, vinyl methacrylate, and alpha-olefins.

7. The composition according to claim 1 wherein said fluoroaliphatic radical-containing composition comprises a monovalent, fluorinated, aliphatic organic radical having an average of at least 5 to 14 carbon atoms.

8. The composition according to claim 1 wherein said anhydride copolymer is present in the range of 10 to 67 weight percent.

9. The composition according to claim 1 wherein said flexibilizing polymer is present in the range of 10 to 57 weight percent.

10. The composition according to claim 1 wherein said fluoroaliphatic radical-containing composition is present in the range of 7 to 68 weight percent.

11. The composition according to claim 1 wherein said mercaptan compound is present in the range of 0.05 to 1.0 weight percent.

12. The composition according to claim 1 wherein said antioxidant compound is present in the range of 1.5 to 18 weight percent.

13. The composition according to claim 1 wherein said mercaptan compound is selected from a silane mercaptan having 4 to 17 carbon atoms and an alkyl or alkoxy mercaptan of 4 to 24 carbon atoms.

14. The composition according to claim 13 wherein said silane mercaptan is gamma-mercaptopropyltrimethoxysilane.

15. The composition according to claim 13 wherein said alkyl or alkoxy mercaptan is octadecene mercaptan.

16. A coating solution comprising an admixture of:

a. 4 to 30 weight percent of the total solution of;

(1) 8 to 75 weight percent of the dried coating of an anhydride copolymer,

(2) 8 to 75 weight percent of the dried coating of a flexibilizing polymer selected from polyisobutylene, styrene olefin styrene block polymer, and polymers of ethylene copolymerized with vinyl acetate, vinyl acrylate, vinyl methacrylate, and alpha-olefins;

(3) 5 to 75 weight percent of the dried coating of a hydrophobic, soluble, compatible, fluoroaliphatic radical-containing compound or polymer,

(4) 0 to 7 weight percent of the dried coating of a mercaptan compound,

(5) 1.0 to 20 weight percent of an antioxidant compound, and

b. 96 to 70 weight percent of the total solution of;

a solvent system comprising a mixture of at least one C₆ to C₉ aliphatic hydrocarbon, at least one lower molecular weight C₁ to C₄ alcohol, and trichlorotrifluoroethane;

said solution being capable of drying to form a soft, defomable coating.

17. The solution according to claim 16 wherein said aliphatic hydrocarbon comprises 5 to 35 percent, said alcohol comprises 0.5 to 25 percent, and said trichlorotrifluoroethane comprises 30 to 90 percent by weight of the solvent mixture.

18. The solution according to claim 16 wherein said aliphatic hydrocarbon in said solvent system is selected from heptane and hexane.

19. The solution according to claim 16 wherein said alcohol in said solvent system is isopropyl alcohol.

20. An article having at least one set of metallic contacts, which contacts are coated on at least one surface thereof with a soft, deformable contact enhancing composition comprising:

a. 8 to 75 weight percent of the dried contact enhancing composition of an anhydride copolymer,

b. 8 to 75 weight percent of the dried contact enhancing composition of a flexibilizing polymer selected from polyisobutylene, styrene olefin styrene block polymer, and polymers of ethylene copolymerized with vinyl acetate, vinyl acrylate, vinyl methacrylate, and alpha-olefins;

c. 5 to 75 weight percent of the dried contact enhancing composition of a hydrophobic, compatible, fluoroaliphatic radical-containing compound or polymer,

d. 0 to 7 weight percent of the dried contact enhancing composition of a mercaptan compound,

e. 1.0 to 20 weight percent of the dried contact enhancing composition of an antioxidant compound.

21. The article according to claim 20 wherein said contacts are provided with said composition by means of spraying, dipping, or brushing.

22. An article according to claim 20 wherein said article is an electrical receptacle block.

23. A soft, deformable composition comprising an admixture of:

a. an effective amount of an anhydride copolymer selected from maleic anhydride and itaconic anhydride copolymerized with a C₁₀ to C₂₄ aliphatic hydrocarbon,

b. an effective amount of a flexibilizing polymer,

c. an effective amount of a hydrophobic, compatible, fluoroaliphatic radical-containing composition,

d. up to 5 weight percent of the composition of a mercaptan compound, and

e. an effective amount of an antioxidant compound.

24. A coating solution comprising an admixture of:

a. 4 to 30 weight percent of the total solution of;

(1) 8 to 75 weight percent of the dried coating of an anhydride copolymer selected from maleic anhydride and itaconic anhydride copolymerized with a C₁₀ to C₂₄ aliphatic hydrocarbon,

(2) 8 to 75 weight percent of the dried coating of a flexibilizing polymer,

(3) 5 to 75 weight percent of the dried coating of a hydrophobic, soluble, compatible, fluoroaliphatic radical-containing compound or polymer,

(4) 0 to 7 weight percent of the dried coating of a mercaptan compound,

(5) 1.0 to 20 weight percent of an antioxidant compound, and

b. 96 to 70 weight percent of the total solution of;

a solvent system comprising a mixture of at least one C₆ to C₉ aliphatic hydrocarbon, at least one lower molecular weight C₁ to C₄ alcohol, and trichlorotrifluoroethane,

said solution being capable of drying to form a soft, deformable coating.

25. An article having a least one set of metallic contacts, which contacts are coated on at least one surface thereof with a soft, deformable contact enhancing composition comprising:

a. 8 to 75 weight percent of the dried contact enhancing composition of an anhydride copolymer selected from maleic anhydride or itaconic anhydride copolymerized with a C₁₀ to C₂₄ aliphatic hydrocarbon,

b. 8 to 75 weight percent of the dried contact enhancing composition of a flexibilizing polymer,

c. 5 to 75 weight percent of the dried contact enhancing composition of a hydrophobic, compatible, fluoroaliphatic radical-containing compound or polymer,

d. 0 to 7 weight percent of the dried contact enhancing composition of a mercaptan compound,

e. 1.0 to 20 weight percent of the dried contact enhancing composition of an antidioxidant compound.