Shaped cellulose article prepared from a solution containing cellulose dissolved in a tertiary amine N-oxide solvent and a process for making the article

• US 4,416,698 A
• Filed: 04/03/1980
• Issued: 11/22/1983
• Est. Priority Date: 07/26/1977
• Status: Expired due to Term

• Current Assignee: Akzona Incorporated
• Original Assignee: Akzona Incorporated
• Inventors: McCorsley, Clarence C. III
• Primary Examiner(s): Morris, Theodore
• Application Number:
  US06/136,990
• Time in Patent Office: 1,328 Days
• Field of Search: 106/186, 106/163, 106/203, 536/57, 536/56, 264/203
• US Class Current: 106/200.2
• CPC Class Codes: C08J 2301/02 Cellulose; Modified cellulose
• CPC Class Codes: C08J 3/096 Nitrogen containing compounds
• CPC Class Codes: D01F 2/00 Monocomponent artificial filaments or the like of cellulose or cellulose derivatives; Manufacture thereof

Abstract

A solution containing cellulose dissolved in a tertiary amine N-oxide solvent containing a nonsolvent for cellulose such as water is shaped by extrusion or other shaping process to form a shaped cellulose fiber, rod, plate, tubing or film. The extruded shaped article is stretched in air while still a solution to impart improved physical properties thereto and the cellulose is precipitated from the shaped solution to set the properties without additional drawing. The solution may be prepared by dissolving cellulose in the tertiary amine N-oxide solvent in the barrel of an extrusion apparatus, extending the solution, orienting by stretching the resulting product in air while still a solution and then precipitating the cellulose from the shaped article before significant degradation of the cellulose. The cellulose and tertiary amine N-oxide may be ground to substantially the same particle size before charging the extruder barrel. The tertiary amine N-oxide is recovered and recycled to avoid environmental pollution problems. The resulting cellulose fibers or films can be used to make fabrics, wrapping or packaging materials or non-woven products.

Claims

1. A shaped cellulose article which has been formed by a process which comprises shaping a solution containing cellulose dissolved in a solvent therefor which contains a tertiary amine N-oxide solvent for cellulose and a nonsolvent for cellulose which is miscible with the tertiary amine N-oxide solvent, stretching the resulting shaped solution and then precipitating the cellulose from said resulting shaped solution to form said shaped cellulose article having improved physical properties.

2. The product of claim 1 having a wet modulus of at least about 7 gpd at 5% elongation.

3. The product of claim 1 having a conditioned tenacity of at least about 1.4 gpd.

7. The product of claim 1 stretched at a spin stretch ratio of greater than about 3.

8. The product of claim 7 having a conditioned tenacity of at least about 1.4 gpd.

9. The product of claim 7 having a wet tenacity of at least about 0.5 gpd.

10. The product of claim 7 having a conditioned tenacity from about 1.4 to about 4.7 gpd.

11. The product of claim 7 having a wet tenacity of about 0.5 to about 3.7 gpd.

12. The product of claim 7 having a wet modulus from about 7 to about 28 gpd at 5% elongation.

13. The shaped article of claim 1 in the form of a fiber.

14. The shaped article of claim 1 in the form of a film.

4. A shaped cellulose article which has been formed by a process which comprises shaping a solution containing cellulose dissolved in a solvent therefor which contains a tertiary amine N-oxide solvent for cellulose and a nonsolvent for cellulose which is miscible with the tertiary amine N-oxide solvent, and shaped cellulose article having a wet modulus of at least about 7 gpd at 5% elongation.

6. The product of claim 4 having a conditioned tenacity of at least about 1.4 gpd.

5. A shaped cellulose article which has been formed by a process which comprises shaping a solution containing cellulose dissolved in a solvent therefor which contains a tertiary amine N-oxide solvent for cellulose and a nonsolvent for cellulose which is miscible with the tertiary amine N-oxide solvent, said shaped cellulose article having a conditioned tenacity of at least about 1.4 gpd.

15. A cellulose fiber or film prepared by spinning a solution containing cellulose into a nonprecipitating fluid medium, stretching the resulting filament in said medium while still a solution to orient the cellulose molecules and thereafter precipitating the cellulose with a nonsolvent for cellulose to set the physical properties, said fiber or film having a conditioned elongation about equal to its elongation while wet.

16. A cellulose fiber which has been formed by spinning a solution containing cellulose dissolved in a solvent therefor, said solvent containing a tertiary amine N-oxide solvent for cellulose and a non-solvent for cellulose which is miscible with the tertiary amine N-oxide, stretching the resulting filament at a spin-stretch ratio of at least 3 to 1 while the cellulose is still dissolved in the said solvent to orient the molecules and to improve the physical properties of the resulting fiber, and thereafter precipitating the cellulose from the filament to form a fiber having a wet modulus of at least about 7 gpd at 5% elongation, a conditioned tenacity of at least about 1.4 gpd and a wet elongation which is about equal to the fiber'"'"'s conditioned elongation.

17. The fiber of claim 16 wherein the spinning, stretching and precipitation follow each other without substantial interruption.