Electrochemical cell

• US 4,416,957 A
• Filed: 03/03/1982
• Issued: 11/22/1983
• Est. Priority Date: 03/03/1982
• Status: Expired due to Term

• Current Assignee: Yardney Technical Products, Inc. (Vectra Corp.)
• Original Assignee: GTE Products Corporation (Ams-Osram AG)
• Inventors: McDonald, Robert C., Goebel, Franz
• Primary Examiner(s): Skapars, Anthony
• Application Number:
  US06/354,276
• Time in Patent Office: 629 Days
• Field of Search: 429/91, 429/90, 429/101, 429/196, 429/218, 429/178, 429/197
• US Class Current: 429/91
• CPC Class Codes: H01M 4/12 of consumable metal or alloy electrodes use of alloy compositions as active materials H01M4/38
• CPC Class Codes: H01M 6/14 Cells with non-aqueous electrolyte
• CPC Class Codes: H01M 6/5055 End of discharge indicated by a voltage step

Abstract

A primary electrochemical cell operative to provide a warning indication toward the end of discharge of the cell signalling an approaching end-of-life of the cell. The cell includes a tubular porous carbon cathode structure disposed within a metal housing of the cell together with an anode structure and an electrolytic solution.

The anode structure includes first and second electrochemically active elements, for example, lithium and calcium, having different oxidation potentials within the cell and consumable by electrochemical action within the cell during discharge of the cell. The consumption of the active elements during discharge of the cell results in the establishment of different and distinguishable operating voltages for the cell. The active elements are arranged with respect to each other such that the active element of higher oxidation potential (i.e., the lithium) is consumed prior to the other active element (i.e., the calcium). The change in value of the operating voltage of the cell due to successive consumptions of the two active elements is detected to provide a warning indication signalling the approaching end-of-life of the cell.

Claims

1. An electrochemical cell comprising:

a housing;

an electrochemical system within the housing and including an electrolytic solution and a battery stack exposed to said electrolytic solution, said battery stack comprising;

a cathode; and

an anode structure spaced from the cathode and the housing, said anode structure comprising;

a first active element of a first material having a first oxidation potential within the cell, said first active element being consumed by electrochemical action within the cell during discharge of the cell and establishing a first value of operating voltage for the cell during discharge of the cell and the consumption of the first active element; and

a second active element of a second material having a second oxidation potential within the cell, said second active element being consumed by electrochemical action within the cell during discharge of the cell and establishing a second, different value of operating voltage for the cell during discharge of the cell and the consumption of the second active element;

said first and second active elements being arranged with respect to each other so that one of the active elements is consumed before the other whereby the value of operating voltage of the cell changes from one of its two values to the other of its two values;

wherein;

the electrolytic solution includes a catalytically-reducible soluble cathode;

the cathode of the battery stack is a porous carbon structure adjacent to an interior wall of the housing and operative during discharge of the cell to catalytically reduce the soluble cathode of the electrolytic solution; and

the first active element is of a material having a greater oxidation potential within the cell than that of the second active element and surrounds the second active element.

2. An electrochemical cell in accordance with claim 1 wherein:

the reducible soluble cathode of the electrolytic solution is thionyl chloride;

the carbon cathode structure comprises an aggregation of porous carbon conglomerates permeable by the electrolytic solution and defining a surface area for the catalytic reduction of the thionyl chloride in the electrolytic solution;

the first active element is of a first metal; and

the second active element is of a second metal.

3. An electrochemical cell in accordance with claim 2 wherein:

the first active element is of lithium; and

the second active element is of calcium.

4. An electrochemical cell in accordance with claim 3 wherein:

the thionyl chloride is consumed during discharge of the cell by electrochemical action within the cell; and

the lithium and calcium metals are selected so as to be consumed during discharge of the cell prior to the consumption of the thionyl chloride.

5. A primary electrochemical cell comprising:

a metal housing and a cover for said housing, said cover having a metal electrical terminal extending therethrough;

an electrochemical system within the housing and including an electrolytic solution and a battery stack exposed to said electrolytic solution, said electrolytic solution including a catalytically-reducible soluble cathode, and said battery stack comprising;

a cathode structure adjacent to the metal housing and operating during discharge of the cell to catalytically reduce the soluble cathode of the electrolytic solution; and

an anode structure comprising;

a first active element of a first material spaced from the cathode structure and the metal housing, said first active element having a first oxidation potential within the cell and being consumed by electrochemical action within the cell during discharge of the cell and establishing a first value of operating voltage for the cell during discharge of the cell and the consumption of the first active element;

a second active element of a second material having a second oxidation potential within the cell, said second active element being consumed by electrochemical action within the cell during discharge of the cell and establishing a second, different value of operating voltage for the cell during discharge of the cell and the consumption of the second active element;

said first and second active elements being arranged with respect to each other so that one of the active elements is consumed before the other whereby the value of operating voltage of the cell changes from one of its two values to the other of its two values; and

an electrical terminal assembly physically and electrically connected to, and between, the combination of the first and second active elements and the metal electrical terminal in the cover of the housing for the detection at the metal electrical terminal in the cover of the first and second operating voltages and changes in the values thereof;

wherein;

the metal housing is an elongated cylindrical housing;

the cathode structure is an elongated, cylindrical, porous, tubular carbon member;

the first active element is a generally elongated cylindrical element disposed within and spaced from the carbon cathode structure, said cylindrical active element having an oxidation potential within the cell greater than that of the second active element; and

the second active element is positioned adjacent to and surrounded by the active cylindrical element.

6. A primary electrochemical cell in accordance with claim 5 wherein:

the cylindrical active element is of a first metal; and

the second active element is of a second metal.

7. A primary electrochemical cell in accordance with claim 6 wherein:

the cylindrical active element is of lithium; and

the second active element is of calcium.

8. A primary electrochemical cell in accordance with claim 5 further comprising:

an elongated electrically-nonconductive member disposed within the cylindrical active element and having a portion of reduced diameter and cross section than the remainder thereof;

and wherein;

the second active element is in the form of a ring and is physically disposed on the reduced diameter and cross section portion of the electrically-nonconductive member.

9. A primary electrochemical cell in accordance with claim 8 wherein:

the reducible soluble cathode of the electrolytic solution is thionyl chloride;

the elongated, cylindrical, porous, tubular carbon cathode member comprises an aggregation of porous carbon conglomerates permeable by the electrolytic solution and defining a surface area for the catalytic reduction of the thionyl chloride in the electrolytic solution;

the cylindrical active element is of lithium; and

the active ring element is of calcium.

10. A primary electrochemical cell in accordance with claim 9 wherein:

the thionyl chloride is consumed during discharge of the cell; and

the lithium and calcium are selected so as to be consumed during discharge of the cell prior to the consumption of the thionyl chloride.

11. A primary electrochemical cell in accordance with claim 10 wherein:

the elongated electrically-nonconductive member is of glass.

12. A primary electrochemical cell in accordance with claim 10 wherein:

the elongated electrically-nonconductive member is of a ceramic material.