Imaging media capable of displaying sharp indicia

• US 4,418,098 A
• Filed: 02/12/1982
• Issued: 11/29/1983
• Est. Priority Date: 09/02/1980
• Status: Expired due to Term

• Current Assignee: 3M Company
• Original Assignee: 3M Company
• Inventors: Maistrovich, Anthony R.
• Primary Examiner(s): Hess, Bruce H.
• Application Number:
  US06/348,653
• Time in Patent Office: 655 Days
• Field of Search: 428/317.5, 428/317.7, 428/317.9, 428/321.1, 428/321.3, 428/195, 428/206, 428/315.5, 428/315.7, 428/315.9, 428/317.1, 428/317.3, 428/318.4 , 428/338, 427/146, 427/161, 427/180, 427/203, 427/212, 427/214, 427/245, 427/246, 427/256, 427/261
• US Class Current: 427/161
• CPC Class Codes: B41M 5/0029 Formation of a transparent pattern using a liquid marking fluid
• CPC Class Codes: Y10T 428/24893 including particulate material
• CPC Class Codes: Y10T 428/24998 Composite has more than two layers
• CPC Class Codes: Y10T 428/249984 Adhesive or bonding component contains voids
• CPC Class Codes: Y10T 428/249986 Void-containing component contains also a solid fiber or solid particle
• CPC Class Codes: Y10T 428/249995 Constituent is in liquid form
• CPC Class Codes: Y10T 428/268 Monolayer with structurally defined element

Abstract

Improved sheet material of the type where a base sheet is provided with an opaque microvoid-containing layer which can be locally transparentized by applying a colorless liquid which is a non-solvent for the layer. Indicia remain more sharply defined by including in the layer an organic polymer which jellifies in the presence of the liquid and blocks lateral migration.

Claims

1. In sheet material of the type wherein a base sheet is coated on at least one face with a layer comprising a first organic polymer containing interconnected microvoids, said layer being locally transparentizable to display contrasting indicia when there is applied to its exposed surface a transparent, colorless liquid which has a refractive index similar to that of the solid constituents of the layer but which is a non-solvent for said first polymer,

the improvement comprising, incorporated in said layer, a second organic polymer which has a solubility parameter differing from that of the liquid by about 2 hildebrands and which jellifies the liquid,

whereby the indicia maintain substantially the same dimensions throughout the time that the layer is locally transparentized.

2. The invention of claim 1 wherein the first organic polymer is thermoset and holds particles in pseudo sintered juxtaposition.

3. The invention of claim 1 or 2 wherein the jellifying substance comprises cellulose acetate butyrate.

4. The invention of claim 1 or 2 wherein the jellifying substance comprises methyl cellulose.

5. The invention of claim 1 or 2 wherein the jellifying substance comprises carboxypolymethylene.

6. The invention of claim 1 or 2 wherein the jellifying substance comprises a styrene:

isoprene;

styrene block copolymer.

7. A method of making the sheet material of claim 1 comprising incorporating, in an opaque microvoid-containing layer which is locally transparentizable but not dissolved when contacted with a liquid having a refractive index similar to that of the solid constituents of said layer but not being a solvent therefor, an organic polymer which jellifies said liquid and which is different from said other solid substituents.

8. The method of claim 7 wherein, prior to formation of said layer, the jellifying polymer is incorporated in the composition which is used to form the layer.

9. The method of claim 7 wherein, after said layer has been formed, the jellifying polymer is incorporated in said layer.

10. A method of imparting to the sheet material of claim 1 indicia which maintain substantially the same dimensions comprising applying to the surface of said sheet material a transparent, colorless liquid that is a non-solvent for the first organic polymer and that has a solubility parameter differing from that of said second polymer by about 2 hildebrands.

11. The sheet material of claim 1 provided with contrasting indicia that maintain substantially the same dimensions during their period of visibility, said indicia being formed by localized transparentization of the microvoid-containing layer resulting from the presence of a transparent, colorless liquid that is a non-solvent for the solid constituents of the microvoid-containing layer and has a solubility parameter differing from that of the second organic polymer by about 2 hildebrands.

12. Self-supporting sheet material which is substantially insensitive to marking by the localized application of heat or pressure but which is receptive to ink, pencil, crayon or similar markings and which is adapted to being temporarily or permanently provided with markings by the application of a colorless liquid, comprising in combination:

a. a self-supporting base sheet,

b. bonded over at least one side of the base sheet, a reflective opaque white to pastel layer having a cohesive value of at least 400 grams and consisting essentially of particles held in pseudo-sintered juxtaposition by a thermoset binder so that interconnected microvoids are present throughout the layer, and

c. a jellifying organic polymer other than the binder partially filling said microvoids,

whereby, when there are applied to the exposed surface of said layer desired indicia of a marking liquid which has a refractive index approximately that of the particles, a solubility parameter differing from that of said polymer by about 2 hildebrands, is a non-solvent for said binder and is jellified by the jellifying polymer, the liquid not only penetrates the microvoids and is jellified by the jellifying polymer, thereby reducing the reflectivity of the layer in the vicinity of the liquid-penetrated microvoids to impart transparency and maintaining substantially constant dimensions of the indicia throughout the time that the layer is locally transparentized, but also is inhibited from lateral wicking.