Electrochemical monitoring method

• US 4,419,191 A
• Filed: 08/20/1982
• Issued: 12/06/1983
• Est. Priority Date: 02/05/1982
• Status: Expired due to Fees

• Current Assignee: Lockheed Martin Corporation (Martin Marietta Corporation)
• Original Assignee: Lockheed Martin Corporation (Martin Marietta Corporation)
• Inventors: Weber, Kenneth E., Hoffer, Steven D.
• Primary Examiner(s): Tung, T.
• Application Number:
  US06/410,184
• Time in Patent Office: 473 Days
• Field of Search: 204/1 T, 204/195 R, 204/195 P, 204/195 B
• US Class Current: 205/782
• CPC Class Codes: C23C 22/64 Treatment of refractory metals or alloys based thereon
• CPC Class Codes: C23C 22/77 Controlling or regulating of the coating process
• CPC Class Codes: G01N 27/4166 measuring a particular property of an electrolyte

Abstract

A modified alkaline peroxide pre-bond process for the surface treatment of titanium is useful as a practical production process. In this modified process, an exceptionally wide range of allowable peroxide concentration, namely, from 0.001 molar to 0.2 molar (and preferably 0.001 molar to 0.01 molar) may be tolerated and a novel real-time peroxide monitoring and control technique is employed. The process is further improved by means of the use of stabilizers such as precipitated magnesium silicate which greatly increases bath life-time and reduces the overall operating cost of the process. Solution operating conditions have been defined which permit titanium adherends to be processed satisfactorily over a wide range of hydrogen peroxide concentration. In particular, the acceptance temperature range is 125° F.-165° F. (51.7° C.-73.8° C.); the treatment period is 15 to 25 minutes and the hydroxide concentration is 0.3 to 0.9 molar. The preferred values are approximately 145° F. (62.7° C.); 20 minutes, and 0.5 molar, respectively. An electromechanical method has been established utilizing a magnesium electrode (114) which provides a stable potential characteristic that is dependent only on the concentration of the peroxide. The resultant capability to reliably monitor the peroxide concentration in real time in turn permits an automated feed system to be effectively utilized for sustaining the peroxide concentration within the desired limits.

Claims

1. An electrochemical method for monitoring the concentration of hydrogen peroxide within an alkaline peroxide solution comprising the steps of:

(a) immersing a saturated calomel first electrode into said solution;

(b) immersing a pure metal magnesium second electrode into said solution; and

(c) measuring the electrochemical potential voltage generated between said first and second electrodes.

2. The electrochemical monitoring method of claim 1, wherein said measuring step is performed manually by means of a volt meter.

3. The electrochemical monitoring method of claim 1, wherein said measuring step is performed automatically by means of a circuit for detecting when said potential reaches a predetermined threshold voltage.

4. The electrochemical monitoring method of claim 1, wherein said hydrogen peroxide concentration is in excess of 10^-4 molar.