Silver catalyst for the manufacture of ethylene oxide and a process for preparing the catalyst

• US 4,419,276 A
• Filed: 09/30/1981
• Issued: 12/06/1983
• Est. Priority Date: 09/30/1981
• Status: Expired due to Term

• Current Assignee: Union Carbide Corporation (Dow, Inc.)
• Original Assignee: Union Carbide Corporation (Dow, Inc.)
• Inventors: Bhasin, Madan M., Warner, Glenn H.
• Primary Examiner(s): Shine, W. J.
• Application Number:
  US06/307,242
• Time in Patent Office: 797 Days
• Field of Search: 252/476, 260/348.34, 549/534
• US Class Current: 502/347
• CPC Class Codes: B01J 23/66 Silver or gold
• CPC Class Codes: C07D 301/10 with catalysts containing silver or gold
• CPC Class Codes: Y02P 20/52 using catalysts, e.g. selective catalysts

Abstract

This invention relates to a supported silver catalyst for the manufacture of ethylene oxide prepared by a process comprising impregnating a porous catalyst support with a solvent containing a silver salt and treating the impregnated support to effect deposition of silver on the support surface. Following silver deposition, the support is impregnated with a liquid containing a compound of at least one metal promoter dissolved in an organic solvent in which water is soluble at ambient temperature in an amount no greater than about 50 wt. % based on the weight of the water-solvent solution. The impregnated support is then treated to effect deposition of the promoter. There is also described herein a process of making such catalyst and a process for producing ethylene oxide.

Claims

1. A process for preparing a supported silver catalyst for the production of ethylene oxide by the vapor phase oxidation of ethylene with an oxygen-containing gas comprising:

(a) impregnating a porous catalyst support with a solution comprising a solvent or a solubilizing agent, and silver salt in an amount sufficient to deposit the desired amount of silver on said support;

(b) treating the impregnated support to convert at least a fraction of the silver salt to silver metal and effect deposition of silver on the surface of said support;

(c) impregnating the support treated in step (b) with a compound of at least one metal cation promoter in an amount sufficient to deposit the desired amount of promoter on said support dissolved in an organic solvent in which water is soluble at ambient temperature in an amount no greater than about 50 wt. % based on the weight of water-solvent solution; and

(d) treating the impregnated support produced in step (c) to effect deposition of said promoter on the surface of said support.

2. A process as in claim 1 wherein the metal promoter containing solution used in step (c) thereof contains at least about 50 wt. % of said organic solvent.

3. A process as in claim 1 wherein said organic solvent is n-butanol.

4. A process as in claim 1 wherein said organic solvent is iso-butanol.

5. A process as in claim 1 wherein said promoter is an alkali metal.

6. A process as in claim 5 wherein said alkali metal is selected from the group consisting of lithium, sodium, potassium, cesium, rubidium and mixtures thereof.

7. A process as in claim 5 wherein the amount of alkali metal deposited on the catalyst support is at least 10% greater than that amount of like alkali metal which provides the maximum enhancement of efficiency when used in a coincidental method of preparation with the same amount of silver and the same catalyst support.

8. A process as in claim 1 wherein said catalyst contains silver in an amount of from about 2% to about 20% based on the total weight of the catalyst.

9. A supported silver catalyst for the production of ethylene oxide by the vapor phase oxidation of ethylene with an oxygen-containing gas prepared by a process comprising:

(a) impregnating a porous catalyst support with a solution comprising a solvent of solubilizing agent, and silver salt in an amount sufficient to deposit the desired amount of silver on said support;

(b) treating the impregnated support to convert at least a fraction of the silver salt to silver metal and effect deposition of silver on the surface of said support;

(c) impregnating the support treated in step (b) with a compound of at least one alkali metal in an amount sufficient to deposit the desired amount of promoter on said support dissolved in an organic solvent in which water is soluble at ambient temperature in an amount no greater than about 50 weight percent based on the weight of water-solvent solution; and

(d) treating the impregnated support produced in step (c) to effect deposition of said promoter on the surface of said support.

10. The catalyst of claim 9 wherein the solution used in step (c) thereof contains at least about 50 wt. % of said organic solvent.

11. The catalyst of claim 9 wherein said organic solvent is n-butanol.

12. The catalyst of claim 9 wherein said organic solvent is iso-butanol.

13. The catalyst of claim 9 wherein said alkali metal is selected from the group consisting of lithium, sodium, potassium, cesium, rubidium and mixtures thereof.

14. The catalyst of claim 9 wherein the amount of alkali metal deposited on the catalyst support is at least 10% greater than that amount of like alkali metal which provides the maximum enhancement of efficiency when used in a coincidental method of preparation with the same amount of silver and the same catalyst support.