Composite films for deep-drawn packings

• US 4,420,516 A
• Filed: 03/22/1982
• Issued: 12/13/1983
• Est. Priority Date: 04/11/1981
• Status: Expired due to Fees

• Current Assignee: Wolff Walsrode AG (Dow, Inc.)
• Original Assignee: Wolff Walsrode AG (Dow, Inc.)
• Inventors: Klein, Rudi, Funk, Hans W., Ermert, Wolfgang
• Primary Examiner(s): Lesmes, George F.
• Assistant Examiner(s): Johnson, Beverly K.
• Application Number:
  US06/360,307
• Time in Patent Office: 631 Days
• Field of Search: 428/347, 428/349, 428/476.3, 428/476.9, 428/35
• US Class Current: 428/476.1
• CPC Class Codes: B32B 2307/31 Heat sealable
• CPC Class Codes: B32B 2307/736 Shrinkable
• CPC Class Codes: B32B 2553/00 Packaging equipment or accessories not otherwise provided for
• CPC Class Codes: B32B 27/08 of synthetic resin
• CPC Class Codes: B32B 27/306 comprising vinyl acetate or vinyl alcohol (co)polymers
• CPC Class Codes: B32B 27/32 comprising polyolefins comprising vinyl (co)polymers or acrylic (co)polymers B32B27/30
• CPC Class Codes: B32B 27/34 comprising polyamides
• CPC Class Codes: B32B 7/12 using interposed adhesives or interposed materials with bonding properties
• CPC Class Codes: Y10T 428/2826 Synthetic resin or polymer
• CPC Class Codes: Y10T 428/31746 Polymer of monoethylenically unsaturated hydrocarbon
• CPC Class Codes: Y10T 428/3175 Next to addition polymer from unsaturated monomer[s]

Abstract

The invention relates to composite packing films shrinkable by deep drawing and consisting of at least one copolyamide layer containing at least 50% by weight of ε-caprolactam units and at least one heat-sealable layer, and optionally, an adhesion-promoting layer.

Claims

1. A heat-sealable composite film shrinkable by deep drawing, which comprises

(1) at least one layer of at least one copolyamide 6/12 containing at least 50% by weight of ε

-caprolactam units and having a melting temperature of 75°

to 215°

C.,

(2) at least one heat-sealable layer of a copolymer containing at least 50 mole percent of ethylene and, optionally,

(3) an adhesive or adhesion-promoting layer between layers 1 and 2.

2. A composite film as claimed in claim 1, wherein the melting temperature range of the copolyamide is from 160°

to 200°

C.

3. A composite film as claimed in claim 1, wherein the copolyamide contains besides ε

-caprolactam units, units derived from lauric lactam.

4. A composite film as claimed in claim 1, wherein the copolymer of layer 2 comprises units of ethylene and of an α

,β

-unsaturated C₃ -C₅ -monocarboxylic acid.

5. A composite film as claimed in claim 4, wherein the monocarboxylic acid units are at least partly present in the form of salts of alkaline metals, alkaline earth metals or Zn.

6. A composite film as claimed in claim 1, wherein the ethylene copolymer has a melt index of from 0.5 to 40 g/10 mins. according to DIN 53 735.

7. A composite film as claimed in claim 1, wherein layer 1 also includes from 5 to 30% by weight of an ethylene/vinyl acetate copolymer containing from 50 to 80% by weight of vinyl acetate units, of which at least 90% are saponified.

8. A heat-sealable composite film according to claim 1, wherein said layer of copolyamide 6/12 additionally contains a saponified ethylene/vinylacetate copolymer.

9. A heat-sealable composite film according to claim 1, wherein said layer of copolyamide 6/12 additionally contains an ionomer resin.

10. A heat-sealable composite film according to claim 8, wherein said layer of copolyamide 6/12 additionally contains an ionomer resin.

11. A heat sealable composite film according to claim 1, wherein said layer of copolyamide 6/12 consists essentially of copolyamide 6/12.

12. A heat sealable composite film according to claim 1, wherein said film has a shrinkage in volume of at least 40% after having been deep-drawn.

13. A heat sealable composite film according to claim 12, wherein said shrinkage is at 50%.

14. A heat sealable composite film according to claim 13, wherein said shrinkage is at least 75%.

15. A heat sealable composite film according to claim 1 which is pleat-free.