Electrode material, electrode and electrochemical cell

• US 4,422,917 A
• Filed: 08/18/1981
• Issued: 12/27/1983
• Est. Priority Date: 09/10/1980
• Status: Expired due to Term

• Current Assignee: Atraverda Limited (Ebonex Limited)
• Original Assignee: IMI Marston Ltd. (IMI PLC)
• Inventors: Hayfield, Peter C. S.
• Primary Examiner(s): Valentine, Donald R.
• Application Number:
  US06/293,961
• Time in Patent Office: 861 Days
• Field of Search: 204/291, 204/280, 204/284, 204/290 R, 204/290 F, 204/196-197, 204/228, 204/242, 204/254-256, 204/268-270, 204/222, 204/106, 204/109, 204/112, 204/114 , 204/72, 204/82-104, 219/286, 219/288, 219/295
• US Class Current: 204/196.01
• CPC Class Codes: C02F 1/46109 Electrodes
• CPC Class Codes: C04B 2235/652 Reduction treatment C04B2235/664 takes precedence
• CPC Class Codes: C04B 2235/6567 Treatment time
• CPC Class Codes: C04B 2235/6582 Hydrogen containing atmosphere
• CPC Class Codes: C04B 2235/79 Non-stoichiometric products, e.g. perovskites (ABO3) with an A/B-ratio other than 1
• CPC Class Codes: C04B 2235/94 Products characterised by their shape
• CPC Class Codes: C04B 35/46 based on titanium oxides or titanates containing also zirconium or hafnium oxides, zirconates or hafnates C04B35/49
• CPC Class Codes: C25B 11/04 characterised by the material
• CPC Class Codes: C25B 11/055 characterised by the substrate or carrier material
• CPC Class Codes: C25C 7/02 Electrodes consumable anodes for the refining the metals C25C1/00 - C25C5/00; Connections thereof

Abstract

The invention provides an electrode material, and a method for its manufacture, for use in electrochemical reactions comprising bulk titanium oxide having the general formula TiO_x where x is from 1.55 to 1.95 and also electrochemical cells including an electrode formed from such a material.

Claims

1. An electrochemical cell incorporating an electrode in which the electrode is formed from an electrode material of solid coherent bulk titanium oxide having the general formula TiO_x where x is a number in the region 1.67 to 1.9.

2. A cell as in claim 1 furher characterized in that x is in a range selected from the groups 1.67 to 1.85 and 1.7 to 1.8.

3. A cell as in claim 2 in which the titanium oxide is selected from the group consisting of predominantly Ti₄ O₇ and predominantly Ti₅ O₉.

4. A cell as in claim 1 in which there is provided an electrocatalytically active surface on part at least of the surface of the electrode.

5. A cell as in claim 4 in which the electrocatalytically active surface includes a material selected from the group consisting of platinum group metals, platinum group metal alloys, platinum group metal oxides, lead and lead dioxide.

6. A cell as in claim 4 in which the cell is used for metal electrowinning and the anodes in the cell are formed of the electrode material.

7. A cell as in claim 6 in which the metal to be electrowon is selected from the group consisting of zinc, cobalt, manganese, copper, nickel, gold, platinum, silver, rhodium, ruthenium, palladium, osmium and iridium.

8. A cell as claimed in claim 4 in which the cell is a metal plating cell, the metal being plated being selected from the group consisting of nickel, chromium, cadmium and iron.

9. A cell as in claim 1 in which the electrode is formed of a range of titanium oxide compositions.

10. A cell as in claim 1 in which the cell comprises a cathodic protection system and the electrode comprises an anode.

11. A cell as in claim 10 in which the anode is a ground bed anode.

12. A cell as in claim 1 in which the cell is a bipolar cell and the bipolar electrode is formed of the titanium oxide material, preferably having a coating on one or both of its active faces.

13. A cell as in claim 12 in which the cell comprises a plurality of bipolar electrodes assembled in an array, the cell being a chlorate or hypochlorite cell having an aqueous sodium chloride feed and a chlorate or hypochlorite removal system.

14. A cell as in claim 12 in which the current passing through the cell is periodically reversed.

15. A cell as in claim 1 in which the current passing through the cell is periodically reversed in direction.

16. A cell as in claim 1 in which the electrode is formed of a series of tiles of the titanium oxide material, each tile being bonded to a substrate metal by an electrically conductive joint.

17. A cell as claimed in claim 1 in which the cell is used for the synthesis of organic compounds or inorganic compounds.

18. A cell as claimed in claim 1 in which the cell is an electrode boiler and alternating current is applied to the cell to boil liquids between the electrodes formed of the electrode material.

19. An electode for use in an electrochemical cell, the electrode consisting essentially of a solid coherent bulk titanium oxide having the general formula TiO_x where x is a number in the region 1.67 to 1.9 and an electrocatalytically active surface or part at least of the surface of the electrode.

20. An electrode as in claim 19 in which the electrode is in the form of a plate with electrocatalytically active material on one side only.

21. An electrode as in claim 20 in which the electrode material is manufactured by reducing titanium dioxide in a reducing atmosphere at a temperature in excess of 1000°

C. for a time in excess of one hour.

22. An electrode as in claim 21 in which the reduction takes place in an atmosphere of hydrogen.

23. An electrode based on titanium in which all the titanium is present in the form of an oxide having the general formula TiO_x where x is a number in the region 1.67 to 1.8, the electrode being a solid coherent bulk titanium oxide.

24. An electrode as in claim 23 in which the electrode material is manufactured by reducing titanium dioxide in a reducing atmosphere at a temperature in excess of 1000°

C. for a time in excess of one hour.

25. An electrode having a substrate consisting only of a metal in oxide form, the metal being titanium and the oxide having a general formula of TiO_x where x is in the region 1.67 to 1.8, the oxide being in solid coherent bulk form and having an electrolytically active surface on part at least of the surface of the electrode.