Apparatus for treating powdery materials utilizing microwave plasma

• US 4,423,303 A
• Filed: 05/05/1981
• Issued: 12/27/1983
• Est. Priority Date: 05/06/1980
• Status: Expired due to Fees

• Current Assignee: Tokyo Shibaura Denki Kabushiki Kaisha
• Original Assignee: Tokyo Shibaura Denki Kabushiki Kaisha
• Inventors: Nishida, Katsutoshi, Hirose, Masahiko
• Primary Examiner(s): PASCHALL, MARK H
• Application Number:
  US06/260,755
• Time in Patent Office: 966 Days
• Field of Search: 219/10.55 R, 219/10.55 A, 219/121 P, 219/121 PY, 219/121 PR, 219/121 AG, 219/121 PD, 219/121 PX, 204/164, 204/157.1 H, 250/531, 315/111.2, 373/18
• US Class Current: 219/121.36
• CPC Class Codes: B01J 19/126 Microwaves
• CPC Class Codes: B01J 2219/0894 Processes carried out in the presence of a plasma
• CPC Class Codes: C01B 21/0685 Preparation by carboreductive nitridation
• CPC Class Codes: C01P 2002/70 defined by measured X-ray, neutron or electron diffraction data
• CPC Class Codes: C01P 2002/82 by IR- or Raman-data
• CPC Class Codes: C09C 3/048 Treatment with a plasma
• CPC Class Codes: H05B 6/80 Apparatus for specific applications stoves or ranges F24C7/02
• CPC Class Codes: Y02P 20/10 Process efficiency

Abstract

The apparatus includes a microwave generating device and, a waveguide connected with the microwave generating device. A reaction vessel disposed through the waveguide and supplied with a powdery material to be treated with a reaction gas. Pumps are provided for exhausting the reaction vessel. The reaction vessel comprises a vertically elongated vessel having a bottom above which a plasma generating area is formed. In one embodiment, the reaction vessel further comprises a bottom plate horizontally supported in the reaction tube and connected so as to be vertically slidable within the reaction tube.

Claims

1. An apparatus for treating powdery materials utilizing microwave plasma, comprising means for generating a microwave, a waveguide connected with said microwave generating means, a reaction vessel disposed through said waveguide, means for supplying said reaction vessel with a powdery material to be treated, means for supplying said reaction vessel with a reaction gas, and means for exhausting said reaction vessel;

wherein said reaction vessel comprises a vertically elongated vessel having an upper area air tightly connected to said exhaustion means and a bottom area disposed in said waveguide so that a plasma generating area is formed at the bottom area, said vessel having a central axis and being disposed such that said central axis is oriented substantially in the direction of gravity; and

said reaction gas supplying means includes a gas introducing pipe having an outlet located adjacent said bottom area, and including a movable plate positioned such that said powdery material is supported in said bottom area whereby said powdery material is blown up and agitated by the plasma.

2. An apparatus according to claim 1, wherein said reaction vessel comprises a reaction tube disposed substantially vertically therein and a bottom plate horizontally supported in said reaction tube, said bottom plate being vertically slidable within said reaction tube with substantially no clearance between the side of the plate and the inner wall of the reaction tube.

3. An apparatus according to claim 2, wherein said bottom plate is a disc made of quartz or graphite.

4. An apparatus according to claim 2, wherein the reaction tube is further provided at a bottom end portion thereof with means for collecting treated powdery materials.

5. An apparatus according to claim 4, wherein the bottom plate is vertically slidable between a lower portion of the plasma generating area and the treated powdery materials collecting means.

6. An apparatus for treating powdery materials utilizing a microwave plasma, comprising:

means for generating microwave energy;

a wave guide connected to said microwave generating means;

a reaction vessel disposed through said wave guide, said reaction vessel being vertically oriented and having inlets for receiving a powdery material to be treated and a reaction gas, said reaction vessel further including a portion containing means for supporting powdery material in said wave guide, said supporting means comprising a movable plate positioned such that said powdery material is supported in said wave guide whereby said powdery material is blown up by the plasma and automatically agitated in the plasma reaction area resulting in a uniform reaction, and a powdery material outlet;

means for supplying one of said reaction vessel inlets with a powdery material to be treated;

means for supplying another of said reaction vessel inlets with a reaction gas; and

means for exhausting said reaction vessel.

7. An apparatus for treating powdery materials utilizing microwave plasma, comprising means for generating a microwave, a waveguide connected with said microwave generating means, a reaction vessel disposed through said waveguide, means for supplying said reaction vessel with a powdery material to be treated, means for supplying said reaction vessel with a reaction gas, and means for exhausting said reaction vessel;

wherein said reaction vessel comprises a vertically elongated vessel having an upper area air tightly connected to said exhaustion means and a bottom area disposed in said waveguide so that a plasma generating area is formed at the bottom area, said vessel having a central axis and being disposed such that said central axis is oriented substantially in the direction of gravity; and

said reaction gas supplying means includes a gas introducing pipe having an outlet located adjacent said bottom area, and including a means for causing said powdery material to be supported in said waveguide in said bottom area whereby said powdery material is blown up and agitated by the plasma.