Method of forming battery electrodes

• US 4,425,192 A
• Filed: 06/17/1983
• Issued: 01/10/1984
• Est. Priority Date: 12/07/1982
• Status: Expired due to Fees

• Current Assignee: General Battery Corporation
• Original Assignee: Allied Corp. (Honeywell International Inc.)
• Inventors: McKinley, Larry F.
• Primary Examiner(s): Tufariello, T. M.
• Application Number:
  US06/504,595
• Time in Patent Office: 207 Days
• Field of Search: 204/2.1, 204/228
• US Class Current: 205/63
• CPC Class Codes: H01M 4/22 Forming of electrodes
• CPC Class Codes: Y02E 60/10 Energy storage using batteries

Abstract

A method for forming battery plates or electrodes produces a substantial reduction in the forming energy per gram of active material, by providing the plates or electrodes being formed with energy in the form of at least three, and preferably eight, constant-current steps, an intermediate step being a higher current level than steps which precede or follow it. A low constant current is provided at the beginning of formation, when plate resistivity appears to be high due to the resistivity of the raw material, a higher constant-current is provided when formation has begun and plate conductivity is high, and a lower constant-current is provided towards the end of formation, as plate or electrode potential builds towards full charge. The method and apparatus disclosed is used in the tank formation of positive and negative battery plates or electrodes for use in dry charged batteries having antimonial and calcium grid positive plates.

Claims

1. A method of forming battery electrodes, comprising the steps of:

placing said battery electrodes in an electrolyte solution;

connecting said battery electrodes to a source of electrical current; and

controlling said source of electrical current to provide said current for forming said battery electrodes in at least three discrete sequential predetermined constant-current levels, an intermediate one of said at least three discrete sequential predetermined constant-current levels being greater than a first predetermined constant-current level preceding said intermediate one of said at least three constant-current levels and being greater than a second predetermined constant-current levels following said intermediate one of said at least three constant-current levels, said second predetermined level being lesser than said first predetermined level, to provide an approximately-constant voltage across said battery electrodes.

2. A method of forming battery electrodes according to claim 1, wherein:

said step of controlling said source of electrical current includes the step of controlling said current to provide five discrete sequential predetermined constant-current levels, a second one of said sequential predetermined constant-current levels being controlled to be a higher level than a first one of said levels, a third one of said levels being controlled to be a higher level than said second one of said levels, a fourth one of said levels being controlled to be a lower level than said third one of said levels, and a fifth one of said sequential predetermined constant-current levels being lower than the level of said fourth one of said sequential predetermined constant current levels and being controlled to be a lower level than said first one of said levels.

3. A method of forming battery plates according to claim 2, wherein:

said step of controlling said source of electrical current includes the step of controlling said current to provide eight discrete sequential predetermined constant-current levels, a second one of said sequential predetermined constant-current levels being controlled to be a higher level than a first one of said levels, a third one of said levels being controlled to be a higher level than said second one of said levels, a fourth one of said levels being controlled to be a higher level than said third one of said levels, and a fifth one of said sequential predetermined constant-current levels being controlled to be a lower level than the level of said fourth level, and a sixth one of said levels being controlled to be a lower level than the level of said fifth level, and a seventh one of said levels being controlled to be a lower level than the level of said seventh level, and an eighth of said levels being controlled to be a lower level than the level of said seventh of said sequential predetermined constant-current levels, and being controlled to be a lower level than said first one of said levels.

4. Apparatus for controlling electrical current for forming battery electrodes, comprising:

input means for receiving a predetermined manual input of total desired forming current ampere hours;

current step calculator means operably connected to said input means for calculating a plurality of sequential forming current steps as predetermined percentages of said total desired forming current ampere hours at predetermined forming current levels;

power supply means for supplying said forming current;

current control means for stepwise controlling the current provided by said current control means;

current integrator means for measuring and integrating the current supplied to said battery electrodes by said power supply means, and for providing an output signal upon measuring a predetermined number of ampere hours;

stepper control means operably connected to said calculator means for controlling stepper means, said stepper means being operably connected to said current control means for stepwise adjusting said current control means;

said current integrator means providing a signal to said stepper control means for selecting a succeeding said sequential forming current step when said current integrator means provides said output signal.