Planar battery comprising a terminal plate having gas venting orifice covered with a layer of gas permeable material

• US 4,427,748 A
• Filed: 12/22/1975
• Issued: 01/24/1984
• Est. Priority Date: 10/03/1973
• Status: Expired due to Term

• Current Assignee: Polaroid Corporation (PLR IP Holdings LLC)
• Original Assignee: Polaroid Corporation (PLR IP Holdings LLC)
• Inventors: Land, Edwin H.
• Primary Examiner(s): Skapars, Anthony
• Application Number:
  US05/642,798
• Time in Patent Office: 2,955 Days
• Field of Search: 354/202, 354/275, 136/111, 136/177, 136/179, 429/82, 429/162, 429/210, 429/224, 429/229, 429/152, 429/160, 429/178, 429/201, 429/185, 429/72, 429/53
• US Class Current: 429/82
• CPC Class Codes: H01M 50/30 Arrangements for facilitating escape of gases
• CPC Class Codes: H01M 50/394 Gas-pervious parts or elements
• CPC Class Codes: H01M 6/48 with bipolar electrodes

Abstract

A relatively thin, flat or planar battery is disclosed which includes one or more cells in series relationship each comprising a planar anode in superposed relationship with a planar cathode and a separator disposed intermediate and extending substantially coextensive the facing surfaces of the anode and cathode possessing marginal portions and an aqueous electrolyte permeable central portion. Each cell includes an aqueous electrolyte disposed in the central portion of the separator and in contact with the facing surfaces of both the anode and the cathode and an electrically nonconducting, sealant extending intermediate and providing adhesive contact between the marginal portions of the separator and next adjacent facing surfaces. Each battery is designed to include a planar anode and/or cathode next adjacent a surface of the battery which electrode includes a conductive metal sheet; a gas permeable, water-vapor impermeable plastic sheet and an electrochemically active negative or positive material. At least one of the conductive metal sheets is designed to specifically include one or more orifices extending through the sheet to conduct from the battery gas generated within its cells.

Claims

1. In a planar battery which comprises, in combination and in superposed relationship, electrical energy generating components including a plurality of cells connected in series by electrolyte impermeable electronically conducting intercell connectors, each of said cells comprising,

(a) a planar anode;

(b) a planar cathode superposed substantially coextensive the anode;

(c) a planar separator positioned intermediate and extending substantially coextensive the facing surfaces of the anode and the cathode; and

(d) aqueous electrolyte disposed in the separator and in contact with the facing surfaces of the anode and the cathode;

the improvement which comprises an exterior one of said anode and said cathode comprising a planar electrically conductive metallic sheet possessing at least one gas release orifice extending through the sheet normal to its plane and in contiguous relationship to the orifices a gas permeable, water-vapor impermeable polymeric sheet.

2. A planar battery as defined in claim 1 wherein the anode comprises zinc.

3. A planar battery as defined in claim 2 wherein the zinc is secured to the surface of an electrically conductive, gas permeable and water-vapor impermeable polymeric sheet positioned distal the separator.

4. A planar battery as defined in claim 3 wherein the conductive metallic sheet is secured to the surface of the conductive polymeric sheet opposite the zinc.

5. A planar battery as defined in claim 4 wherein the conductive metallic sheet comprises steel.

6. A planar battery as defined in claim 2 wherein the cathode comprises carbon.

7. A planar battery as defined in claim 6 wherein the cathode includes manganese dioxide.

8. A planar battery as defined in claim 7 wherein the carbon and manganese dioxide are disposed in an electrically conductive ionically permeable polymeric matrix.

9. A planar battery as defined in claim 8 wherein the carbon/manganese dioxide mixture is secured to the surface of a conductive carbon retaining polymeric sheet positioned distal the separator.

10. A planar battery as defined in claim 9 wherein a conductive metallic sheet is secured to the surface of the exterior conductive carbon retaining sheet opposite the carbon/manganese mixture.

11. A planar battery as defined in claim 6 wherein the electrolyte comprises zinc chloride and/or ammonium chloride.

12. A planar battery as defined in claim 11 wherein the electrolyte is disposed in an ionically permeable polymeric matrix.

13. A planar battery as defined in claim 12 wherein the separator comprises electrolyte permeable fibrous sheet.

14. A planar battery as defined in claim 1 wherein the marginal portions of the separator comprise electrolyte permeable separator sheet impregnated with an electrolyte impermeable thermoplastic polymer in a concentration effective to prevent electrolyte permeation of the marginal portions of the separator sheet.

15. A planar battery as defined in claim 14 wherein the thermoplastic polymer is a polymeric hot melt adhesive.

16. A planar battery as defined in claim 15 wherein the polymeric hot melt adhesive is a thermoplastic vinyl adhesive.

17. A planar battery as defined in claim 1 wherein the intercell connectors comprise an electrolyte impermeable electrically conducting polymeric sheet material.

18. A planar battery as defined in claim 17 wherein the anode of the first of two superposed cells is adhesively secured to one surface of the intercell connector and the cathode of the second of the superposed cells is adhesively secured to the opposite surface of the connector.

19. A planar battery as defined in claim 1 wherein the electrically conductive metallic sheet possessing said orifices possesses a plurality of spaced orifices extending along the midline of the metallic sheet'"'"'s long dimension.

20. A planar battery as defined in claim 1 including gas collector means for capture of volatile effluvia exiting said battery.

21. A photographic film assembly which comprises, in combination:

(a) a photographic film cassette adapted for enclosing a plurality of planar photographic film units arranged in stacked relationship and including a forward wall possessing a light-transmitting section to provide for exposure of the forwardmost film unit and a withdrawal opening in one wall of the container permitting selective withdrawal of the film units following exposure thereof;

(b) a plurality of photographic film units disposed in stacked relationship within the cassette next adjacent the forward wall;

(c) a planar battery positioned in the cassette and including, in combination;

(i) a planar anode;

(ii) a planar cathode superposed substantially coextensive the anode;

(iii) a planar battery separator positioned intermediate and extending at least coextensive the facing surfaces of the anode and the cathode; and

(iv) an electrolyte disposed in contact with the facing surfaces of the anode and the cathode;

at least one of said anode and said cathode comprising a planar electrically conductive metallic sheet possessing at least one gas release orifice extending through the sheet normal to its plane; and

a gas permeable, water-vapor impermeable polymeric sheet in a contiguous relationship to the orifices; and

(d) including gas collector means positioned in said cassette intermediate said battery and said film units for capture of volatile effluvia exiting from the battery.

22. A thin, flat cell having a metal anode;

a cathode of depolarizer mix;

a separator between said anode and said cathode;

an electrolyte in contact with said anode and said cathode; and

a cathode collector;

said cathode collector having a plurality of openings for venting undesirable gases formed within the cell and having on at least one of its surfaces a substantially continuous coated layer of a gas-permeable, electrolyte-impermeable conductive material; and

wherein said cathode, said separator and said electrolyte are within and bounded by a peripheral frame of electrolyte impermeable sealing material, said frame being marginally adhered to said anode and said coated cathode collector.

23. The cell of claim 22 wherein said anode is zinc, said cathode comprises manganese dioxide, and said electrolyte comprises ammonium chloride.

24. The cell of claim 22 wherein said anode is zinc, said cathode comprises manganese dioxide, and said electrolyte comprises zinc chloride.

25. A multicell battery comprising an outer negative electrode;

an outer positive electrode;

at least one duplex electrode between the outer positive electrode and the outer negative electrode;

a separator and an electrolyte between each positive and negative electrode; and

a cathode collector having a plurality of openings for venting undesirable gases formed within the battery and having on at least one of its surfaces a substantially continuous layer of a gas-permeable, electrolyte-impermeable conductive material;

said duplex electrode comprising a positive electrode bonded to a porous negative electrode via an electronically conductive layer; and

all of said components of said battery substantially secured together so as to maintain a relatively low electrical resistance contact between said individual cell components.

26. The battery of claim 25 wherein each anode is zinc, each cathode comprises manganese dioxide, and each electrolyte comprises ammonium chloride.

27. The battery of claim 25 wherein each anode is zinc, each cathode comprises manganese dioxide, and each electrolyte comprises zinc chloride.

28. A thin flat cell having a sheet metal anode;

a cathode of depolarizer mix;

a separator between said anode and said cathode;

an electrolyte in contact with said anode and said cathode; and

a cathode collector;

said cathode collector having a plurality of openings for venting undesirable gases formed within the cell and having on at least one of its surfaces a substantially continuous layer of a gas-permeable, electrolyte-impermeable conductive material; and

wherein all of said components of said cell are substantially secured together so as to maintain a relatively low electrical resistance contact between said individual cell components.

29. The cell of claim 28 wherein said anode is zinc, said cathode comprises manganese dioxide, and said electrolyte comprises ammonium chloride.

30. The cell of claim 28 wherein said anode is zinc, said cathode comprises manganese dioxide, and said electrolyte comprises zinc chloride.

31. A thin, flat cell having a metal anode, a cathode of depolarizer mix, a separator between said anode and said cathode, an electrolyte in contact with said anode and said cathode, and a cathode collector;

said anode having a plurality of openings for venting undesirable gases formed within the cell and having on its outer surface a substantially continuous layer of a gas-permeable, electrolyte-impermeable material; and

wherein said cathode, said separator and said electrolyte are within and bounded by a peripheral frame of electrolyte-impermeable sealing material, said frame being marginally adhered to said anode and said cathode collector.

32. The cell of claim 31 wherein the cathode collector has a plurality of openings for venting undesirable gases formed within the cell and has on at least one of its surfaces a substantially continuous layer of a gas-permeable, electrolyte-impermeable conductive material.

33. The cell of claim 31 wherein said anode is zinc, said cathode comprises manganese dioxide, and said electrolyte comprises ammonium chloride.

34. The cell of claim 31 wherein said anode is zinc, said cathode comprises manganese dioxide, and said electrolyte comprises zinc chloride.

35. A multicell battery comprising an outer negative electrode, an outer positive electrode;

at least one duplex electrode between the outer positive electrode and the outer negative electrode;

a separator and an electrolyte between each positive and negative electrode; and

a cathode collector secured to the outer side of the positive electrode;

said outer negative electrode having a plurality of openings for venting undesirable gases formed within the cell and having on its outer surface a substantially continuous layer of a gas-permeable, electrolyte-impermeable material;

said duplex electrode comprising a positive electrode bonded to a porous negative electrode via a conductive layer, and all of said components of said battery secured together so as to maintain a relatively low electrical resistance contact between said individual cell components.

36. The battery of claim 35 wherein the cathode collector has a plurality of openings for venting undesirable gases formed within the cell and has on at least one surface a substantially continuous layer of a gas-permeable, electrolyte-impermeable conductive material.

37. The battery of claim 35 wherein each anode is zinc, each cathode comprises manganese dioxide, and each electrolyte comprises ammonium chloride.

38. The battery of claim 35 wherein each anode is zinc, each cathode comprises manganese dioxide and each electrolyte comprises zinc chloride.

39. A thin, flat cell having a sheet metal anode;

a cathode of depolarizer mix;

a separator between said anode and said cathode, an electrolyte in contact with said anode and said cathode; and

a cathode collector;

said anode having a plurality of openings for venting undesirable gases formed within the cell and having on its outer surface a substantially continuous layer of a gas-permeable, electrolyte-impermeable material, and wherein all of said components of said cell are secured together so as to maintain a relatively low electrical resistance contact between said individual cell components.

40. The cell of claim 39 wherein the cathode collector has a plurality of openings for venting undesirable gases formed within the cell and has on at least one surface a substantially continuous layer of a gas-permeable, electrolyte-impermeable conductive material.

41. The cell of claim 39 wherein said anode is zinc, said cathode comprises manganese dioxide, and said electrolyte comprises ammonium chloride.

42. The cell of claim 39 wherein said anode is zinc, said cathode comprises manganese dioxide, and said electrolyte comprises zinc chloride.

43. In a thin, flat laminar battery of the type comrising a plurality of superposed cells connected in series by conductive plastic intercell connectors and terminated at each end by a conductive plastic current collector covered by a metallic sheet terminal collector plate, the improvement which comprises at least one gas venting orifice formed in at least one of said metallic sheet terminal collector plates and a layer of gas permeable, water vapor impervious material coverting said orifice.

44. A thin, flat laminar battery comprising a stack of superposed series-connected cells each comprising an anode, a cathode and a separator between said anode and said cathode, said cells being connected in series by conductive plastic intercell connectors, said stack being terminated at each end by a conductive plastic intercell connector adhering to the exposed anode and cathode at opposite ends of said stack, a thin metal terminal sheet adhering to each of said current collectors, at least one of said metal terminal sheets being formed with at least one gas venting orifice, and a sheet of gas permeable, liquid impervious material over and contiguous with said vented terminal sheet and covering said orifice.