Process for preparing an overcoated photopolymer printing plate

• US 4,427,759 A
• Filed: 01/21/1982
• Issued: 01/24/1984
• Est. Priority Date: 01/21/1982
• Status: Expired due to Term

• Current Assignee: E. I. du Pont de Nemours and Company (Corteva, Inc.)
• Original Assignee: E. I. du Pont de Nemours and Company (Corteva, Inc.)
• Inventors: Gruetzmacher, Robert R., Munger, Stanley H.
• Primary Examiner(s): BRAMMER, JACK
• Application Number:
  US06/341,250
• Time in Patent Office: 733 Days
• Field of Search: 430/273, 430/271, 430/281, 156/234, 427/365
• US Class Current: 430/273.1
• CPC Class Codes: G03F 7/0955 one of the photosensitive systems comprising a non-macromolecular photopolymerisable compound having carbon-to-carbon double bonds, e.g. ethylenic compounds
• CPC Class Codes: G03F 7/16 Coating processes; Apparatus therefor applying coatings to base materials in general B05; applying photosensitive compositions to base for photographic purposes G03C1/74

Abstract

Process for preparing flexographic photopolymer elements by passing into the nip of a calender a photopolymer composition mass comprising elastomeric binder, monomeric compound, and photoinitiator and calendering the photopolymer composition either between (1) a support and multilayer cover element consisting essentially of a flexible cover film, optionally a flexible polymeric film, e.g., polyamide, and a layer of elastomeric composition which is photosensitive or becomes photosensitive during or after calendering, or between (2) two supports, one of which is removed prior to contact, e.g., by lamination or pressing, with the multilayer cover element. The flexographic photopolymer elements are useful for flexographic printing, e.g., dry-offset, letterpress printing.

Claims

1. In a process for preparing flexographic photopolymerizable elements which comprises passing into the nip of a calender a mass of a hot photopolymerizable composition comprising an elastomeric binder, an ethylenically unsaturated compound having at least one terminal ethylenic group, and a photoinitiator or photoinitiator system, and, while hot, calendering the photopolymerizable composition between a support and a multilayer cover element to form a photopolymerizable layer therebetween, the improvement wherein the multilayer cover element consists essentially of a flexible cover film and a layer of an elastomeric composition and optionally between the flexible cover film and the layer of elastomeric composition a flexible polymeric film, the layer of elastomeric composition being adjacent to the photopolymerizable layer and being photosensitive or becoming photosensitive during or after calendering by contact with the photopolymerizable layer, said layer of elastomeric composition comprising an elastomeric polymeric binder and optionally a second polymeric binder and a nonmigratory dye or pigment and, in addition, when said layer of elastomeric composition is photosensitive one or more ethylenically unsaturated monomeric compounds and/or photoinitiator or initiator system.

2. A process according to claim 1 wherein the mass of photopolymerizable composition is passed into the calender nip by an extruder.

3. A process according to claim 1 wherein the mass of photopolymerizable composition is passed into the calender nip as a hot melt from a mixing mill.

4. A process according to claim 1 wherein calendering occurs between two flexible supports, one of which is subsequently removed from the photopolymerizable layer, and the multilayer cover element is laminated to the photopolymerizable layer.

5. A process according to claim 1 wherein calendering occurs between two flexible sheets, one of which is subsequently removed from the photopolymerizable layer, and the multilayer cover element and photopolymerizable layer are pressed into contact.

6. A process according to claim 1 wherein the elastomeric layer in the multilayer cover element is a photopolymerizable elastomeric layer.

7. A process according to claim 1 wherein the flexible cover film in the multilayer cover element is a film bearing a silicone subbing layer.

8. A process according to claim 1 wherein the flexible polymeric film is a polyamide film.

9. A process according to claim 1 wherein the elastomeric composition in the multilayer cover element comprises an elastomeric block copolymer.

10. A process according to claim 9 wherein the block copolymer is a polystyrene-isoprene-polystyrene block copolymer.

11. A process according to claim 9 wherein the block copolymer is a polystyrene-polybutadiene-polystyrene block copolymer.

12. A process according to claim 1 wherein the photopolymerizable composition is passed into the nip of the calendar by extruding at a temperature in the range of about 130°

to 200°

C.

13. A process according to claim 1 wherein the elastomeric binder of the photopolymerizable composition is an elastomeric block copolymer.

14. A process according to claim 13 wherein the ethylenically unsaturated compound has two terminal ethylenic groups.

15. A process according to claim 14 wherein the ethylenically unsaturated compound is hexamethylene glycol diacrylate, hexamethylene glycol dimethacrylate or a mixture of both.

16. A process according to claim 1 wherein a colorant is present in the photopolymerizable layer.

17. A process according to claim 16 wherein a nonmigrating dye or pigment is present in the layer of elastomeric composition of the multilayer cover element which provides a contrasting color with the colorant in the photopolymerizable layer.

18. A process according to claim 1 wherein the flexible polymeric film is present in the multilayer cover element between the flexible cover film and the layer of elastomeric composition.