Bleach catalyst compositions and use thereof in laundry bleaching and detergent compositions

• US 4,430,243 A
• Filed: 07/30/1982
• Issued: 02/07/1984
• Est. Priority Date: 08/08/1981
• Status: Expired due to Fees

• Current Assignee: The Procter & Gamble Company
• Original Assignee: The Procter & Gamble Company
• Inventors: Bragg, Charles D.
• Primary Examiner(s): ALBRECHT, DENNIS
• Application Number:
  US06/403,376
• Time in Patent Office: 557 Days
• Field of Search: 252/102, 252/182, 252/186.33, 252/186.38, 252/95, 252/99, 252/429 R, 252/428, 252/429 C, 252/430, 252/431 C, 252/90, 252/91, 8/111
• US Class Current: 510/311
• CPC Class Codes: C11D 3/33 Amino carboxylic acids
• CPC Class Codes: C11D 3/364 containing nitrogen
• CPC Class Codes: C11D 3/3932 Inorganic compounds or complexes

Abstract

Laundry bleaching and detergent compositions comprising a peroxygen bleaching agent and a catalyst system therefor, the catalyst system comprising a heavy metal cation of defined bleach catalytic activity, particularly copper, iron or manganese cations, an auxiliary metal cation having little or no bleach catalytic activity, particularly zinc or aluminium cations, and a sequestrant having defined stability constants for the catalytic and auxiliary metal cations, particularly ethylenediaminetetraacetic acid, ethylenediaminetetra(methylenephosphonic acid) and water-soluble salts thereof. The laundry bleaching and detergent compositions deliver improved bleach performance, particularly at medium to high wash temperatures. Catalyst compositions for peroxygen bleaching agents are also disclosed.

Claims

1. A laundry detergent composition comprising from about 0% to about 40% of surfactant selected from anionic, nonionic, ampholytic and zwitterionic surfactants and mixtures thereof, from about 5% to about 90% of inorganic or organic detergency builder, from about 5% to about 35% of particulate peroxygen bleaching agent, and from about 0.05% to about 2% of a catalyst system soluble in water at pH 10 and comprising a dry mixture of:

(a) a first particulate component comprising a catalytic heavy metal cation having a catalytic activity for decomposition of the peroxygen bleaching agent of at least 10%, selected from the group consisting of cations of vanadium, chromium, manganese, iron, cobalt, copper, osmium, platinum, palladium, silver, mercury, and lead,

(b) a second particulate component comprising an auxiliary metal cation having a catalytic activity for decomposition of the peroxygen bleaching agent of less than 10%, selected from the group consisting of cations of zinc, aluminum and nickel, and

(c) a water soluble sequestrant selected from the group consisting of ethylenediaminetetraacetic acid, diethylenetriaminepentaacetic acid, ethylenediaminetetra-(methylenephosphinic acid), diethylenetriaminepenta-(methylene phosphonic acid), and alkali-metal and alkaline-earth metal salts thereof,

wherein the molar ratio of the sum total of (auxiliary metal cation+catalytic heavy metal cation) to sequestrant is in the range from 1;

1 to 20;

1 and the molar ratio of sequestrant to catalytic heavy metal cation is in the range from 1;

1 to 40;

1.

2. A composition according to claim 1 wherein the catalytic heavy metal cation is Cu(II), the auxiliary metal cation is selected from Zn(II) and Al(III), the sequestrant is selected from ethylenediamine-tetraacetic acid, ethylenediaminetetra(methylene-phosphonic acid), mixtures thereof and alkali-metal or alkaline earth metal salts thereof, and wherein the molar ratio of the sum total of (auxiliary metal cation+catalytic heavy metal cation) to sequestrant is in the range from 1.1:

1 to 10;

1 and the molar ratio of sequestrant to catalytic heavy metal cation is in the range from 1.1;

1 to 10;

1.

3. A composition according to claim 1 wherein the second particulate component is an agglomerate comprising from about 0.01 to about 2, preferably from about 0.05 to about 1.5 mMoles% of catalytic metal cation and from about 0.01 to about 3, preferably from about 0.05 to about 3 mMoles% of sequestrant incorporated in a water-soluble or water-dispersible organic carrier having a melting point greater than about 30°

C., preferably greater than about 40°

C.

4. A composition according to claim 3 wherein the organic carrier is selected from C₁₆ -C₂₄ fatty alcohols ethoxylated with from 10 to 100 ethylene oxide units, polyethyleneglycols having a molecular weight of from about 400 to about 40,000 and mixtures thereof.

5. A composition according to claim 1 comprising a dry mixture of:

(a) from about 40% to about 93.9% of spray dried base powder comprising from 0% to about 40% surfactant, from about 5% to about 90% inorganic or organic detergency builder, and from about 0.5 to about 3 mMoles% of auxiliary metal cation,

(b) from about 0.1% to about 10% of an agglomerate comprising from about 0.01 to about 2, preferably about 0.05 to about 1.5 mMoles% of catalytic metal cation and from about 0.01 to about 3, preferably from about 0.05 to about 3 mMoles% of the sequestrant incorporated in a water-soluble or water-dispersible organic carrier having a melting point of at least about 30°

C. and/or in a matrix of water-soluble salt, said agglomerate being substantially free of unbound water, and

(c) from about 5% to about 35% of peroxygen bleaching agent;

the composition additionally containing from 1% to 15% of ethoxylated nonionic surfactant sprayed onto the dry mixture of spray-dried base powder, agglomerate and peroxygen bleaching agent.

6. A process for making the composition of claim 1 comprising the step of precomplexing the catalytic heavy metal cation and sequestrant prior to admixture with the peroxygen bleaching agent.

7. A process according to claim 6 comprising the steps of agglomerating the complex of catalytic heavy metal cation and sequestrant with a water-soluble or water-dispersible organic carrier having a melting point of at least about 30°

C. and/or with a water-soluble salt whereby the agglomerate so formed is substantially free of unbound water, and dry-mixing the agglomerate with a separate particulate component comprising the auxiliary metal cation and with particulate peroxygen bleaching agent.