Asphalt composition

• US 4,430,465 A
• Filed: 03/22/1982
• Issued: 02/07/1984
• Est. Priority Date: 03/22/1982
• Status: Expired due to Term

• Current Assignee: BP Corporation North America Incorporated (BP PLC)
• Original Assignee: Phillips Petroleum Company (ConocoPhillips)
• Inventors: Abbott, Clifford E.
• Primary Examiner(s): Welsh, Maurice J.
• Assistant Examiner(s): Moore, M. L.
• Application Number:
  US06/360,303
• Time in Patent Office: 687 Days
• Field of Search: 524/64, 524/59, 524/68, 524/62, 428/291, 428/289
• US Class Current: 524/64
• CPC Class Codes: C04B 14/04 Silica-rich materials; Silicates
• CPC Class Codes: C04B 14/26 Carbonates
• CPC Class Codes: C04B 2111/0075 for road construction
• CPC Class Codes: C04B 24/12 Nitrogen containing compounds organic derivatives of hydrazine hydrazine C04B22/00
• CPC Class Codes: C04B 24/26 obtained by reactions only involving carbon-to-carbon unsaturated bonds C04B24/243 takes precedence
• CPC Class Codes: C04B 24/2676 Polystyrenes
• CPC Class Codes: C04B 26/26 Bituminous materials, e.g. tar, pitch C08L95/00 takes precedence
• CPC Class Codes: C08K 5/17 Amines; Quaternary ammonium compounds
• CPC Class Codes: C08L 57/02 Copolymers of mineral oil hydrocarbons
• CPC Class Codes: C08L 9/06 Copolymers with styrene
• CPC Class Codes: C08L 95/00 Compositions of bituminous materials, e.g. asphalt, tar, pitch
• CPC Class Codes: D06N 5/00 Roofing materials comprising a fibrous web coated with bitumen or another polymer, e.g. pitch compositions of bituminous materials C08L95/00, roof covering E04D5/00, roofing underlays E04D12/002
• CPC Class Codes: Y10T 442/2918 Polypropylene fiber fabric
• CPC Class Codes: Y10T 442/682 Needled nonwoven fabric

Abstract

An asphalt composition is made by mixing together asphalt, at least one alkadiene-vinylarene copolymer, a petroleum hydrocarbon resin and an amine-based antistripping agent. A fibrous mate can be coated with the above-described composition to produce an article useful for road repair applications and waterproofing purposes.

Claims

1. A composition comprising (a) asphalt, (b) at least one alkadiene-vinylarene copolymer, (c) at least one petroleum hydrocarbon resin, and (d) at least one antistripping agent;

wherein said antistripping agent is a highly branched organic amine.

2. A composition in accordance with claim 1 wherein said antistripping agent is a member of the group consisting of aliphatic and cycloaliphatic organic amines ranging in molecular weight from about 200 to about 500.

3. A composition in accordance with claim 2 wherein said antistripping agent comprises a mixture of (i) a mixture of said aliphatic and cycloaliphatic branched organic amines and (ii) at least one member of the group consisting of alcohols, ethers and ketones;

wherein the molecular weight of each of said alcohols, ethers and ketones is less than about 200; and

wherein each of said alcohols, ethers and ketones contains a cycloalkyl group selected from the class consisting of cyclohexyl and cyclopentyl groups.

4. A composition in accordance with claim 3 wherein the molecular weight of said aliphatic and cycloaliphatic branched organic amines ranging from about 350 to about 400.

5. A composition in accordance with claim 1, 2, 3 or 4 wherein said petroleum hydrocarbon resin has been derived from 1,3-pentadiene and indene monomers.

6. A composition in accordance with claim 1, 2, 3 or 4 wherein said alkadiene-vinylarene copolymer is a thermoplastic 1,3-butadiene-styrene block copolymer having a bound styrene content of about 10 to about 50 weight percent.

7. A composition in accordance with claim 6 wherein said petroleum hydrocarbon resin has been derived from 1,3-pentadiene and indene monomers.

8. A composition in accordance with claim 7 wherein said composition further comprises an extender oil and a filler selected from the group consisting of silicates, carbonates and mineral aggregates.

9. A composition in accordance with claim 1 or 2 wherein the amount of (b) is within the range of about 5 to about 50 parts by weight per 100 parts by weight of (a);

wherein the amount of (c) is within the range of about 1 to about 20 parts by weight per 100 parts by weight of (a); and

wherein the amount of (d) is within the range of about 0.1 to about 5 parts by weight per 100 parts by weight of (a).

10. A composition in accordance with claim 7 wherein the amount of (b) is within the range of about 25 to about 35 parts by weight per 100 parts by weight of (a);

wherein the amount of (c) is within the range of about 8 to about 12 parts by weight per 100 parts by weight of (a); and

wherein the amount of (d) is within the range of about 0.4 to about 2 parts by weight per 100 parts by weight of (a).

11. An article of manufacture comprising a mat coated on at least one side with the composition of claim 1;

wherein said mat is comprised of fibers selected from the group consisting of natural organic fibers, synthetic resin fibers and inorganic fibers.

12. An article of manufacture in accordance with claim 11 wherein said natural organic fibers are selected from the group consisting of wool fibers and cotton fibers;

wherein said synthetic resin fibers are selected from the group consisting of polypropylene fibers, polyethylene fibers, polyester fibers and nylon fibers; and

wherein said inorganic fibers are selected from the group consisting of glass fibers, carbon fibers and asbestos fibers.

13. An article of manufacture in accordance with claim 11 wherein said mat is a nonwoven needlepunched fabric comprised of polypropylene fibers.

14. An article of manufacture in accordance with claim 11 wherein the ratio of the weight of said composition to the weight of said mat is within the range of about 1:

1 to about 30;

1.

15. An article of manufacture in accordance with claim 14 wherein said ratio is within the range of about 5:

1 to about 15;

1.

16. An article of manufacture comprising a mat coated on at least one side with the composition of claim 7;

wherein said mat is a nonwoven needlepunched fabric comprised of polypropylene fibers; and

wherein the ratio of the weight of said composition to the weight of said mat is within the range of about 8;

1 to about 10;

1.