Reverse osmosis apparatus and method incorporating external fluid exchange

• US 4,432,876 A
• Filed: 07/30/1980
• Issued: 02/21/1984
• Est. Priority Date: 07/30/1980
• Status: Expired due to Term

• Current Assignee: Recovery Engineering, Incorporated (The Procter & Gamble Company)
• Original Assignee: Seagold Industries Corporation
• Inventors: Keefer, Bowie G.
• Primary Examiner(s): Spear, Jr., Frank A.
• Application Number:
  US06/173,456
• Time in Patent Office: 1,301 Days
• Field of Search: 210/416.1, 210/134, 210/652, 210/130, 210/321.1, 210/433.2, 417/541, 417/374, 417/323, 417/517
• US Class Current: 210/652
• CPC Class Codes: B01D 2313/18 Specific valves
• CPC Class Codes: B01D 2313/246 Energy recovery means
• CPC Class Codes: B01D 61/06 Energy recovery
• CPC Class Codes: F04B 11/0033 with a mechanical spring
• CPC Class Codes: F04B 11/005 using two or more pumping pistons
• CPC Class Codes: F04B 11/0091 using a special shape of fluid pass, e.g. throttles, ducts

Abstract

Reverse osmosis pump using a fluid volume exchange structure interconnecting pumping and expansion chambers of feed cylinder externally of feed cylinder. This structure permits exchange of volume between pumping and expansion chambers following initiation of induction or pumping stroke. Volume exchange provides a dwell interval to shift main directional valve across closed center position thereof, thus increasing tolerance to valve actuation, and also tends to equalize pressure differences across ports of the valve prior to opening of such ports, thus reducing erosion and valve gear wear. Also tends to reduce pressure differences across feed displacer, thus reducing sealing problems. Volume exchange structure can be a resilient diaphragm with no intermixing of fluid, mechanically timed valve permitting intermixing of fluid, or cross-over relief valves which are pressure responsive to permit intermixing of fluid.

Claims

1. Pumping apparatus for membrane separation apparatus for separating a feed fluid into permeate fluid and concentrate fluid fractions which respectively are permeated and rejected by selective membrane means, the pumping apparatus including:

a reciprocating feed pump having at least one feed cylinder with a feed displacer mounted on a feed displacer rod reciprocable within the feed cylinder, the cylinder and displacer rod having relative diameters which define cylinder interior/displacer rod proportions to determine in part the recovery ratio of permeate fluid fraction to total feed fluid flow;

a pumping chamber on one side of the displacer communicating with inlet conduit means to admit feed fluid, and with outfeed conduit means to conduct feed fluid to the membranes;

return conduit means to conduct concentrate fluid from the membranes to an expansion chamber on an opposite side of the displacer;

means to reduce fluctuations in pressure and fluid flow across the membranes, first and second valve means communicating with the expansion chamber and pumping chamber respectively and cooperating with the conduit means to direct fluid flow to and from the membrane means and to exhaust de-pressurized concentrate fluid fraction from the expansion chamber, the first valve means having a closed intermediate position between two open positions;

reciprocable drive means activating the feed displacer rod and first valve means whilst maintaining a phase difference or angle between the feed displacer stroke and actuation of the first valve means, the pumping apparatus including dwell means having fluid volume exchange means further characterized by;

(a) an exchange conduit means extending externally of the feed cylinder interior and interconnecting the pumping and expansion chambers,

(b) volume exchange control means within the exchange conduit to control volume exchange between the chambers,

so that fluid volume is exchanged between the chambers to approximately equalize pressure between the pumping and expansion chambers following reversal of feed displacer rod movement and to provide a dwell interval or angle sufficient to shift the first valve means across an effectively closed intermediate position thereof while initial movement of the feed displacer rod tends to equalize pressure differences across ports of the first valve means that are about to be opened prior to opening of such ports.

2. Apparatus as claimed in claim 1 further characterized by:

(a) the volume exchange control means being a yieldable partition means extending across the exchange conduit to prevent intermixing of fluid between the pumping and expansion chambers, and yet yielding to pressure differences resulting from initiation of displacer rod stroke.

3. Apparatus as claimed in claim 2 further characterized by:

(a) the yieldable partition means being an exchange displacer means within an exchange chamber, the displacer being resiliently centered within the displacer chamber.

4. Apparatus as claimed in claim 1 further characterized by:

(a) the volume exchange control means being dwell vent valve means adapted to open to permit fluid flow therethrough to intermix fluid between the pumping and expansion chambers following reversal of displacer rod stroke.

5. Apparatus as claimed in claim 4 further characterized by:

(a) the exchange conduit dividing into two bifurcated portions,

(b) the vent valve means being cross over relief valves fitted in the bifurcated portions/of the exchange conduit means to balance approximately pressure differences between the pumping and expansion chambers.

6. Apparatus as claimed in claim 2, 3, 4 or 5 further characterized by:

(a) exchange conduit means communicating with the return and outfeed conduit means and positioned between the chambers of the feed cylinder and the first and second valve means associated with the return and outfeed conduit means.

7. Apparatus as claimed in claim 1 further characterized by:

(a) at least two additional feed cylinders, each cylinder having a feed displacer and a feed displacer rod, the rods being driven by the rotatable drive means so that the cylinders are phased apart from each other, each additional cylinder communicating with the conduit means to pump fluid to, and to receive fluid from, the membrane means,

(b) the first valve means of each feed cylinder cooperating with the rotatable drive means associated with one of the additional cylinders to provide phase difference for valve actuation.

8. Pumping apparatus as claimed in claim 1 further characterized by:

(a) a plurality of similar feed cylinders wherein the total number of feed cylinders in a cooperating set is factored by an odd number greater than one, the feed cylinders having respective reciprocable feed displacers and respective feed displacer rods, each displacer rod cooperating with the rotatable drive means so that the feed displacers are phased angularly equally apart, inlet and outfeed conduit means and respective second valve means communicating with the respective pumping chambers to admit feed fluid into and to conduct feed fluid from the pumping chambers to the membrane means, return conduit means to conduct concentrate fluid from the membrane means to respective expansion chambers of each cylinder, the first valve means of each cylinder is responsive to the drive means of a remaining cylinder so that the first valve means controlling fluid flow relative to a particular cylinder is phased relative to that particular cylinder by an amount dependent on phase angle between cylinders of the cooperating set.

9. A pumping apparatus as claimed in claim 8 further characterized by:

(a) the first valve means of each feed cylinder is actuated by a feed displacer rod means of another cylinder separated by a phase angle which differs from 90°

by half of the dwell angle.

10. A pumping apparatus as claimed in claim 7, 8 or 9 further characterized by:

(a) the first valve means of each feed cylinder being a slidable valve spool connected with the respective feed displacer rod so that the valve spool connected to the displacer rod of one cylinder controls the direction of pressurized concentrate fluid flow from the membrane means to the expansion chamber of one of the remaining feed cylinders.

11. A pumping apparatus as defined in claim 7, 8 or 9 further characterized by:

(a) the first, second and third feed cylinders having respective first, second and third valve spools and valve chambers, each spool being reciprocable within the respective valve chamber and rigidly connected to the respective feed displacer rod,

(b) each valve chamber having at one end thereof interconnected concentrate fluid return conduit means, at an opposite end thereof interconnected exhaust fluid conduit means, and adjacent an intermediate position between ends of the chamber an intermediate concentrate fluid conduit means interconnecting the valve chamber of one cylinder with an expansion chamber of one of the remaining cylinders.

12. A method of membrane separation of a feed fluid into permeate fluid and concentrate fluid fractions which are respectively permeated and rejected by selective membrane means, the membrane means being exposed to pressurized feed fluid supplied by a reciprocating feed pump means having at least one feed cylinder with a feed displacer mounted on a feed displacer rod, the rod being driven by reciprocable drive means, the displacer dividing the cylinder into a pumping chamber for feed fluid and an expansion chamber for concentrate fluid, valve means determining fluid flow directions to and from the chambers and the membrane means, the method including steps of:

simultaneously inducting feed fluid into the pumping chamber and exhausting depressurized concentrate fluid from the expansion chamber;

followed by;

pressurizing feed fluid in the pumping chamber and simultaneously admitting pressurized concentrate fluid into the expansion chamber to supplement energy supplied to the feed displacer, the method being characterized by;

(a) following reversal of feed displacer rod movement, exchanging fluid volume between the pumping and expansion chambers externally of the feed cylinder interior so as to approximately equalize pressure difference across ports of a directional valve means that are about to be opened prior to opening of such ports, and essentially simultaneously shifting the first valve means across an effectively closed intermediate position thereof.

13. A method as claimed in claim 12 further characterized by:

(a) exchanging fluid volume between the pumping and expansion chambers by deflecting a pressure responsive partition which separates fluids in the pumping and expansion chambers to prevent intermixing thereof.

14. A method as claimed in claim 12 further characterized by:

(a) exchanging fluid volume between the pumping and expansion chambers by permitting intermixing externally of the chambers between portions of the fluid in the chambers.

15. A method as claimed in claim 12 further characterized by:

(a) simultaneously whilst operating one feed cylinder, also operating from the rotatable drive means at least two additional feed cylinders so that the feed cylinders are phased equally apart from each other,

(b) operating the valve means associated with each feed cylinder by the rotatable drive means associated with one of the additional cylinders, phase difference between the cylinders providing adequate dwell for valve actuation.