CO.sub.2 Removal from gaseous streams

• US 4,433,981 A
• Filed: 06/26/1981
• Issued: 02/28/1984
• Est. Priority Date: 02/18/1981
• Status: Expired due to Term

• Current Assignee: Shell Oil Company (Shell Plc)
• Original Assignee: Shell Oil Company (Shell Plc)
• Inventors: Willis, Carl L., Slaugh, Lynn H.
• Primary Examiner(s): Spitzer, Robert H.
• Application Number:
  US06/277,513
• Time in Patent Office: 977 Days
• Field of Search: 55/59, 55/62, 55/68, 55/74, 252/411 R, 252/462, 252/463, 252/475, 252/476, 423/230
• US Class Current: 95/139
• CPC Class Codes: B01J 20/041 Oxides or hydroxides
• CPC Class Codes: B01J 20/08 comprising aluminium oxide or hydroxide; comprising bauxite
• CPC Class Codes: B01J 20/3078 Thermal treatment, e.g. calcining or pyrolizing
• CPC Class Codes: B01J 20/3204 Inorganic carriers, supports or substrates
• CPC Class Codes: B01J 20/3236 containing metal, other than zeolites, e.g. oxides, hydroxides, sulphides or salts
• CPC Class Codes: B01J 20/3433 of sorbents or filter aids other than those covered by B01J20/3408 - B01J20/3425
• CPC Class Codes: B01J 20/3483 by thermal treatment not covered by groups B01J20/3441 - B01J20/3475, e.g. by heating or cooling
• CPC Class Codes: Y02C 20/40 of CO2

Abstract

Carbon dioxide is removed from a gaseous stream by contacting the stream with an adsorbent prepared by impregnating a porous aluminum with an alkali metal or alkaline earth metal oxide or salt decomposable upon calcination and subsequently calcining the impregnated alumina at about 350° C.-700° C.

Claims

1. A process for removing carbon dioxide from a gaseous stream which comprises contacting said stream at a temperature up to about 300°

C. with an adsorbent prepared by impregnating a porous alumina with a sodium or potassium oxide or salt decomposable to the oxide and calcining the impregnated alumina at a temperature ranging from about 350°

C. to about 850°

C.

2. The process of claim 1 where, in the adsorbent, the molar ratio of sodium or potassium metal to alumina ranges from about 2:

1 to about 1;

50.

3. The process of claim 2 where, in the adsorbent, the sodium or potassium salt is a carbonate or bicarbonate.

4. The process of claim 1 where, in the adsorbent, the impregnated alumina is calcined at about 350°

C. to about 700°

C.

5. The process of claim 4 where, in the adsorbent, the molar ratio of sodium or potassium metal to alumina ranges from about 2:

1 to about 1;

50.

6. The process of claim 5 where, in the adsorbent, the sodium or potassium salt is a carbonate or bicarbonate.

7. The process of claims 1, 2, 3, 4, 5 or 6 wherein after contacting the carbon dioxide-containing gaseous stream with the adsorbent for a substantial period of time, the flow of said stream is stopped, the absorbent is reheated to calcining temperature until substantially all of the carbon dioxide is stripped off, the adsorbent is cooled to operation conditions and the flow of the gaseous stream is resumed.

8. The process of claims 1, 2, 3, 4, 5 or 6 wherein after contacting the carbon dioxide-containing gaseous stream with the adsorbent for a substantial period of time, the flow of said stream is stopped, a stream of non-carbon dioxide-containing gas is passed over the adsorbent at calcining temperature until substantially all of the carbon dioxide is stripped off, the flow of non-carbon dioxide-containing gas is stopped and the flow of carbon dioxide-containing gas is resumed.