Method for producing a reticulate electrode for electrolytic cells

• US 4,435,252 A
• Filed: 09/24/1982
• Issued: 03/06/1984
• Est. Priority Date: 04/25/1980
• Status: Expired due to Fees

• Current Assignee: OLIN Corporation
• Original Assignee: OLIN Corporation
• Inventors: Kadija, Igor V.
• Primary Examiner(s): Edmundson, F.
• Application Number:
  US06/422,799
• Time in Patent Office: 529 Days
• Field of Search: 204/11, 204/12, 204/20, 204/284, 204/290 R, 252/425.4, 429/42, 429/44, 429/236
• US Class Current: 205/75
• CPC Class Codes: C25B 11/00 Electrodes; Manufacture thereof not otherwise provided for
• CPC Class Codes: C25B 11/02 characterised by shape or form

Abstract

An electrode for use in the electrolysis of aqueous solutions of ionizable compounds is produced by a method which comprises affixing filaments to a support fabric to form a network of filaments. An electroconductive metal is deposited on the filaments to form metal coated filaments. During the metal deposition, interfilament bonding takes place at contact sites between adjacent filaments. Removing the support fabric from the metal coated filament network produces a reticulate electrode having a porosity of at least about 80 percent. The three dimensional electrodes are highly conductive, have high internal surface area, and are mechanically strong.

Claims

1. A method for producing a reticulate electrode for use in the electrolysis of aqueous solutions of ionizable compounds which comprises:

(a) affixing filaments to a support fabric to form a network of filaments, said filaments being comprised of a metal or metal sensitized plastic,

(b) depositing an electroconductive metal on said filaments to form metal coated filaments, said deposition providing interfilament bonding at contact sites between adjacent filaments, and

(c) removing said support fabrics from said metal coated filament network to produce a reticulate electrode having a porosity of at least 80 percent.

2. The method of claim 1 in which said support fabric is comprised of synthetic fibers selected from the group consisting of polyesters, nylon, polyolefins, and polyarylene compounds.

3. The method of claim 2 in which said reticulate electrode has a porosity of from about 95 to about 98 percent.

4. The method of claim 2 in which said support fabric is a felt fabric.

5. The method of claim 3 in which said support fabric is removed from said metal coated filament network by mechanical means.

6. The method of claim 3 in which said support fabric is removed from said metal coated filament network by dissolving said support fabric in a solvent.

7. The method of claim 1 in which said electroconductive metal is selected from the group consisting of nickel, nickel alloys, molybdenum, molybdenum alloys, cobalt, cobalt alloys, vanadium, vanadium alloys, tungsten, tungsten alloys, titanium, titanium alloys, gold, gold alloys, platinum group metals, and platinum group metal alloys.

8. The method of claim 7 in which said filaments are comprised of a metal selected from the group consisting of nickel, nickel alloys, titanium, titanium alloys, steel, silver or copper.

9. The method of claim 7 in which said filaments are comprised of a plastic selected from the group consisting of polyarylene sulfides, polyolefins produced from olefins having 2 to about 6 carbon atoms and their chloro- and fluoro-derivatives, and nylon, said plastics being sensitized by a metal selected from the group consisting of silver, aluminum, or palladium.

10. The method of claim 8 or claim 9 in which said filaments are in the form of a web affixed to said support fabric.

11. The method of claim 10 in which said filaments have diameters in the range of from about 1 to about 100 microns.

12. The method of claim 10 in which said electroconductive metal is deposited by electroplating.

13. The method of claim 12 in which said filament is nylon and said metal is silver.

14. The method of claim 13 in which said electroconductive metal is nickel or nickel alloy.

15. The method of claim 9 in which said electroconductive metal is titanium or an alloy of titanium.

16. The method of claim 15 in which said electroconductive metal has a coating of a platinum group metal or an alloy of a platinum group metal.