Polyester polymer polyols made with polyester polycarbonates and polyurethanes therefrom

• US 4,435,527 A
• Filed: 01/24/1983
• Issued: 03/06/1984
• Est. Priority Date: 01/24/1983
• Status: Expired due to Term

• Current Assignee: The Dow Chemical Company (Dow, Inc.)
• Original Assignee: Texaco Incorporated (Chevron Corp.)
• Inventors: Cuscurida, Michael
• Primary Examiner(s): WELSH JR, MAURICE
• Application Number:
  US06/460,506
• Time in Patent Office: 407 Days
• Field of Search: 521/173, 260/463, 528/76, 528/77
• US Class Current: 521/173
• CPC Class Codes: C08G 18/12 using two or more compounds having active hydrogen in the first polymerisation step
• CPC Class Codes: C08G 18/4018 Mixtures of compounds of group C08G18/42 with compounds of group C08G18/48
• CPC Class Codes: C08G 18/44 Polycarbonates
• CPC Class Codes: C08G 18/72 Polyisocyanates or polyisothiocyanates
• CPC Class Codes: C08G 63/64 Polyesters containing both carboxylic ester groups and carbonate groups
• CPC Class Codes: C08G 63/672 Dicarboxylic acids and dihydroxy compounds
• CPC Class Codes: C08G 63/914 derived from polycarboxylic acids and polyhydroxy compounds

Abstract

A polyester polymer polyol made by the reaction of a polyester polycarbonate, a polyether polyol and an organic polyisocyanate is described. The polyester polycarbonate may have a molecular weight of about 250 to 1,000. The polyether polyol may have a molecular weight of about 3,000 to 8,000. This polyester polymer polyol may be used in the manufacture of flexible polyurethane foams which are characterized by good load bearing properties as well as good water absorption and retention properties. Foams made from these polymer polyols show a lesser tendency to yellow than those made from prior art polyols and polymer polyols.

Claims

1. A polyester polymer polyol made by the reaction of a polyester polycarbonate, a polyether polyol and an organic polyisocyanate wherein the combined portion of polyester polycarbonate and polyisocyanate is 10 to 40 wt. % of the polyether polyol portion, and the ratio of equivalents of polyester groups to equivalents of isocyanate groups ranges from 0.5 to 2.0.

2. The polyester polymer polyol of claim 1 wherein the polyether polyol has a molecular weight in the range of about 3,000 to 8,000.

3. The polyester polymer polyol of claim 1 wherein the polyester polycarbonate has a molecular weight in the range of about 250 to 1,000.

4. A method for producing a polyurethane which comprises first making a polyester polymer polyol by reacting a polyester polycarbonate, a polyether polyol and an organic polyisocyanate wherein the combined portion of polyester polycarbonate and polyisocyanate is 10 to 40 wt. % of the polyether polyol portion and the ratio of equivalents of polyester groups to equivalents of isocyanate groups ranges from 0.5 to 2.0 and then reacting said polyester polymer polyol with an organic polyisocyanate.

5. The method of claim 4 wherein the polyether polyol has a molecular weight in the range of about 3,000 to 8,000.

6. The method of claim 4 wherein the polyester polycarbonate has a molecular weight in the range of about 250 to 1,000.