Method of producing kraft pulp using an acid prehydrolysis and pre-extraction

• US 4,436,586 A
• Filed: 01/22/1982
• Issued: 03/13/1984
• Est. Priority Date: 01/22/1982
• Status: Expired due to Fees

• Current Assignee: Kamyr, Inc.
• Original Assignee: Kamyr, Inc.
• Inventors: Elmore, Carl L.
• Primary Examiner(s): Alvo, Steve
• Application Number:
  US06/341,627
• Time in Patent Office: 781 Days
• Field of Search: 162/19, 162/90, 162/76, 162/65, 162/237, 162/82, 435/161, 435/163, 435/165
• US Class Current: 162/19
• CPC Class Codes: C12P 7/10 substrate containing cellulosic material
• CPC Class Codes: D21C 1/00 Pretreatment of the finely-divided materials before digesting of waste paper D21C5/02
• CPC Class Codes: Y02E 50/10 Biofuels, e.g. bio-diesel

Abstract

A method for produce both kraft pulp and alcohol from hardwood chips or the like. The chips are subjected to mild acid prehydrolysis following by mild caustic pre-extraction. The withdrawn hydrolysate has insufficient furfural to inhibit microorganism growth, and both the hexose and pentose sugars in the hydrolysate are fermented to ultimately produce ethanol, butanol, or the like. The chips - after caustic pre-extraction - are subjected to a sulphate cook, and wash, and the resultant pulp is kraft pulp and even has viscosity and tear strength characteristics more desirable than that of conventional kraft pulp. The pulp can be subjected to oxygen delignification, and achieve a higher K number in fewer subsequent bleaching stages than conventional kraft pulp.

Claims

1. A method of producing carbohydrate material and kraft pulp from a liquid slurry of comminuted cellulosic fiber material comprising the steps of continuously:

(a) subjecting the liquid slurry of comminuted cellulosic fiber material to mild acid prehydrolysis, by subjecting said material to an acid concentration of, or equivalent to, about 0.2-0.5 percent H₂ SO₄, and a temperature of about 120°

C. or less;

(b) subjecting the slurry of prehydrolized comminuted cellulosic fiber material to mild caustic pre-extraction, by subjecting said material to a caustic concentration of, or equivalent to, about 0.5-4.0 percent NaOH, and at a temperature of about 60°

-90°

C.;

(c) removing hydrolysate, having carbohydrate material, released during the practice of steps (a) and (b) from the comminuted cellulosic material while continuously practicing steps (a) and (b); and

(d) effecting kraft cooking of the prehydrolized, pre-extracted comminuted cellulosic fiber material to produce kraft pulp.

2. A method as recited in claim 1 wherein steps (a)-(c) are practiced so that the hydrolysate has a low enough furfural content so that it is useful as feed material for the production of alcohol.

3. A method as recited in claim 2 comprising the further steps of subjecting the hydrolysate to neutralization, clarification, fermentation, and distillation to produce alcohol.

4. A method as recited in claims 1, 2 or 3 wherein step (a) is practiced by providing a concurrent flow of the slurry of comminuted cellulosic fiber material and acid.

5. A method as recited in claim 4 wherein step (c) is practiced by providing a countercurrent flow of the slurry of comminuted cellulosic fiber material and caustic.

6. A method as recited in claims 1, 2 or 3 wherein step (c) is practiced by providing a countercurrent flow of the slurry of comminuted cellulosic fiber material and caustic.

7. A method as recited in claim 1 comprising the further step (e) of effecting oxygen delignification of the kraft pulp, and wherein steps (a)-(e) are practiced so that the delignified kraft pulp produced has a lower Kappa number than such pulp produced from the same comminuted cellulosic fiber material and under substantially identical kraft cooking and oxygen delignification conditions but without prehydrolysis and pre-extraction.

8. A method as recited in claim 7 wherein the cellulosic fiber material is chips or sawdust of hardwood.

9. A method as recited in claim 7 wherein steps (a)-(c) are practiced so that the hydrolysate has a low enough furfural content so that it is useful as feed material for the production of alcohol.

10. A method as recited in claims 1, 2 or 7 wherein steps (a)-(c) are practiced in a first vertical vessel, and step (d) is practiced in a second vertical vessel, distinct from the first vessel.

11. A method of treating cellulosic fiber material utilizing a first vessel and a separate second vessel, said method comprising the steps of continuously:

(a) feeding comminuted cellulosic fiber material entrained in treatment liquid to a top portion of the first vessel;

(b) effecting mild acid prehydrolysis in an upper portion of the first vessel, by subjecting the material to an acid concentration of, or equivalent to, about 0.2-0.5 percent H₂ SO₄, and a temperature of about 120°

C. or less;

(c) effecting mild caustic pre-extraction in a lower portion of the first vessel, by subjecting the material to a caustic concentration of, or equivalent to, about 0.5-4.0 percent NaOH, and at a temperature of about 60°

-90°

C.;

(d) withdrawing hydrolysate from a screen of the first vessel;

(e) withdrawing liquid from a top portion of the first vessel to feed it back to entrain further feed comminuted cellulosic fiber material;

(f) withdrawing prehydrolized and pre-extracted fiber material from the bottom of the first vessel;

(g) feeding the material withdrawn from the bottom of the first vessel to the top of the second vessel;

(h) effecting sulfate digestion of the fiber material in the second vessel;

(i) withdrawing liquid from the top portion of the second vessel and returning it to the bottom of the first vessel; and

(j) withdrawing pulp from the bottom of the second vessel.

12. A method as recited in claim 11 wherein the acid prehydrolysis in the first vessel is practiced with concurrent flow between the acid and fiber material being treated.

13. A method as recited in claim 12 wherein the caustic pre-extraction is practiced with a countercurrent flow of caustic to the direction of flow of fiber material;

and wherein the hydrolysate is withdrawn through a screen at a central vertical position of the first vessel.

14. A method as recited in claims 11 or 12 comprising the further steps of:

withdrawing liquid from a position along the acid prehydrolysis portion of the first vessel;

heating the withdrawn liquid;

adding acid to the withdrawn liquid to effect the desired acid concentration in the prehydrolysis zone; and

returning the withdrawn liquid, after heating and acid addition, to the acid prehydrolysis zone of the first vessel.

15. A method as recited in claim 12 comprising the further step of:

effecting acid addition to the return line from the top of the first vessel to entrain further fiber material prior to the entrainment of further fiber material therewith, the acid addition providing the proper acid concentration for the acid prehydrolysis zone in the first vessel.

16. A method as recited in claim 11 wherein said mild caustic pre-extraction is practiced by withdrawing liquid through a screen at a bottom portion of the pre-extraction zone of the first vessel;

cooling the withdrawn liquid;

adding sufficient alkali to the withdrawn liquid to maintain the caustic concentration in the pre-extraction zone at a desired level; and

introducing the cooled, alkali-added liquid to a central portion of the first vessel in the caustic pre-extraction zone.

17. A method as recited in claim 16 wherein said central portion for re-introduction of liquid into the caustic pre-extraction zone is adjacent the bottom of the caustic pre-extraction zone, and wherein the introduced caustic flows countercurrently to the material flowing downwardly in the first vessel.

18. A method as recited in claim 11 comprising the further steps of:

adding white liquor to the return line from the top of the second vessel to the bottom of the first vessel, and heating the liquid in the return line from the top of the second vessel to the first vessel.

19. A method as recited in claim 11 wherein the method steps are practiced so that the pulp discharged from the second vessel is sulphate pulp having a substantially higher viscosity than the same pulp produced from the same comminuted cellulosic fiber material and under substantially identical sulfate processing conditions but without prehydrolysis and pre-extraction;

and wherein the withdrawn hydrolysate is subjected to the further steps of;

neutralization;

clarification;

fermentation; and

distillation to produce alcohol.

20. A method as recited in claim 19 comprising the further step (k) of effecting oxygen delignification of the sulphate pulp, and wherein steps (a)-(k) are practiced so that the delignified sulphate pulp produced has a lower Kappa number than such pulp produced from the same comminuted cellulosic fiber material and under substantially identical sulphate cooking and oxygen delignification conditions but without prehydrolysis and pre-extraction.