Method and apparatus for determination of lubricant stability

• US 4,438,203 A
• Filed: 06/14/1982
• Issued: 03/20/1984
• Est. Priority Date: 06/14/1982
• Status: Expired due to Fees

• Current Assignee: the united states of america as represented by the secretary of the navy
• Original Assignee: the united states of america as represented by the secretary of the navy
• Inventors: Wohltjen, Henry, Ravner, Harold, Sniegoski, Paul J.
• Primary Examiner(s): Turk, Arnold
• Application Number:
  US06/388,356
• Time in Patent Office: 645 Days
• Field of Search: 436/60, 436/160, 436/139, 422/78, 422/80, 422/94, 422/95
• US Class Current: 436/60
• CPC Class Codes: G01N 33/2888 Lubricating oil characteristics, e.g. deterioration lubricating properties G01N33/30

Abstract

Method and apparatus for determining when a lubricant has reached the end its useful life due to oxidative degradation. The apparatus continuously monitors the evolution of gaseous emission from the lubricant when subjected to oxidizing conditions, and detects the increased gas emission accompanying oxidative breakdown.

Claims

1. An apparatus for determining the stable lifetime of a lubricant when subjected to oxidizing conditions, comprising:

an oxidation cell for containing a sample of the lubricant;

means for heating the cell to the oxidation temperature of the lubricant;

means for bubbling oxygen at a constant flow rate through the cell;

means for detecting the concentration of combustible gas in oxygen flowing out of the cell; and

means for measuring the time elapsing until the onset of a rapid increase in the concentration of combustible gas.

2. The apparatus recited in claim 1 wherein the heating means includes:

an oven; and

a temperature-controller for the oven.

3. The apparatus recited in claim 1 wherein the bubbling means includes:

a pump for pumping ambient air;

a trap communicating with the pump for filtering moisture and other contamination from the air;

a flow meter communicating with the trap for measuring the flow rate of the pumped air; and

a side-arm bubbler tube disposed inside the oxidation cell and communicating with the flow meter for receiving the air and bubbling it through the lubricant sample and out of the cell.

4. The apparatus recited in claim 1 wherein the combustible gas-detecting means includes:

a gas sensor positioned over the cell in the path of the oxygen flowing out of the cell and responsive to the presence of combustible gas in the oxygen for generating a sensing signal;

an inverting amplifier for amplifying the signal from the sensor,

a potential divider connected to the output of the inverting amplifier for scaling down the amplified signal; and

a summing amplifier connected between the gas sensor and the inverting amplifier and including means for connecting an input of the summing amplifier to an external voltage source to balance out a quiescent signal from the sensor when no combustible gas is present in the oxygen flowing out of the cell.

5. The apparatus recited in claim 4 wherein the measuring means includes:

a chart recorder connected to the potential divider for recording the scaled-down signal as a function of time.

6. A method for determining the stable lifetime of a lubricant when subjected to oxidizing conditions comprising the steps of:

disposing a sample of the lubricant under test in an oxidation cell;

heating the cell to the oxidation temperature of the lubricant;

bubbling oxygen at a constant flow rate through the cell;

detecting the concentration of combustible gas in the oxygen flowing out of the cell; and

measuring the time elapsing until the onset of a rapid increase in the concentration of combustible gas.

7. The method recited in claim 6 wherein the bubbling step includes:

pumping ambient air;

filtering moisture and other contamination from the air;

measuring the flow rate of the pumped air; and

transferring the air to a bubbler tube inside the cell.

8. The method recited in claim 6 wherein the heating step includes:

inserting the cell in an oven; and

controlling the temperature of the oven.

9. The method recited in claim 6 wherein the detecting step includes:

positioning a gas sensor over the cell in the path of the oxygen flowing out of the cell;

amplifying the signal from the sensor;

scaling down the amplified signal; and

balancing out a quiescent signal from the sensor when no combustible gas is present in the oxygen flowing out of the cell.

10. The method recited in claim 9 wherein the measuring step includes:

recording the scaled-down signal as a function of time.