Redox mediation and hydrogen-generation with bipyridinium reagents

• US 4,439,302 A
• Filed: 11/24/1981
• Issued: 03/27/1984
• Est. Priority Date: 11/24/1981
• Status: Expired due to Term

• Current Assignee: Massachusetts Institute of Technology
• Original Assignee: Massachusetts Institute of Technology
• Inventors: Lewis, Nathan S., Wrighton, Mark S., Bruce, James A., Bookbinder, Dana C., Dominey, Raymond N.
• Primary Examiner(s): Andrews, R. L.
• Application Number:
  US06/324,496
• Time in Patent Office: 854 Days
• Field of Search: 204/129, 204/291, 204/290 R, 204/242, 252/428, 252/430, 252/429 R, 252/431 N, 428/411, 428/426, 428/457
• US Class Current: 204/290.11
• CPC Class Codes: C09K 2323/04 Charge transferring layer characterised by chemical composition, i.e. conductive
• CPC Class Codes: C25B 1/55 Photoelectrolysis
• CPC Class Codes: H01M 4/9008 Organic or organo-metallic compounds
• CPC Class Codes: Y02E 60/50 Fuel cells

Abstract

A variety of redox mediating agents employing bipyridinium reagents and such reagents in conjunction with dispersed noble metals, such as platinium, are disclosed as coatings for substrates and electrodes. The agents may be charged by an applied voltage or by photoelectric effects or may be equilibrated with hydrogen. The agents are useful in reducing biological materials and electrolytic hydrogen production.

Claims

1. An apparatus for redox mediation comprising:

(a) a substrate;

(b) a substrate bound reagent comprising molecules having a redox-active bipyridinium center and binding groups which permit substrate-binding and cross-linking; and

(c) at least one noble metal catalyst dispersed within the substrate-bound reagent.

2. The apparatus of claim 1 wherein the anchoring substrate comprises a glass reactor vessel.

3. The apparatus of claim 1 wherein the anchoring substrate comprises a high surface area support structure.

4. The apparatus of claim 1 wherein the noble metal comprises platinum.

5. The apparatus of claim 1 wherein the noble metal comprises gold.

6. The apparatus of claim 1 wherein the noble metal comprises paladium.

7. The apparatus of claim 2 wherein the substrate is an electrode.

8. The apparatus of claim 7 wherein the electrode comprises platinum.

9. The apparatus of claim 7 wherein the electrode comprises gold.

10. The apparatus of claim 7 wherein the electrode comprises a p-type semiconductor.

11. The apparatus of claim 10 wherein the semiconductor is silicon.

12. The apparatus of claim 10 wherein the semiconductor is indium phosphide.

13. The apparatus of claim 10 wherein the semiconductor is gallium arsenide.

14. The apparatus of claim 7 wherein the apparatus further comprises a noble metal catalyst dispersed within the bipyridinium reagent.