Crystallographically-oriented spatially-dispersed conductive fiber electrode

• US 4,439,303 A
• Filed: 06/28/1982
• Issued: 03/27/1984
• Est. Priority Date: 06/28/1982
• Status: Expired due to Fees

• Current Assignee: Maurice Cocchi
• Original Assignee: Maurice Cocchi
• Inventors: Cocchi, Maurice
• Primary Examiner(s): Niebling, John F.
• Application Number:
  US06/393,128
• Time in Patent Office: 638 Days
• Field of Search: 204/294, 204/434, 204/1 T
• US Class Current: 204/434
• CPC Class Codes: G01N 27/308 at least partially made of carbon
• CPC Class Codes: G01N 27/38 Cleaning of electrodes
• CPC Class Codes: G01N 27/42 Measuring deposition or liberation of materials from an electrolyte; Coulometry, i.e. measuring coulomb-equivalent of material in an electrolyte

Abstract

An electrode for use in electrochemical reactions such as electrochemical stripping analysis comprises a plurality of generally parallelly oriented and laterally spatially displaced electrically conductive fibers which are separated and held in a core by electrically insulating bonding material which substantially completely fills the lateral spaces between the fibers. The fibers, preferably carbon fibers, have a crystallographic structure of a plurality of maximum electrical conducting planes extending generally parallel to the fiber. The bonding material is substantially electrically insulating and may be a polyester or epoxy resin. The electrode is formed by saturating a plurality of fibers with fluid resin bonding material, compressing the resin saturated fibers by passing them through a form, allowing the bonding material to harden and forming an electrode face on the resulting core which extends transversely with respect to the fibers to maximumly expose the conductivity planes of the fibers at the electrode face.

Claims

1. An electrode for electrochemical stripping analysis, comprising a core of a plurality of generally uniformly oriented and laterally spatially displaced electrically conductive fibers having a crystallographic structure of conducting planes of greatest electrical conductivity extending parallel to the longitudinal dimension of the fiber, an electrically insulating bonding material connected to and substantially completely filling the lateral spaces throughout the core between the laterally spatially displaced fibers and bonding the fibers into the core,

an electrode face extending generally transversely with respect to and intersecting the ends of the fibers to maximumly expose the ends of the conducting planes for electron flow at the electrode face, and

an electrical conductor directly electrically connected to each fiber at the other end of each fiber opposite of the electrode face, each fiber extending continuously between its ends at the electrode face and at the electrical conductor.

2. An electrode as defined in claim 1 further comprising an electrical insulating jacket surrounding the core at the electrode face and exposing substantially only the electrode face for stripping analysis.

3. An electrode as defined in claim 2 wherein the electrode face extends perpendicular to the fibers at the electrode face.

4. An electrode as defined in claim 3 wherein each fiber of the core is substantially the same length between its ends at the conductor and at the electrode face.

5. An electrode as defined in claim 1 further comprising a plurality of said cores, including a central core and at least one laterally displaced ring core surrounding the central core, and an insulation ring including electrically insulating bonding material connected intermediately of and completely filling the space between the central and ring cores at the electrode face.

6. An electrode as defined in claims 1 or 5 wherein said fiber is a carbon fiber.

7. An electrode as defined in claims 1 or 5 wherein said bonding material is one of an epoxy or polyester resin.

11. An electrode as defined in claims 1 or 8 wherein the fibers are generally parallelly oriented in the core.

12. An electrode as defined in claim 1 wherein each fiber of the core has substantially the same resistance between its ends at the conductor and at the electrode face.

8. An electrode for electrochemical stripping analysis, and having an electrode face at which to perform the electrochemical reactions during the stripping analysis, comprising:

a plurality of uniformly oriented and laterally spatially displaced carbon fibers, each carbon fiber having paths of greatest electrical conductivity along its length defined by a crystallographic structure of each fiber having parallel conducting planes extending generally parallel to the longitudinal dimension of the fiber;

an electrical insulating resin material substantially completely surrounding each fiber and filling the lateral volume between the fibers and bonding the fibers permanently into a core;

a polished surface on the core intersecting substantially perpendicularly all of the fibers at ends thereof and substantially maximumly exposing the ends of the conducting planes of the fibers for electron flow at the polished surface, the polished surface defining the electrode face; and

an electrical insulating jacket surrounding the core and confining electrochemical reactions substantially only to the electrode face; and

electrical connection means for directly conducting current to the ends of all of the fibers which are opposite the ends of the electrode face, each fiber extending continuously between the electrical connection means and the electrode face.

9. An electrode as defined in claim 8 wherein the electrical connection means comprises a layer of electrically conducting material attached to each of the ends of the fibers of the opposite end of the core from the electrode face.

10. An electrode as defined in claims 8 or 9 further comprising a plurality of said cores including a generally cylindrical center core and at least one radially spaced and concentric ring core, and an insulating ring including an electrical insulating resin material ring connected intermediately of and completely filling the annular space between the central core and the ring core.