Process for removal of carbon dioxide from industrial gases

• US 4,440,731 A
• Filed: 09/08/1981
• Issued: 04/03/1984
• Est. Priority Date: 09/08/1981
• Status: Expired due to Term

• Current Assignee: Fluor Enterprises Incorporated (Fluor Corporation)
• Original Assignee: The Dow Chemical Company (Dow, Inc.)
• Inventors: Pearce, Roscoe L.
• Primary Examiner(s): Meros, Edward J.
• Assistant Examiner(s): Leeds, Jackson
• Application Number:
  US06/299,689
• Time in Patent Office: 938 Days
• Field of Search: 423/226, 423/228, 423/229, 252/388, 252/389 R, 252/390, 252/392, 252/400 R, 252/401
• US Class Current: 423/228
• CPC Class Codes: B01D 53/1493 Selection of liquid materials for use as absorbents
• CPC Class Codes: B01D 53/62 Carbon oxides
• CPC Class Codes: C23F 11/06 in markedly alkaline liquids
• CPC Class Codes: Y02C 20/40 of CO2

Abstract

Corrosion inhibiting compositions for use in aqueous absorbent gas-liquid contacting processes for recovering carbon dioxide (CO₂) from industrial gas and oil combustion and partial combustion process flue gases, particularly employing copper carbonate, in combination with one or more of dihydroxyethylglycine, alkali metal permangenate, alkali metal thiocyanate, nickel or bismuth oxides with or without an alkali metal cartonate. The inhibitors are effective in reducing corrosion of metals in contact with the aqueous absorbent in the absorbent regeneration section of the plant as well as reduce the thermal degradation of the absorbent when high oxygen content combustion gases are treated to recover the CO₂.

Claims

1. In a process for removing carbon dioxide (CO₂) from industrial combustion gases containing the CO₂ and O₂ contacting the gas, in a gas-liquid contactor, with an aqueous solution which contains an alkanol amine absorbent-reactant;

circulating the solution from the contactor to a regeneration step wherein the CO₂ is released from the absorbent, the CO₂ recovered and the essentially CO₂ free absorbent recycled to the contactor, the improvement which consists of employing as the essential additives to said solution, to reduce degradation of the absorbent under the conditions of use and corrosion of the metals in contact with said solution during use, at least above 50 ppm of copper⁺² and at least from 50 parts per million parts of solution one or more of the following;

dihydroxyethylglycine, an alkali metal carbonate, an alkali metal or ammonium permanganate and nickel and/or bismuth oxides.

2. In a process for removing carbon dioxide (CO₂) from industrial combustion gases containing the CO₂ and O₂ contacting the gas, in a gas-liquid contactor, with an aqueous solution which contains an alkanol amine absorbent-reactant;

circulating the solution from the contactor to a regeneration step wherein the CO₂ is released from the absorbent, the CO₂ recovered and the essentially CO₂ free absorbent recycled to the contactor, the improvement which consists of employing as the essential additives to said solution, to reduce degradation of the absorbent under the conditions of use and corrosion of the metals in contact with said solution during use, from 50 to 2000 ppm of copper as copper carbonate and at least from about 50 to about 2000 parts per million parts of the total solution of one or more of the following;

dihydroxyethylglycine, an alkali metal carbonate, an alkali metal or ammonium permanganate, and nickel and/or bismuth oxides.

3. In a process for removing carbon dioxide (CO₂) from industrial combustion gases containing the CO₂ and O₂ by contacting the gas, in a gas:

liquid contactor, with an aqueous solution which contains an alkanol amine absorbent-reactant;

circulating the solution from the contactor to a regeneration step wherein the CO₂ is released from the absorbent, the CO₂ recovered and the essentially CO₂ free absorbent recycled to the contactor, the improvement which consists of employing as the essential additives to said solution, to reduce degradation of the absorbent under the conditions of use and corrosion of the metals in contact with said solution during use, from at least about 50 ppm of dihydroxyethylglycine and at least about 50 parts per million parts of a thiocyanate salt and nickel and/or bismuth oxides.