Non-iridescent glass structures

• US 4,440,822 A
• Filed: 05/07/1981
• Issued: 04/03/1984
• Est. Priority Date: 04/04/1977
• Status: Expired due to Term

• Current Assignee: Roy G. Gordon
• Original Assignee: Roy G. Gordon
• Inventors: Gordon, Roy G.
• Primary Examiner(s): Robinson, Ellis P.
• Application Number:
  US06/261,371
• Time in Patent Office: 1,062 Days
• Field of Search: 428/428, 428/432, 428/336, 428/216, 428/701, 428/702, 428/696, 350/1.6, 427/160, 427/162, 427/163, 427/165
• US Class Current: 428/216
• CPC Class Codes: C03C 17/002 for flat glass, e.g. float glass
• CPC Class Codes: C03C 17/3417 all coatings being oxide coatings
• CPC Class Codes: C03C 2218/36 Underside coating of a glass sheet
• CPC Class Codes: G02B 5/208 for use with infrared or ultraviolet radiation, e.g. for separating visible light from infrared and/or ultraviolet radiation
• CPC Class Codes: G02B 5/282 reflecting for infrared and transparent for visible light, e.g. heat reflectors, laser protection
• CPC Class Codes: Y10T 428/24975 No layer or component greater than 5 mils thick
• CPC Class Codes: Y10T 428/265 1 mil or less

Abstract

This disclosure describes transparent glass window structures of the type bearing a first coating of infra-red reflective material which is advantageously less than about 0.85 microns in thickness and wherein the observance of iridescence resulting from such a first coating is markedly reduced by provision of a layer of continuously varying refractive index between the glass and the coating, such that the refractive index increases continuously from the glass to the first coating, thereby preventing the observation of iridescence. The invention also encompasses simple processes for providing such windows. A particular advantage of the invention is its efficacy with clear and lightly tinted glasses wherein the problem of iridescent color has had its greatest commercial impact.

Claims

1. A transparent glass product substantially free of iridescent appearance, having a glass substrate bearing a coating which is substantially uniform across the surface area thereof, said coating consisting of

(a) a lower coating zone comprising a material formed of at least two components which is characterized by a gradual change from a first composition proximate to said substrate having a relatively large proportion of a second component;

and

(b) an upper coating zone having a refractive index substantially the same as that of said second component;

wherein said lower coating zone is substantially linear with respect to its molecular proporation of said first component, as a function of distance from the glass substrate;

wherein said first component is SiO₂, said second component is SnO₂, and said upper coating zone is fluorine-doped tin oxide and wherein said material forming said lower coating zone contains tin oxide in a quantity below 40 percent at the interface of said lower coating zone which is closest to said glass substrate.

2. A glass product as defined in claim 1 wherein the lower coating zone contains at least about 30 percent of tin oxide at the interface of said lower coating zone which is closest to said glass substrate and wherein there is a haze-inhibiting layer of 25 to 100 angstroms of silicon dioxide at the interface of said glass substrate and said lower coating zone.

3. A glass product as defined in claim 1 or 2 wherein the visible reflectivity of said product is about 15 percent color of said product is neutral, and said product is free of visible haze.

4. A glass product as defined in claim 2 wherein the visible reflectivity of said product is about 15 percent, the color of said product is neutral, and said product is free of visible haze.

5. A product as defined in claims 1, 2, or 4 wherein refractive index of the glass substrate is within ±

0.04 refractive index units of refractive index of the coating material of said lower zone.

6. A product as defined in claim 1 or 4 wherein the thickness of said lower zone is between about 0.15 micron and about 0.30 microns.

7. A transparent glass product substantially free of iridescent appearance, having a glass substrate bearing a coating which is substantially uniform across the surface area thereof, said coating consisting of

(a) a lower coating zone comprising a material formed of at least two components which is characterized by a gradual change from a first composition proximate to said substrate having a relatively large proportion of a second component;

and

(b) an upper coating zone having a refractive index substantially the same as that of said second component;

wherein said lower coating zone is substantially linear with respect to its molecular proporation of said first component, as a function of distance from the glass substrate;

wherein said first component is SiO₂, said second component is SnO₂, and said upper coating zone is fluorine-doped tin oxide and wherein the refractive index of the glass substrate is with ±

0.04 refractive index units of the refractive index of the coating material of said lower zone.

8. A product as defined in claim 7 wherein the thickness of said lower zone is between about 0.15 micron and about 0.30 microns in thickness, and wherein visible reflectivity of said product is about 15 percent, color of said product is neutral, and said product is free of any substantial visible haze.