Phosphors

• US 4,442,377 A
• Filed: 03/10/1983
• Issued: 04/10/1984
• Est. Priority Date: 06/01/1976
• Status: Expired due to Term

• Current Assignee: The secretary of state for defence in her Britannic Majesty's Government of the United Kingdom of Great Britain And Northern Ireland
• Original Assignee: The secretary of state for defence in her Britannic Majesty's Government of the United Kingdom of Great Britain And Northern Ireland
• Inventors: Vecht, Aron, Higton, Malcolm
• Primary Examiner(s): Smith, John D.
• Application Number:
  US06/474,059
• Time in Patent Office: 397 Days
• Field of Search: 252/301.4 S, 252/301.6 S, 313/503, 313/506, 313/509, 427/12, 427/64, 427/66, 427/157
• US Class Current: 313/503
• CPC Class Codes: C09K 11/586 with alkaline earth metals
• CPC Class Codes: C09K 11/7703 with alkaline earth metals
• CPC Class Codes: C09K 11/7718 with alkaline earth metals
• CPC Class Codes: C09K 11/7731 with alkaline earth metals
• CPC Class Codes: H05B 33/14 characterised by the chemical or physical composition or the arrangement of the electroluminescent material , or by the simultaneous addition of the electroluminescent material in or onto the light source

Abstract

This invention provides phosphors for use in electroluminescent devices. Each phosphor contains a dopant, selected from the group consisting of europium, erbium, and terbium and at least one of the sulphides selected from the group consisting of strontium and calcium sulphide.

Claims

1. A process for making a DC electroluminescent device including the steps of

a. producing phosphor particles including a sulphide selected from the group consisting of strontium and calcium sulphide mixed with a dopant selected from the group consisting of europium, terbium, and erbium,

b. coating said phosphor particles with an element of Group Ib of the Periodic Table to introduce said element onto the outer surface of said particles,

c. embedding the coated particles in a matrix,

d. arranging the resulting particle bearing matrix as a phosphor layer in contact with two electrodes, and

e. passing a forming direct electrical current between the two electrodes until the electrical resistance is increased in a localized and predetermined region of the phosphor layer.

2. A process for making a DC electroluminescent device as set forth in claim 1, wherein the element of Group Ib of the Periodic Table is copper.

3. A process for making a DC electroluminescent device as set forth in claim 1, wherein said sulphide is calcium sulphide and said dopant is erbium.

4. A process for making a DC electroluminescent device as set forth in claim 1, wherein said sulphide is calcium sulphide and said dopant is europium.

5. A process for making a DC electroluminescent device as set forth in claim 4, wherein said dopant further comprises chlorine.

6. A process for making a DC electroluminescent device as set forth in claim 1, wherein said sulphide is calcium sulphide and said dopant is terbium.

7. A process for making a DC electroluminescent device as set forth in claim 1, wherein said sulphide is strontium sulphide and said dopant is erbium.

12. A DC electroluminescent device as set forth in claim 1, wherein said dopant further comprises chlorine.

8. A DC electroluminescent device prepared by a process comprising

a. producing phosphor particles including a sulphide selected from the group consisting of strontium and calcium sulphide mixed with a dopant selected from the group consisting of europium, terbium, and erbium,

b. coating said phosphor particles with an element of Group Ib of the Periodic Table and introducing said element onto the outer surface of said particles,

c. embedding the coated particles in a matrix,

d. arranging the resulting particle bearing matrix as a phosphor layer in contact with two electrodes, and

e. passing a forming direct electrical current between the two electrodes until the electrical resistance is increased in a localized and predetermined region of the phosphor layer.

9. A DC electroluminescent device as set forth in claim 8, wherein the element of Group Ib of the Periodic Table is copper.

10. A DC electroluminescent device as set forth in claim 8, wherein said sulphide is calcium sulphide and said dopant is erbium.

11. A DC electroluminescent device as set forth in claim 8, wherein said sulphide is calcium sulphide and said dopant is europium.

13. A DC electroluminescent device as set forth in claim 8, wherein said sulphide is calcium sulphide and said dopant is terbium.

14. A DC electroluminescent device as set forth in claim 8, wherein said sulphide is strontium sulphide and said dopant is erbium.

15. A DC electroluminescent device comprising an electrical insulating base, a first electrode supported on the base, a plastic matrix having phosphor particles embedded therein disposed as a layer with one side on said base and over said first electrode and an opposite side, a second electrode disposed in electrical contact with said opposite side of the said layer, and means for connecting said electrodes to a source of DC electric current to excite the phosphor layer to emit light, said phosphor particles comprising a member selected from the group consisting of strontium sulphide and calcium sulphide mixed with a dopant which activates the phosphor to be electroluminescent, wherein said dopant is selected from the group consisting of europium, terbium, and erbium, said phosphor particles being coated with an element of Group Ib of the Periodic Table.

16. A DC electroluminescent device as set forth in claim 15, wherein the element of Group Ib of the Periodic Table is copper.

17. A DC electroluminescent device as set forth in claim 15, wherein said sulphide is calcium sulphide and said dopant is erbium.

18. A DC electroluminescent device as set forth in claim 15, wherein said sulphide is calcium sulphide and said dopant is europium.

19. A DC electroluminescent device as set forth in claim 18, wherein said dopant further comprises chlorine.

20. A DC electroluminescent device as set forth in claim 15, wherein said sulphide is calcium sulphide and said dopant is terbium.

21. A DC electroluminescent device as set forth in claim 15, wherein said sulphide is strontium sulphide and said dopant is erbium.